CALCULATION OF HYDRAULIC CONDUCTIVITY DECREASES IN THE PRESENCE OF MIXED NaCl-CaCl2 SOLUTIONS

1978 ◽  
Vol 58 (2) ◽  
pp. 145-152 ◽  
Author(s):  
J. H. DANE
Keyword(s):  
Hydraulic Conductivity ◽  
Electrolyte Concentration ◽  
Solid Phase ◽  
Particle Density ◽  
Sodium Adsorption Ratio ◽  
Soil Porosity ◽  
Swelling Soils ◽  
Swelling Model ◽  
Good Agreement ◽  
Swelling Factor

A model was developed to calculate hydraulic conductivity decreases in swelling soils in the presence of mixed NaCl-CaCl2 solutions. A calculated swelling factor, based on a demixed-ion clay swelling model, was used to compute an effective soil porosity corresponding to each electrolyte solution. The procedure required knowledge of the total electrolyte concentration (C) and sodium adsorption ratio (SAR) of the solution phase, and of the fraction of expansible minerals, the bulk density, and the particle density of the solid phase. The calculated effective soil porosities were used to predict hydraulic conductivity values corresponding to solutions of decreasing C or increasing SAR values. A hydraulic conductivity value, corresponding to a solution which suppressed all swelling, had to be experimentally determined in order to make the prediction. Good agreement was found between predicted and experimental hydraulic conductivity values for two soils containing different amounts of expansible minerals and subjected to salt solutions of varying compositions.

Influence of sodium adsorption ratio on sodium and calcium breakthrough curves and hydraulic conductivity in soil columns

Soil Research ◽  
2007 ◽  
Vol 45 (8) ◽  
pp. 586 ◽  
Author(s):  
Oagile Dikinya ◽  
Christoph Hinz ◽  
Graham Aylmore
Keyword(s):  
Hydraulic Conductivity ◽  
Electrolyte Concentration ◽  
Soil Aggregates ◽  
Breakthrough Curves ◽  
Sodium Adsorption Ratio ◽  
Threshold Concentration ◽  
Critical Threshold ◽  
Soil Columns ◽  
Clay Particles ◽  
The Matrix

The paper examines the effects of electrolyte concentration and sodium adsorption ratio (SAR) on the relative saturated hydraulic conductivity (RHC) and the ionic behaviour of calcium (Ca) and sodium (Na) ions in the Na–Ca exchange complex. Batch binary exchange and saturated column transport experiments were carried out to quantify these effects using an agricultural Balkuling soil and a mining residue. Generally, RHC has been found to decrease with time, with increasing SAR, and with decreasing electrolyte concentration. The more rapid decrease in RHC in the mining residue, particularly at the lowest concentration (1 mmol/L), was consistent at all SAR values. The decreases in RHC were likely to be caused by partial blocking of pores by dispersed clay particles, as evidenced by the appearance of suspended clay particles in the effluent during leaching. Significant differences in RHC were observed in the passage of fronts of decreasing electrolyte concentrations for CaCl2 and SAR 15 solutions through the soil columns. These differences were attributable to structural alterations (slaking) of the media and the nature of the particles released and mobilised within the porous structure at any given point in the column. Measurements at the critical threshold concentration and turbidity concentration at SAR 15 revealed structural breakdown of the pore matrix system as evidenced by decreased RHC. The increase in SAR to 15 is initially accompanied by erratic RHC, presumably due to the break up of soil aggregates under the increased swelling forces. The less coherent mining residue soil was substantially more vulnerable to blockage of pores than the Balkuling soil in which clay particles are likely to be more readily mobilised, and hence available to re-deposit and occlude the matrix pores.

Hydraulic properties of a red-brown earth determined from in situ measurements

Soil Research ◽  
1978 ◽  
Vol 16 (2) ◽  
pp. 169 ◽  
Author(s):  
KA Olsson ◽  
CW Rose
Keyword(s):  
Hydraulic Conductivity ◽  
Hydraulic Properties ◽  
In Situ Measurements ◽  
Swelling Properties ◽  
Swelling Soils ◽  
Field Check ◽  
Measured Change ◽  
Water Contents ◽  
Good Agreement

Hydraulic conductivity characteristics are described for the soil profile of a red-brown earth exhibiting swelling properties. These were determined from in situ measurements of water content and suction during the redistribution of water following the irrigation of a non-vegetated field plot. Greater water contents were required for the same hydraulic conductivity in the subsoil than for the surface soil below cultivation depth. At a given suction, hydraulic conductivity was generally lower in the subsoil. In a field check on the theory of hydrostatics in swelling soils, values of the overburden potential (�) were derived from theory in terms of readily measurable parameters; these were shown to be in good agreement with values determined independently from the measured change in soil-water suction following the removal of overburden.

