POTASSIUM EXCHANGE CHARACTERISTICS IN RELATION TO MINERALOGICAL PROPERTIES AND POTASSIUM UPTAKE BY GRAPES OF SELECTED SOILS IN THE NIAGARA PENINSULA OF SOUTHERN ONTARIO

1984 ◽  
Vol 64 (1) ◽  
pp. 87-98 ◽  
Author(s):  
G. J. ROSS ◽  
R. A. CLINE

Potassium deficiency in grapes, as well as in other fruit crops grown on soils in the Niagara peninsula, is a common and often serious problem. Ap horizon samples from 12 of these soils and grape petiole samples from nine of the soil locations were analyzed to elucidate the behavior of the soil K and its availability to grapes. The soils ranged in texture from sandy loam to silty clay and their clay mineralogy was relatively uniform with mica as the main layer silicate. Vermiculite was quantified by potential K fixation methods and was concentrated in the clay. Up to 5.8% vermiculite was present in the soils which seemed to be sufficient to reduce K availability by K fixation. Amounts of exchangeable K extracted with NaCl or NH4Cl were relatively high (0.46–2.09 meq/100 g) but were not correlated with K uptake by grapes. Energies of K exchange obtained from immiscibly displaced soil solutions were closely related to vermiculite contents and amounts of K fixed after air drying. Energies of K exchange and ratios of exchangeable K over exchangeable Ca + Mg were highly correlated with K uptake by grapes. Soils with energies of K exchange less than or equal to −2800 cal/equiv. or K exch./(Ca + Mg) exch. equal to or more than 7% appeared to have adequate amounts of available K for grapes. These two analyses therefore show promise for predicting K availability to grapes. Key words: Exchangeability of K, energy of K exchange, fixation of K, soil mineralogy, availability of K to grapes

1992 ◽  
Vol 6 (3) ◽  
pp. 583-586 ◽  
Author(s):  
John S. Wilson ◽  
Chester L. Foy

The soil organic matter and/or humic matter fraction was highly correlated with the adsorption of ICIA-0051 herbicide onto five soils; clay content and other soil factors were less correlated. The Freundlich equation was used to describe the adsorption of ICIA-0051 by the various soils. Based on the K constants, the general order for adsorption for each soil was Hyde silty clay loam > Frederick silt loam > Davidson clay = Bojac sandy loam > Appling loamy sand. Across all soils, 25 to 50% of the amount adsorbed was removed by two desorptions. Appling, Bojac, and Davidson soils retained less herbicide after two desorptions than did Frederick and Hyde.


1966 ◽  
Vol 46 (1) ◽  
pp. 23-28 ◽  
Author(s):  
D. K. Acquaye ◽  
A. J. MacLean

Ammonium applied alone or after addition of K depressed the uptake of K by oats grown in a sandy loam soil in the greenhouse. When NH4 was added first and K later at seeding, however, NH4 increased K-uptake.In the absence of K fertilizer, NH4 reduced the release of non-exchangeable K to the plants. When added prior to or at the same time as K at seeding, NH4 reduced K-fixation. This inhibitory effect of NH4 on fixation of added K was reflected in higher amounts of K in solution as shown by lower [Formula: see text] ratios. These results of chemical extraction of the soil indicated that the effects of NH4 on K-uptake by the oat crop arose from reactions in the soil.


1989 ◽  
Vol 69 (3) ◽  
pp. 649-661 ◽  
Author(s):  
G. J. Ross ◽  
DONALD S. GAMBLE ◽  
R. A. CLINE

Long-term (8 yr) K+ fertilization experiments were started in 1983 on Jeddo clay loam, Smithville silt loam, Oneida loam, and Vineland sandy loam in the Niagara region of southern Ontario to study K+ exchange and fixation in relation to K+ uptake by grapes. Potassium fertilization at rates of 0, 100, 200, 400, and 600 kg K+ ha−1 was discontinued after 4 yr to record the build-up of soil K+ with fertilization and its decline after fertilization ceased. This paper reports the results on K+ exchange and fixation during the 4-yr K+ fertilization period. The clay mineralogy of the soils was similar with their clays containing mainly mica and smaller amounts of vermiculite, chlorite, quartz, and feldspars. There was a highly significant linear relationship between rates of applied K+ and K+ fractions of exchangeable cations for every soil in every year of K+ application. Exchangeable K+ concentrations in the coarse-textured Vineland soil increased sharply from the first to the second year of K+ application. However, there was no consistent increase of exchangeable K+ concentrations with time in the finer-textured soils for the first 2-4 years of K+ application. This was attributed mainly to K+ fixation. This interpretation was supported by chemical and X-ray evidence that showed reduced K+ fixation capacity and transformation of vermiculite to a mica-like mineral at the high rate of K+ application. Potassium exchange equilibria and standard Gibbs free energies for the exchange of (Ca2+ + Mg2+) by K+ were calculated using the theory of multiple ion exchange equilibria. Standard Gibbs free energy values for this exchange became more negative with increase in clay and vermiculite contents of the soils which was attributed to the strong adsorption of K+ in vermiculite and vermiculite-like minerals that were concentrated in the clay fraction. Clay content is therefore the dominant factor determining K+ exchangeability in the soils of the Niagara region of southern Ontario. Key words: soil mineralogy, vermiculite contents, potassium exchange equilibria, standard Gibbs free energy


