Characterizing the New Sphere Interferometer for the Diameter Determination of the Avogadro Spheres

2014 ◽  
Vol 613 ◽  
pp. 11-16
Author(s):  
Torsten Mai ◽  
Guido Bartl ◽  
Arnold Nicolaus ◽  
Andreas Peter
Keyword(s):  
Wave Front ◽  
Direct Access ◽  
Relative Uncertainty ◽  
Optical Fabrication ◽  
Volume Determination ◽  
Amount Of Substance ◽  
Fabrication Errors ◽  
Measurement Results ◽  
Better Than

For the aimed redefinition of the SI-unit kilogram the international Avogadro group is to measure the amount of substance of a silicon sphere with a relative uncertainty of better than 2 x 10-8. Up to now 3.0 x 10-8 is reached, mainly caused by the 2.7 x 10-8 uncertainty of the volume determination. Which itself is essentially affected by the uncertainty of wave front distortion caused by optical fabrication errors and possible misalignment. To gain more information on how the wave front distortion influences the result a new interferometer with improved optics and rather large changes in the etalon is built up. A comparison of the measurements of one sphere taken with two different interferometers gives direct access to this information. Additionally a ray tracing software is being developed to simulate the alignment and measurement processes. Following the alignment steps the resulting positioning uncertainties of each element can be simulated and elements which contribute mainly to the uncertainty can be identified. This gives evidence where an improvement of the alignment techniques is most effective and necessary. With the additional use of Monte Carlo method based calculations the influence on the measurement results can be determined.

Time and Latitude in South Africa

1972 ◽  
Vol 1 ◽  
pp. 27-38
Author(s):  
J. Hers
Keyword(s):  
South Africa ◽  
Cape Town ◽  
Astronomical Observations ◽  
Royal Observatory ◽  
The Republic ◽  
Astronomical Determination ◽  
Limited Accuracy ◽  
Better Than

In South Africa the modern outlook towards time may be said to have started in 1948. Both the two major observatories, The Royal Observatory in Cape Town and the Union Observatory (now known as the Republic Observatory) in Johannesburg had, of course, been involved in the astronomical determination of time almost from their inception, and the Johannesburg Observatory has been responsible for the official time of South Africa since 1908. However the pendulum clocks then in use could not be relied on to provide an accuracy better than about 1/10 second, which was of the same order as that of the astronomical observations. It is doubtful if much use was made of even this limited accuracy outside the two observatories, and although there may – occasionally have been a demand for more accurate time, it was certainly not voiced.

Phosphino-Triazole Ligands for Palladium-Catalysed Cross-Coupling

2018 ◽  
Author(s):  
Yiming Zhao ◽  
Huy van Nguyen ◽  
Louise Male ◽  
Philip Craven ◽  
Benjamin R. Buckley ◽  
...  
Keyword(s):  
Drug Discovery ◽  
Cross Coupling ◽  
Product Formation ◽  
Coupling Reactions ◽  
Volume Determination ◽  
Online Tool ◽  
Triazole Derivatives ◽  
Cross Coupling Reactions ◽  
Modelling Approaches

<div>Twelve 1,5-disubtituted and fourteen 5-substituted 1,2,3-triazole derivatives bearing diaryl or dialkyl phosphines at the 5-position were synthesised and used as ligands for palladium-catalysed Suzuki-Miyaura cross-coupling reactions. Bulky substrates were tested, and lead-like product formation was demonstrated. The online tool SambVca 2.0 was used to assess steric parameters of ligands and preliminary buried volume determination using XRD obtained data in a small number of cases proved to be informative. Two modelling approaches were compared for the determination of</div><div>the buried volume of ligands where XRD data was not available. An approach with imposed steric restrictions was found to be superior in leading to buried volume determinations that closely correlate with observed reaction conversions. The online tool LLAMA was used to determine lead-likeness of potential Suzuki-Miyaura cross-coupling products, from which ten of the most lead-like were successfully synthesised. Thus, confirming these readily accessible triazole-containing phosphines as highly suitable ligands for reaction screening and optimisation in drug discovery campaigns.</div>

Determination of trace concentrations of copper by FIA-FAAS after preconcentration on chelating sorbents

1989 ◽  
Vol 54 (7) ◽  
pp. 1785-1794 ◽  
Author(s):  
Vlastimil Kubáň ◽  
Josef Komárek ◽  
Zbyněk Zdráhal
Keyword(s):  
Sampling Frequency ◽  
Copper Determination ◽  
Flow Rates ◽  
Sample Injection ◽  
Injection Flow ◽  
Chelating Sorbents ◽  
Set Up ◽  
Trace Concentrations ◽  
Better Than