Use of gamma emission computed tomography to study the effect of electrolyte concentration on regions of preferred flow and hydraulic conductivity in deep regolith materials

Soil Research ◽  
2008 ◽  
Vol 46 (2) ◽  
pp. 101 ◽  
Author(s):  
M. L. Turner ◽  
R. S. B. Greene ◽  
M. Knackstedt ◽  
T. J. Senden ◽  
A. Sakellariou ◽  
...  
Keyword(s):  
Computed Tomography ◽  
Fluid Flow ◽  
Hydraulic Conductivity ◽  
Pore Structure ◽  
Electrolyte Concentration ◽  
Sodium Adsorption Ratio ◽  
Emission Computed Tomography ◽  
Saline Aquifer ◽  
Gamma Emission ◽  
Emission Computed

Understanding fluid flow, displacement, and mixing processes in natural porous media is fundamentally dependent upon the accurate characterisation of complex 3-dimensional structures. This current study delineated the distribution of conducting regions within a suite of regolith materials as they interacted with electrolyte solutions of different concentrations. Previous studies on the effects of electrolyte concentration on clay swelling and dispersion and the concomitant changes in pore structure, and hence soil permeability, have mainly been carried out on repacked samples of disturbed surface soils. This study used unconsolidated materials recovered as undisturbed cores from a saline aquifer from the deeper regolith (8.0–55.8 m). Progressive dilution of the electrolyte concentration of the percolating fluid (while maintaining a constant sodium adsorption ratio) was used to alter the pore structure of these saturated regolith materials. The electrolyte concentration was reduced from an initial value of 383 m.e./L (the original electrolyte concentration of the saline aquifer) to below the threshold concentration, and finally the cores were rinsed with deionised water. The corresponding changes to the regions conducting fluid and therefore pore structure, and the major fluid pathways followed during the percolation process, were imaged using gamma emission computed tomography. Five experimental core samples from depths of 8, 28, 30 (×2), and 55 m were used in the experiments. The average hydraulic conductivity was measured and found to decrease as a function of electrolyte concentration. The regions containing the major fluid pathways were found to decrease in volume as a function of electrolyte concentration. Clay mineralogy, sodium adsorption ratio, and grain size characteristics were found to be positively correlated with reductions in the average hydraulic conductivity. This method has the potential to aid in our understanding of the fundamental processes that govern the dynamics of pore structure changes and hence fluid flow in porous regolith materials, particularly in relation to changes in the electrolyte concentration and sodium adsorption ratio of the pore fluid. Such data will add significantly to our understanding of factors that affect the hydraulic properties of regolith materials under saline/sodic conditions.

scholarly journals Gamma-Ray Attenuation to Evaluate Soil Porosity: An Analysis of Methods

2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Luiz F. Pires ◽  
André B. Pereira
Keyword(s):  
Gamma Ray ◽  
Particle Density ◽  
Pore Space ◽  
Physical Property ◽  
Soil Bulk Density ◽  
Soil Porosity ◽  
Porous System ◽  
Soil Pore Space ◽  
Gamma Ray Attenuation ◽  
Dry Soil

Soil porosity (ϕ) is of a great deal for environmental studies due to the fact that water infiltrates and suffers redistribution in the soil pore space. Many physical and biochemical processes related to environmental quality occur in the soil porous system. Representative determinations ofϕare necessary due to the importance of this physical property in several fields of natural sciences. In the current work, two methods to evaluateϕwere analyzed by means of gamma-ray attenuation technique. The first method uses the soil attenuation approach through dry soil and saturated samples, whereas the second one utilizes the same approach but taking into account dry soil samples to assess soil bulk density and soil particle density to determineϕ. The results obtained point out a good correlation between both methods. However, whenϕis obtained through soil water content at saturation and a 4 mm collimator is used to collimate the gamma-ray beam the first method also shows good correlations with the traditional one.

Emission of molecular nitrogen at tight focusing of femtosecond laser pulses in air

2021 ◽  
pp. 42-48
Author(s):  
A.A. Ilyin ◽  
◽  
K.A. Shmirko ◽  
S.S. Golik ◽  
D.Yu. Proschenko ◽  
...  
Keyword(s):  
Particle Density ◽  
Molecular Nitrogen ◽  
Laser Pulses ◽  
Femtosecond Laser Pulses ◽  
Plasma Particle ◽  
Sharp Drop ◽  
Radiation Level ◽  
Femtosecond Radiation ◽  
Tight Focusing ◽  
Good Agreement

A numerical model describing the dynamics of plasma particle density upon filamentation of femtosecond radiation in the air is presented. The simulation results are in good agreement with the experimental data. The pumping processes of the N2 and N2+ radiative levels are investigated. The model predicts a sharp drop in electron temperature and density within 1 ns. For the first positive nitrogen system, an excess of the population of the upper radiation level over the population of the lower one is observed for 550 ps.