Soil Research ◽  
2006 ◽  
Vol 44 (3) ◽  
pp. 265 ◽  
Author(s):  
P. W. Moody ◽  
M. J. Bell

Thirty-seven surface (0–0.10 or 0–0.20 m) soils covering a wide range of soil types (16 Vertosols, 6 Ferrosols, 6 Dermosols, 4 Hydrosols, 2 Kandosols, 1 Sodosol, 1 Rudosol, and 1 Chromosol) were exhaustively cropped in 2 glasshouse experiments. The test species were Panicum maximum cv. Green Panic in Experiment A and Avena sativa cv. Barcoo in Experiment B. Successive forage harvests were taken until the plants could no longer grow in most soils because of severe potassium (K) deficiency. Soil samples were taken prior to cropping and after the final harvest in both experiments, and also after the initial harvest in Experiment B. Samples were analysed for solution K, exchangeable K (Exch K), tetraphenyl borate extractable K for extraction periods of 15 min (TBK15) and 60 min (TBK60), and boiling nitric acid extractable K (Nitric K). Inter-correlations between the initial levels of the various soil K parameters indicated that the following pools were in sequential equilibrium: solution K, Exch K, fast release fixed K [estimated as (TBK15 – Exch K)], and slow release fixed K [estimated as (TBK60 – TBK15)]. Structural K [estimated as (Nitric K – TBK60)] was not correlated with any of the other pools. However, following exhaustive drawdown of soil K by cropping, structural K became correlated with solution K, suggesting dissolution of K minerals when solution K was low. The change in the various K pools following cropping was correlated with K uptake at Harvest 1 (Experiment B only) and cumulative K uptake (both experiments). The change in Exch K for 30 soils was linearly related to cumulative K uptake (r = 0.98), although on average, K uptake was 35% higher than the change in Exch K. For the remaining 7 soils, K uptake considerably exceeded the change in Exch K. However, the changes in TBK15 and TBK60 were both highly linearly correlated with K uptake across all soils (r = 0.95 and 0.98, respectively). The slopes of the regression lines were not significantly different from unity, and the y-axis intercepts were very small. These results indicate that the plant is removing K from the TBK pool. Although the change in Exch K did not consistently equate with K uptake across all soils, initial Exch K was highly correlated with K uptake (r = 0.99) if one Vertosol was omitted. Exchangeable K is therefore a satisfactory diagnostic indicator of soil K status for the current crop. However, the change in Exch K following K uptake is soil-dependent, and many soils with large amounts of TBK relative to Exch K were able to buffer changes in Exch K. These soils tended to be Vertosols occurring on floodplains. In contrast, 5 soils (a Dermosol, a Rudosol, a Kandosol, and 2 Hydrosols) with large amounts of TBK did not buffer decreases in Exch K caused by K uptake, indicating that the TBK pool in these soils was unavailable to plants under the conditions of these experiments. It is likely that K fertiliser recommendations will need to take account of whether the soil has TBK reserves, and the availability of these reserves, when deciding rates required to raise exchangeable K status to adequate levels.


Agronomy ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 128
Author(s):  
Ruihuan She ◽  
Yongxiang Yu ◽  
Chaorong Ge ◽  
Huaiying Yao

Soil salinization typically inhibits the ability of decomposer organisms to utilize soil organic matter, and an increase in soil clay content can mediate the negative effect of salinity on carbon (C) mineralization. However, the interactive effects of soil salt concentrations and properties on C mineralization remain uncertain. In this study, a laboratory experiment was performed to investigate the interactive effects of soil salt content (0.1%, 0.3%, 0.6% and 1.0%) and texture (sandy loam, sandy clay loam and silty clay soil with 6.0%, 23.9% and 40.6% clay content, respectively) on C mineralization and microbial community composition after cotton straw addition. With increasing soil salinity, carbon dioxide (CO2) emissions from the three soils decreased, but the effect of soil salinity on the decomposition of soil organic carbon varied with soil texture. Cumulative CO2 emissions in the coarse-textured (sandy loam and sandy clay loam) soils were more affected by salinity than those in the fine-textured (silty clay) soil. This difference was probably due to the differing responses of labile and resistant organic compounds to salinity across different soil texture. Increased salinity decreased the decomposition of the stable C pool in the coarse-textured soil, by reducing the proportion of fungi to bacteria, whereas it decreased the mineralization of the active C pool in the fine-textured soil through decreasing the Gram-positive bacterial population. Overall, our results suggest that soil texture controlled the negative effect of salinity on C mineralization through regulating the soil microbial community composition.


