Technology and Properties of (1-x)PZT-(x)PFW Ceramics with 0.25

2014 ◽  
Vol 605 ◽  
pp. 424-427 ◽  
Author(s):  
Ryszard Skulski ◽  
Ewa Nogas-Cwikiel ◽  
Dariusz Bochenek ◽  
Przemysław Niemiec ◽  
Paweł Wawrzała
Keyword(s):  
Solid Solution ◽  
Dielectric Properties ◽  
Room Temperature ◽  
Hysteresis Loops ◽  
Ceramic Technology ◽  
Ceramic Samples

We present the results of obtaining and investigating ceramic samples of solid solution (1-x)(PbZr0.53Ti0.47O3)-x (PbFe2/3W1/3O3) [i.e. (1-x)PZT-xPFW] with x = 0.25, 0.35, 0.45 and 0.55 obtained from oxides using conventional ceramic technology. In this paper we present the results of investigations of XRD and main dielectric properties. For x = 0.25 and x = 0.35 we investigated also P-E hysteresis loops at room temperature.

scholarly journals Technology and Electrophysical Properties of Multiferroic PZT–PFT Ceramics

2013 ◽  
Vol 58 (4) ◽  
pp. 1361-1364 ◽  
Author(s):  
P. Niemiec ◽  
R. Skulski ◽  
D. Bochenek ◽  
P. Wawrzała
Keyword(s):  
Dielectric Permittivity ◽  
Room Temperature ◽  
Ferroelectric Phase ◽  
Hysteresis Loops ◽  
Wide Distribution ◽  
Ceramic Technology ◽  
Dielectric Losses ◽  
Dielectric Measurements ◽  
Ceramic Samples ◽  
The Mean

Abstract We present the results of obtaining and investigating ceramic samples of solid solution (1-x)(PbZr0.53Ti0.47O3)- x(PbFe0.5Ta0.5O3) [i.e. (1-x)PZT-xPFT] with x =0.25, 0.35 and 0.45 obtained using conventional ceramic technology. These materials belong to class of materials known as multiferroics. Solid solutions PZT-PFT are the lowest-loss room-temperature multiferroics known, and as a result there are very interesting for magnetoelectric devices. Paper presents the results of termogravimetric investigations, EDS, XRD and main dielectric measurements. It has been stated that with increasing content of PFT decreases the mean diameter of grains and more wide distribution of grain diameters is observed. For x =0.25 sharp phase transition from ferroelectric phase to paraelectric one is observed and high values of dielectric permittivity. Composition PZT-PFT with x =0.45 has the lowest values of dielectric permittivity, and the transition is more diffused. The increase of x leads also to the shift of the temperature of maximum of dielectric permittivity towards lower temperatures. Samples with x =0.25 and x =0.35 exhibit very low values of dielectric losses up to about 100°C. Dielectric losses for samples with x =0.45 are higher. For obtained PZT-PFT samples we have investigated P-E hysteresis loops at room temperature for frequency 1 Hz. For composition x =0.25 it after application the field about 2.5 kV/mm polarization is equal approximately 28 μC/cm2, while for x =0.35, and x =0.45 after application the field about 2.0 kV/mm the polarizations are equal about 25 μC/cm2 and 20 μC/cm2 respectively. Very low values of losses and high values of polarization lead to the conclusion that interesting material PZT-PFT for applications should be composition with x =0.25.