Impact of sulfate on the solubility of Tc(IV) in acidic to hyperalkaline aqueous reducing systems

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Sarah B. Duckworth ◽  
Xavier Gaona ◽  
Alexander Baumann ◽  
Kathy Dardenne ◽  
Jörg Rothe ◽  
...  
Keyword(s):  
Solid Phase ◽  
Correction Factors ◽  
Mixed Salt ◽  
Ph Values ◽  
Reducing Conditions ◽  
Upper Limits ◽  
Salt Systems ◽  
Amorphous Character ◽  
Good Agreement

Abstract The solubility of 99Tc(IV) was investigated from undersaturation conditions in NaCl–Na2SO4 (0.3 M ≤ I ≤ 5.0 M), MgCl2–MgSO4 (I = 13.5 M) and CaCl2–CaSO4 (I = 13.5 M) systems with 0.001 M ≤ [SO4 2−]tot ≤ 1.0 M and 1 ≤ pH m  ≤ 12 (with pH m  = −log[H+], in molal units). Reducing conditions were set by either Sn(II) or Fe(0). Special efforts were dedicated to accurately characterize the correction factors A m required for the determination of pH m from the experimentally measured pH values in the mixed salt systems investigated, with pH m  = pHexp + A m . The combination of (pe + pH m ) measurements with Pourbaix diagrams of Tc suggests that technetium is present in its +IV redox state. This hypothesis is confirmed by XANES, which unambiguously shows the predominance of Tc(IV) both in the aqueous and solid phases of selected solubility samples. XRD and SEM–EDS support the amorphous character of the solid phase controlling the solubility of Tc(IV). EXAFS data confirm the predominance of TcO2(am, hyd) at pH m  > 1.5, whereas the formation of a Tc(IV)–O–Cl solid phase is hinted at lower pHm values in concentrated NaCl–Na2SO4 systems with ≈5 M NaCl. Solubility data collected in sulfate-containing systems are generally in good agreement with previous solubility studies conducted in sulfate-free NaCl, MgCl2 and CaCl2 solutions of analogous ionic strength. Although the complexation of Tc(IV) with sulfate cannot be completely ruled out, these results strongly support that, if occurring, complexation must be weak and has no significant impact on the solubility of Tc(IV) in dilute up to highly saline media. Solubility upper-limits determined in this work can be used for source term estimations including the effect of sulfate in a variety of geochemical conditions relevant in the context of nuclear waste disposal.

scholarly journals Thermal conductivity of unsaturated clay-rocks

2010 ◽  
Vol 14 (1) ◽  
pp. 91-98 ◽  
Author(s):  
D. Jougnot ◽  
A. Revil
Keyword(s):  
Thermal Conductivity ◽  
Porous Material ◽  
Solid Phase ◽  
Model Parameters ◽  
Electrical Parameters ◽  
New Model ◽  
Unsaturated Clay ◽  
Unsaturated Porous Material ◽  
Clay Rocks ◽  
Good Agreement

Abstract. The parameters used to describe the electrical conductivity of a porous material can be used to describe also its thermal conductivity. A new relationship is developed to connect the thermal conductivity of an unsaturated porous material to the thermal conductivity of the different phases of the composite, and two electrical parameters called the first and second Archie's exponents. A good agreement is obtained between the new model and thermal conductivity measurements performed using packs of glass beads and core samples of the Callovo-Oxfordian clay-rocks at different saturations of the water phase. We showed that the three model parameters optimised to fit the new model against experimental data (namely the thermal conductivity of the solid phase and the two Archie's exponents) are consistent with independent estimates. We also observed that the anisotropy of the effective thermal conductivity of the Callovo-Oxfordian clay-rock was mainly due to the anisotropy of the thermal conductivity of the solid phase.

Influence of Temperature on Hydraulic Conductivity in Compacted Bentonite

1997 ◽  
Vol 506 ◽  
Author(s):  
W. J. Cho ◽  
J. O. Lee ◽  
K. S. Chun
Keyword(s):  
Hydraulic Conductivity ◽  
Influence Of Temperature ◽  
Temperature Range ◽  
Compacted Bentonite ◽  
Influence Of Temperature On ◽  
Water Saturated ◽  
Increasing Temperature ◽  
Good Agreement

ABSTRACTThe hydraulic conductivities in water saturated bentonites at different densities were measured within temperature range of 20 to 80 °C. The results show that the hydraulic conductivities increase with increasing temperature. The hydraulic conductivities of bentonites at the temperature of 80 °C increase up to about 3 times as high as those at 20 °C. The measured values are in good agreement with those predicted. The change in viscosity of water with temperature contributes greatly to increase of hydraulic conductivity.

scholarly journals Gas hold-up in a three-phase reciprocating plate column

2005 ◽  
Vol 70 (11) ◽  
pp. 1363-1371 ◽  
Author(s):  
Ljubisa Nikolic ◽  
Vesna Nikolic ◽  
Vlada Veljkovic ◽  
Dejan Skala
Keyword(s):  
Solid Phase ◽  
Liquid System ◽  
Column Diameter ◽  
Gas Velocity ◽  
Vibration Intensity ◽  
Three Phase ◽  
Superficial Gas Velocity ◽  
Phase Column ◽  
Plate Column ◽  
Good Agreement

The influence of the geometry of a reciprocating plate column (diameter), superficial gas velocity, vibration intensity and content of the solid phase in the column on the gas hold-up in a three phase column (G-L-S) were investigated in this study. For comparison, the gas hold-up was also analyzed in a gas-liquid system (G-L) in the same type of column. Good agreement between the experimentally determined values of the gas hold-up and those calculated on the basis of the derived correlation for the G-L and G-L-S system was obtained.

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