A FIA-FAAS apparatus containing a six-channel sorption equipment with five 3 x 26 mm microcolumns packed with Spheron Oxin 1 000, Ostsorb Oxin and Ostsorb DTTA was set up. Combined with sorption from 0.002M acetate buffer at pH 4.2 and desorption with 2M-HCl, copper can be determined at concentrations up to 100, 150 and 200 μg l-1, respectively. For sample and eluent flow rates of 5.0 and 4.0 ml min-1, respectively, and a sample injection time of 5 min, the limit of copper determination is LQ = 0.3 μg l-1, repeatability sr is better than 2% and recovery is R = 100 ± 2%. The enrichment factor is on the order of 102 and is a linear function of time (volume) of sample injection up to 5 min and of the sample injection flow rate up to 11 ml min-1 for Spheron Oxin 1 000 and Ostsorb DTTA. For times of sorption of 60 and 300 s, the sampling frequency is 70 and 35 samples/h, respectively. The parameters of the FIA-FAAS determination (acetylene-air flame) are comparable to or better than those achieved by ETA AAS. The method was applied to the determination of traces of copper in high-purity water.

scholarly journals A balanced-to-balanced directional coupler based on branch-slotline coupled structure

Frequenz ◽  
2020 ◽  
Vol 74 (11-12) ◽  
pp. 427-433
Author(s):  
Yaxin Liu ◽  
Feng Wei ◽  
Xiaowei Shi ◽  
Cao Zeng
Keyword(s):  
Directional Coupler ◽  
Return Loss ◽  
Design Method ◽  
Differential Mode ◽  
Arbitrary Power ◽  
Measurement Results ◽  
Transition Structures ◽  
Coupled Structures ◽  
Better Than ◽  
Good Agreement

AbstractIn this paper, a balanced-to-balanced (BTB) branch-slotline directional coupler (DC) is firstly presented, which can realize an arbitrary power division ratios (PDRs). The coupler is composed by microstrip-to-slotline (MS) transition structures and branch-slotline coupled structures. The single-ended to balanced-ended conversion is simplified and easy to implemented by the MS transition structures, which intrinsically leads to the differential-mode (DM) transmission and common-mode (CM) suppression. Moreover, the different PDRs which are controlled by the widths of branch-slotlines can be achieved. In order to verify the feasibility of the proposed design method, two prototype circuits of the proposed coupler with different PDRs are fabricated and measured. The return loss and the isolation of two designs are all better than 10 dB. Moreover, the CM suppressions are greater than 35 dB. A good agreement between the simulation and measurement results is observed.

scholarly journals Measuring the quartic Higgs self-coupling at a multi-TeV muon collider

2020 ◽  
Vol 2020 (9) ◽  
Author(s):  
M. Chiesa ◽  
F. Maltoni ◽  
L. Mantani ◽  
B. Mele ◽  
F. Piccinini ◽  
...  
Keyword(s):  
Higgs Boson ◽  
Center Of Mass ◽  
Mass Energy ◽  
Simple Analysis ◽  
Proton Proton ◽  
Coupling Interaction ◽  
Center Of Mass Energy ◽  
Muon Collider ◽  
Better Than

Abstract Measuring the shape of the Higgs boson potential is of paramount importance, and will be a challenging task at current as well as future colliders. While the expectations for the measurement of the trilinear Higgs self-coupling are rather promising, an accurate measurement of the quartic self-coupling interaction is presently considered extremely challenging even at a future 100 TeV proton-proton collider. In this work we explore the sensitivity that a muon collider with a center of mass energy in the multi-TeV range and luminosities of the order of 1035cm−2s−1, as presently under discussion, might provide, thanks to a rather large three Higgs-boson production and to a limited background. By performing a first and simple analysis, we find a clear indication that a muon collider could provide a determination of the quartic Higgs self-coupling that is significantly better than what is currently considered attainable at other future colliders.

scholarly journals Performance of the SoLid reactor neutrino detector

2019 ◽  
Vol 219 ◽  
pp. 08003
Author(s):  
Maja Verstraeten
Keyword(s):  
Quality Control ◽  
Energy Resolution ◽  
Neutrino Detector ◽  
Channel Response ◽  
In Situ Calibration ◽  
Reactor Neutrino ◽  
Li Isotope ◽  
Better Than