Dielectric and Piezoelectric Properties of (Na,Ba)(Nb,Ti)O3 Lead-Free Piezoelectric Ceramics

2010 ◽  
Vol 445 ◽  
pp. 55-58 ◽  
Author(s):  
Rintaro Aoyagi ◽  
Makoto Iwata ◽  
Masaki Maeda
Keyword(s):  
Crystal Structure ◽  
Solid Solution ◽  
Dielectric Properties ◽  
Room Temperature ◽  
Electromechanical Coupling ◽  
Piezoelectric Properties ◽  
Electromechanical Coupling Factor ◽  
Coupling Factor ◽  
Lead Free ◽  
Dielectric And Piezoelectric Properties

(Na1-xBax)(Nb1-xTix)O3 (NNBTx; x=0.0-0.21) solid-solution ceramics were synthesized and their crystal structure, dielectric properties and piezoelectric properties were investigated. The crystal structure at room temperature of NNBTx varied from orthorhombic to tetragonal with increasing BaTiO3 content x. The phase boundary between orthorhombic and tetragonal at room temperature was confirmed BT content between x=0.08 and 0.09. For x>0.05, it was found that the Curie temperature was decreased with increasing x. The highest electromechanical coupling factor, kp, and the largest piezoelectric constant, d33, were obtained at x=0.09-0.10.

scholarly journals Dispersion of dielectric permittivity and magnetic properties of solid solution PZT–PFT

2015 ◽  
Vol 33 (3) ◽  
pp. 497-500 ◽  
Author(s):  
Ryszard Skulski ◽  
Przemysław Niemiec ◽  
Dariusz Bochenek ◽  
Artur Chrobak
Keyword(s):  
Phase Transition ◽  
Solid Solution ◽  
Magnetic Properties ◽  
Room Temperature ◽  
Magnetic Phase ◽  
Dielectric Dispersion ◽  
Antiferromagnetic Ordering ◽  
Mass Magnetization ◽  
Ceramic Samples ◽  
Temperature Dependences

Abstract In this paper we present the results of investigations into ceramic samples of solid solution (1-x)(PbZr0.53Ti0.47O3)- x(PbFe0.5Ta0.503) (i.e. (1-x)PZT-xPFT) with x = 0.25, 0.35 and 0.45. We try to find the relation between the character of dielectric dispersion at various temperatures and the composition of this solution. We also describe the magnetic properties of investigated samples. With increasing the content of PFT also mass magnetization and mass susceptibility increase (i.e. magnetic properties are more pronounced) at every temperature. The temperature dependences of mass magnetization and re­ciprocal of mass susceptibility have similar runs for all the compositions. However, our magnetic investigations exhibit weak antiferromagnetic ordering instead of the ferromagnetic one at room temperature. We can also say that up to room tempera­ture any magnetic phase transition has not occurred. It may be a result of the conditions of the technological process during producing our PZT-PFT ceramics.

Doping Strategies of Bi (Ti0.5Ni0.5)O3 for Increased Performance in BiFeO3

2014 ◽  
Vol 1004-1005 ◽  
pp. 358-361
Author(s):  
Zheng Zheng Ma ◽  
Jian Qing Li ◽  
Zi Peng Chen ◽  
Xiao Jun Hu
Keyword(s):  
Crystal Structure ◽  
Solid Solution ◽  
Magnetic Properties ◽  
Solid Solutions ◽  
Perovskite Structure ◽  
Room Temperature ◽  
Ferroelectric Properties ◽  
Hysteresis Loops ◽  
Space Group ◽  
Substituted 1

Investigation of crystal structure, dielectric, magnetic and local ferroelectric properties of the diamagnetically substituted (1-x)BiFeO3-xBi (Ti0.5Ni0.5)O3solid solutions samples have been carried out. The solid solutions have been found to possess a rhombohedrally distorted perovskite structure described by the space group R3c. Compared with pure BiFeO3compound, both ferroelectric and magnetic properties are much improved by solid solution with Bi (Ti0.5Ni0.5)O3with saturation hysteresis loops observed. Among all the samples, thex=0.1 samples shows the optimal ferromagnetism with Mr~0.56531emμ/g and the optimal ferroelectricity with Pr~5.767μC/cm2 at room temperature.

