The Influence of Modified Additives on Dynamic Properties of Polymeric Materials Based on Ethylene-Vinyl Acetate

2019 ◽  
Vol 945 ◽  
pp. 498-504
Author(s):  
A.N. Volotskoy ◽  
Yuriy V. Yurkin ◽  
V.D. Cherkasov ◽  
V.V. Avdonin

The article deals with the problem of creating vibration damping polymeric materials with high damping properties in a wide temperature range. The purpose of the article is to study physical-mechanical properties of composites based on ethylene-vinyl acetate by adding various modifiers in the form of resins. The main method to investigate this problem is the method of dynamic mechanical analysis, which makes possible to obtain viscoelastic properties of polymeric materials under the influence of an oscillating load at various temperatures and oscillation frequencies. Due to the established experimental dependencies, the authors have determined the type of resin, which improves the damping properties and increases the stiffness of the composites based on ethylene-vinyl acetate. Moreover, the authors have defined the limit of working capacity of composites with resins at negative temperatures.

2018 ◽  
Vol 55 (4) ◽  
pp. 469-473
Author(s):  
Yu. V. Yurkin ◽  
I. A. Mansurova ◽  
V. S. Belozerov ◽  
A. Zlobina

This work deals with the problem of developing vibration damping polymeric materials which are effective at low temperatures (from minus 40 to 0�C). Due to the fact that the vibration damping efficiency in the composite is mainly determined by the properties of the polymer matrix, it is necessary to study its properties depending on the type and amount of structure-forming parameters. The purpose of the work is to determine the changes in the dynamic properties of the polymer composition based on butyl rubber, EPDM, ethylene-vinyl acetate copolymer (EVA) filled with increasing amount of calcium carbonate. The leading methods of studying this problem were the method of scanning electron microscopy and the method of dynamic mechanical analysis. It has been stated that the selected polymers can be considered as competent candidates for damping materials at low temperatures, and the calcium carbonate filler allows more fully to realize the vibration damping properties of the polymer. The obtained dependences can be used as initial data for analytical predicting of damping properties of polymer composites.


Author(s):  
Алексей Волоцкой ◽  
Aleksey Volockoy ◽  
Юрий Юркин ◽  
Yuriy Yurkin ◽  
Василий Черкасов ◽  
...  

2020 ◽  
Vol 3 (2) ◽  
pp. 36-45 ◽  
Author(s):  
O. Tarasova ◽  
Yu. Yurkin ◽  
A. Toroschin

this work is devoted to the problem of developing vibration-damping polymer materials with high damping properties in a wide temperature range. The study of the effect of modifying additives on the strength, damping, adhesive and cohesive properties of a butyl rubber composite is the aim of this work. The task is to identify the actual temperature, frequency, dynamic and mechanical characteristics of a composite material based on butyl rubber depending on the type and concentration of resins. The key methods for studying this problem is the dynamic mechanical analysis method, aimed at obtaining information about changes in the dynamic properties of polymer materials (bond strength with metal when peeling samples of composites, determining the flow resistance of samples, determining the migration of plasticizer). Due to the established experimental dependences, it was found that the addition of resins (3% by weight) in the composition based on butyl rubber leads to an increase in the damping properties of composite materials, and an increase to (4.25% by weight) leads to their decrease. It was established that the obtained filled mixtures with a high damping peak and good adhesive and strength properties are mixtures with the addition of alkyl phenol-formaldehyde resins.


e-Polymers ◽  
2018 ◽  
Vol 18 (1) ◽  
pp. 67-73 ◽  
Author(s):  
Cong Meng ◽  
Jin-ping Qu

AbstractThe poly(butylene terephthalate) (PBT)/ethylene-vinyl acetate copolymer (EVA) blends with different contents of EVA were prepared by an vane extruder. From the observation of morphologies, impact strength and dynamic mechanical analysis (DMA), the EVA particles were well dispersed in the PBT matrix and improved the impact strength of PBT. Differential scanning calorimetry measurements demonstrate that there is little diversification in the crystal structure and type. Thermogravimetric analysis reveals that as the weight fraction of EVA increases, the thermal stability of composite is enhanced. The rheological analyses indicate that the PBT/EVA blends follow a non-Newtonian behavior and viscosities of the blends are drastically lower than that of pure PBT at higher frequencies. The storage modulus (G′) and loss modulus (G″) of the blends monotonously increase as the frequency rises. This work provides a novel method to develop blends with excellent performance.


2020 ◽  
Vol 57 (1) ◽  
pp. 69-79
Author(s):  
Alexey Volotskoy ◽  
Yuriy Yurkin ◽  
Valeriy Avdonin

This article is devoted to the problem of working out of damping polymer materials which are effective in the wide temperature and frequency range. In the modern world, work is being carried out to create damping polymer composite materials (DPM) from which it is possible to manufacture protective elements and parts of engineering structures of reduced vibration excitability. Existing DPM have a narrow temperature range, within which effective vibration absorption is observed, moreover, most of them go through a vulcanization stage, which increases the cost of the final product, has a harmful effect on environment and allows limited recycling of waste. One of the ways to solve this problem is to replace traditional rubber vibration-absorbing materials with thermo-elastoplasts (TEP). The most promising polymer for TEP is ethylene vinyl acetate (EVA), which has high damping properties, oil resistance and relative incombustibility. In this regard, experimental studies were conducted to establish the patterns of influence of the type and concentration of structure-forming components (plasticizers, fillers, modifiers) on the dynamic mechanical properties of TEP based on EVA in order to develop a new DPM effective in a wide temperature range. The leading method to investigate this problem is a method of dynamic mechanical analysis which allows to get information about changes of mechanical characteristics under mechanical load and controlled temperature and frequency. With the help of detected patterns it was possible to determine type of plasticizer which significantly decreases glass temperature of EVA. The percentage ratio of EVA/plasticizer system is stated, and the type of plasticizer at which the maximum of mechanical losses takes over greater values is accordingly detected. It is revealed, that to work out DPM on EVA basis, which are effective in wide temperature range it is more preferable to add not less than 40 % on volume basis inert fillers, such as talc or mica with addition of 5-10 % of carbon as the hardening additive. The kind of resin improving damping properties and raising rigidity of composites on EVA basis is defined. On the basis of the research, a material was developed which has the following properties: the maximum value of tan δ is at least 0.45 at a temperature of plus 5�C (oscillation frequency 10 Hz); width of the temperature interval within which tan δ is not less than 0.3 from minus 40 to plus 50�С (oscillation frequency 10 Hz); conditional tensile strength of not less than 10 kg/cm2, cold resistance up to minus 50�C.


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