The SoLid Collaboration is currently operating a 1.6 ton neutrino detector near the Belgian BR2 reactor. Its main goal is the observation of the oscillation of electron antineutrinos to previously undetected flavour states. The highly segmented SoLid detector employs a compound scintillation technology based on PVT scintillator in combination with LiF-ZnS(Ag) screens containing the 6Li isotope. The experiment has demonstrated a channel-to-channel response that can be controlled to the level of a few percent, an energy resolution of better than 14% at 1 MeV, and a determination of the interaction vertex with a precision of 5 cm. This contribution highlights the major outcomes of the R&D program, the quality control during component manufacture and integration, the current performance and stability of the full-scale system, as well as the in-situ calibration of the detector with various radioactive sources.

scholarly journals The Application of Baum-Welch Algorithm in Multistep Attack

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Yanxue Zhang ◽  
Dongmei Zhao ◽  
Jinxing Liu
Keyword(s):  
Markov Model ◽  
Hidden Markov Model ◽  
Hidden Markov Models ◽  
Viterbi Algorithm ◽  
Markov Models ◽  
Hidden Markov ◽  
Simulation Experiments ◽  
Forward Algorithm ◽  
Better Than

The biggest difficulty of hidden Markov model applied to multistep attack is the determination of observations. Now the research of the determination of observations is still lacking, and it shows a certain degree of subjectivity. In this regard, we integrate the attack intentions and hidden Markov model (HMM) and support a method to forecasting multistep attack based on hidden Markov model. Firstly, we train the existing hidden Markov model(s) by the Baum-Welch algorithm of HMM. Then we recognize the alert belonging to attack scenarios with the Forward algorithm of HMM. Finally, we forecast the next possible attack sequence with the Viterbi algorithm of HMM. The results of simulation experiments show that the hidden Markov models which have been trained are better than the untrained in recognition and prediction.

scholarly journals Mass determination of the 1:3:5 near-resonant planets transiting GJ 9827 (K2-135)

2018 ◽  
Vol 618 ◽  
pp. A116 ◽  
Author(s):  
J. Prieto-Arranz ◽  
E. Palle ◽  
D. Gandolfi ◽  
O. Barragán ◽  
E. W. Guenther ◽  
...  
Keyword(s):  
Planetary System ◽  
Initial Conditions ◽  
Dynamical Evolution ◽  
Space Mission ◽  
Mass Determination ◽  
Velocity Measurements ◽  
Orbital Periods ◽  
The Masses ◽  
Better Than

Context. Multiplanet systems are excellent laboratories to test planet formation models as all planets are formed under the same initial conditions. In this context, systems transiting bright stars can play a key role, since planetary masses, radii, and bulk densities can be measured. Aims. GJ 9827 (K2-135) has recently been found to host a tightly packed system consisting of three transiting small planets whose orbital periods of 1.2, 3.6, and 6.2 days are near the 1:3:5 ratio. GJ 9827 hosts the nearest planetary system (~30 pc) detected by NASA’s Kepler or K2 space mission. Its brightness (V = 10.35 mag) makes the star an ideal target for detailed studies of the properties of its planets. Methods. Combining the K2 photometry with high-precision radial-velocity measurements gathered with the FIES, HARPS, and HARPS-N spectrographs we revised the system parameters and derive the masses of the three planets. Results. We find that GJ 9827 b has a mass of Mb = 3.69−0.46+0.48 M⊕ and a radius of Rb = 1.58−0.13+0.14 R⊕, yielding a mean density of ρb = 5.11−1.27+1.74 g cm−3. GJ 9827 c has a mass of Mc = 1.45−0.57+0.58 M⊕, radius of Rc = 1.24−0.11+0.11 R⊕, and a mean density of ρc = 4.13−1.77+2.31 g cm−3. For GJ 9827 d, we derive Md = 1.45−0.57+0.58 M⊕, Rd = 1.24−0.11+0.11 R⊕, and ρd = 1.51−0.53+0.71 g cm−3. Conclusions. GJ 9827 is one of the few known transiting planetary systems for which the masses of all planets have been determined with a precision better than 30%. This system is particularly interesting because all three planets are close to the limit between super-Earths and sub-Neptunes. The planetary bulk compositions are compatible with a scenario where all three planets formed with similar core and atmosphere compositions, and we speculate that while GJ 9827 b and GJ 9827 c lost their atmospheric envelopes, GJ 9827 d maintained its primordial atmosphere, owing to the much lower stellarirradiation. This makes GJ 9827 one of the very few systems where the dynamical evolution and the atmosphericescape can be studied in detail for all planets, helping us to understand how compact systems form and evolve.

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