The Investigations of Dielectric Properties of BaTiO3 Thin Films on Polycrystalline Pt Substrates by Rf Magnetron Sputtering

1996 ◽  
Vol 433 ◽  
Author(s):  
Jin Wook Jang ◽  
Woon Jo Cho ◽  
Taek Sang Hahn ◽  
Sang Sam Choi ◽  
Su Jin Chung
Keyword(s):  
Thin Films ◽  
Dielectric Properties ◽  
Magnetron Sputtering ◽  
Film Thickness ◽  
Room Temperature ◽  
Strong Dependence ◽  
Hysteresis Loops ◽  
Rf Magnetron Sputtering ◽  
Thickness Dependence ◽  
Grain Sizes

AbstractThickness dependence of ferroelectric and structural properties of BaTiO3 thin films were investigated. Stoichiometric BaTiO3 thin films were prepared by off-axis rf magnetron sputtering on polycrystalline Pt substrates at 700°C. Film thickness range was 2,100–20,000Å. Room temperature permittivity, frequency dependence of permittivity, and D-E hysteresis loops were measured and lattice parameters were determined as a function of the film thickness. It has been found that these properties had the strong dependence on film thickness, which was mainly due to grain sizes of BaTiO3 thin films. The main cause of thickness dependence of dielectric properties was thought to be crystallinity and stresses of thin films which is resulted from changes in grain sizes.

scholarly journals The Properties of (Pb0.97Ba0.03)[(Zr0.98Ti0.02)1-zSnz]O3 Ceramics with 0 < z < 0.08

2013 ◽  
Vol 58 (4) ◽  
pp. 1377-1380
Author(s):  
D. Brzezińska ◽  
R. Skulski ◽  
P. Wawrzała ◽  
G. Dercz
Keyword(s):  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Barium Carbonate ◽  
Hysteresis Loops ◽  
Ceramic Technology ◽  
Dielectric Measurements ◽  
Ceramic Samples

Abstract We present the results of obtaining and investigations of (Pb1-x Bax )((Zr1-yTiy) 1-zSnz )O3 (PBZTS) ceramics with x =const =0.03, y =const=0.02, z =0, 0.02, 0.04, 0.06 and 0.08. Investigated compositions are close to rhombohedral-orthorhombic morphotropic phase boundary. Ceramic samples have been obtained by conventional ceramic technology from oxides PbO, ZrO2, TiO2, SnO2 and barium carbonate BaCO3. The calcined powders were crushed and next pressed into discs and sintered free sintering (FS) method. For such obtained samples the following investigations have been done: EDS, XRD, microstructure of fractured samples, dielectric measurements, /’-/^hysteresis loops investigations at various temperatures.

Dielectric characteristics of Fe-doped LaTiO3+δ and visible light modulation

RSC Advances ◽  
2016 ◽  
Vol 6 (103) ◽  
pp. 101571-101577 ◽  
Author(s):  
Yan Chen ◽  
Yimin Cui ◽  
Jun-en Yao
Keyword(s):  
Dielectric Properties ◽  
Visible Light ◽  
Room Temperature ◽  
Light Modulation ◽  
Frequency Range ◽  
Reaction Route ◽  
Dielectric Characteristics ◽  
Ceramic Samples ◽  
Solid State Reaction Route ◽  
Measured Frequency Range

Fe-doped La1−xFexTiO3+δ (x = 0.05, 0.1, and 0.3, 0.4) ceramic samples were prepared via traditional solid-state reaction route, in which the dielectric properties of visible light modulation were found at room temperature in the measured frequency range.

scholarly journals Technology, Physical Properties and Phase Transitions in PMN-PT-PS Ceramics

2011 ◽  
Vol 56 (4) ◽  
pp. 1051-1056 ◽  
Author(s):  
R. Skulski ◽  
D. Bochenek ◽  
P. Wawrzała
Keyword(s):  
Solid Solution ◽  
Phase Transitions ◽  
Dielectric Permittivity ◽  
Physical Properties ◽  
Ferroelectric Properties ◽  
Sol Gel ◽  
Hysteresis Loops ◽  
Gel Method ◽  
Sol Gel Method ◽  
Ceramic Samples

Technology, Physical Properties and Phase Transitions in PMN-PT-PS CeramicsSolid solution of (1-y)[(1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3]-yPbSnO3(PMN-PT-PS) investigated in this paper is based on (1-x)PMN-xPT (PMN-PT) where, with increasingx, the transition from relaxor to ferroelectric properties is observed depending on composition. PMN-PT ceramics with 0.25<x<0.4 has been obtained using sol-gel method and next mixed together with PS ceramics obtained from oxides. Final sintering of ceramic samples was pressureless. We present the results of microstructure and XRD investigations, dielectric permittivity and hysteresis loops measurements vs. temperature.

Preparation and Dielectric Properties of SiC-AlN Solid Solutions

2007 ◽  
Vol 280-283 ◽  
pp. 127-130 ◽  
Author(s):  
Xiang Yu Zhang ◽  
Shou Hong Tan ◽  
Wei-Wei Xu ◽  
Shao Ming Dong ◽  
Zheng Ren Huang ◽  
...  
Keyword(s):  
Solid Solution ◽  
Dielectric Properties ◽  
Solid Solutions ◽  
Room Temperature ◽  
Microwave Dielectric Properties ◽  
Microstructure Analysis ◽  
Dc Resistivity ◽  
Dielectric Losses ◽  
Homogeneous Solid Solution ◽  
Microwave Dielectric

The microstructure and microwave dielectric properties of inhomogeneous SiC-AlN solid solutions, hot pressed under a pressure of 40 MPa, have been investigated. Microstructure analysis detected the existence of BN in the resulted samples, which may be a reason that homogeneous solid solution was not formed for the samples with AlN content higher than 20%. The dc resistivity of the solid solutions at room temperature varies from 8 × 103 Ω m to 1 × 109 Ω m. Ion jump and dipole relaxation losses are the main mechanism of dielectric losses.

scholarly journals Preparation of Li3PS4–Li3PO4 Solid Electrolytes by Liquid-Phase Shaking for All-Solid-State Batteries

2021 ◽  
Vol 2 (1) ◽  
pp. 39-48
Author(s):  
Nguyen H. H. Phuc ◽  
Takaki Maeda ◽  
Tokoharu Yamamoto ◽  
Hiroyuki Muto ◽  
Atsunori Matsuda
Keyword(s):  
Solid Solution ◽  
Solid State ◽  
Liquid Phase ◽  
Room Temperature ◽  
Reaction Medium ◽  
Magic Angle Spinning ◽  
Resonance Spectroscopy ◽  
Synthesis Methods ◽  
Magic Angle ◽  
Angle Spinning

A solid solution of a 100Li3PS4·xLi3PO4 solid electrolyte was easily prepared by liquid-phase synthesis. Instead of the conventional solid-state synthesis methods, ethyl propionate was used as the reaction medium. The initial stage of the reaction among Li2S, P2S5 and Li3PO4 was proved by ultraviolet-visible spectroscopy. The powder X-ray diffraction (XRD) results showed that the solid solution was formed up to x = 6. At x = 20, XRD peaks of Li3PO4 were detected in the prepared sample after heat treatment at 170 °C. However, the samples obtained at room temperature showed no evidence of Li3PO4 remaining for x = 20. Solid phosphorus-31 magic angle spinning nuclear magnetic resonance spectroscopy results proved the formation of a POS33− unit in the sample with x = 6. Improvements of ionic conductivity at room temperature and activation energy were obtained with the formation of the solid solution. The sample with x = 6 exhibited a better stability against Li metal than that with x = 0. The all-solid-state half-cell employing the sample with x = 6 at the positive electrode exhibited a better charge–discharge capacity than that employing the sample with x = 0.

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