1988 ◽  
Vol 110 (1) ◽  
pp. 119-140 ◽  
Author(s):  
G. N. Thorne ◽  
P. J. Welbank ◽  
F. V. Widdowson ◽  
A. Penny ◽  
A. D. Todd ◽  
...  

SummaryWinter wheat grown following potatoes on a sandy loam at Woburn in 1978–9, 1980–1 and 1981–2 was compared with that on a clay loam at Rothamsted in 1978–9 and 1980–1, and on a silty clay (alluvium) at Woburn in 1981–2. The cultivar was Hustler in the harvest years 1979 and 1981 and Avalon in 1982. On each soil in each year multifactorial experiments tested effects of combinations of six factors, each at two levels.The best 4-plot mean grain yield ranged from 89 to 11·1 t/ha during the 3 years; it was smaller on the sandy soil than on the clay soil in 1979, but larger on sand than on the clay in 1981 and 1982. Until anthesis the number of shoots, dry weight and N content of the wheat giving these best yields were less on sand than on clay. Unlike grain weight, straw weight was always less on sand.Sowing in mid-September instead of mid-October increased grain yield on clay in each year (by 0·4·0·7 t/ha) and increased yield on sand only in 1981 (by 1·6 t/ha). Early sowing always increased dry weight, leaf area, number of shoots and N uptake until May. The benefits were always greater on clay than on sand immediately before N fertilizer was applied in the spring and usually lessened later on both soils.Aldicarb as an autumn pesticide increased grain yield of early-sown wheat on both soils in 1981 by lessening infection with barley yellow dwarf virus. Aldicarb increased yield on clay in 1982; it also decreased the number of plant parasitic nematodes.Wheat on sand was more responsive to nitrogen in division, timing and amount than was wheat on clay. In 1979 yield of wheat on sand was increased by dividing spring N between March, April and May, instead of giving it all in April, and in 1982 by giving winter N early in February. In 1981 division and timing on sand interacted with sowing date. Yield of early-sown wheat given N late, i.e. in March, April and May, exceeded that given N early, i.e. in February, March and May, by 1·4 t/ha; single dressings given all in March or all in April also yielded less than the late divided dressing. Yield of later-sown wheat given all the N in April was at least 1·2 t/ha less than with all N given in March or with divided N. In all years treatments that increased yield usually also increased N uptake. Grain yield on clay was never affected by division or timing of spring N or by application of winter N. This was despite the fact that all treatments that involved a delay in the application of N depressed growth and N uptake in spring on both sand and clay. The mean advantage in N uptake following early application of spring N eventually reversed on both soils, so that uptake at maturity was greater from late than from early application. Increasing the amount of N given in spring from the estimated requirement for 9 t/ha grain yield to that for 12 t/ha increased yield in 1982, especially on sand. The larger amount of N always increased the number of ears but often decreased the number of grains per ear and the size of individual grains.Irrigation increased grain yield only on the sandy soil, by 1·1 t/ha in 1979 and by 07 t/ha in 1981 and 1982. The component responsible was dry weight per grain in 1979 and 1982, when soil moisture deficits reaching maximum values of 136 and 110 mm respectively in the 2 years developed after anthesis; the component responsible was number of ears/m2 in 1982 when the maximum deficit of 76 mm occurred earlier, in late May.


2021 ◽  
Vol 26 (51) ◽  
pp. 27-32
Author(s):  
Biljana Sikirić ◽  
Vesna Mrvić ◽  
Olivera Stajković-Srbinović ◽  
Vladan Ugrenović ◽  
Darko Jaramaz ◽  
...  

During the regular control of soil fertility in the Rasina District, it was established that the plots of land were distributed across Vertisol, Eutric Cambisol and Fluvisol types of soils, and to a lesser extent on Pseudogley and Ranker. The tested samples had different textures - sandy loam and loam, clay-sandy loam and clay loam, and clay. Plots of land that were of very acidic and acidic reactions were predominant, with medium amounts of humus, very low amounts of available phosphorus, and high amounts of available potassium. High or very high cation absorption capacity was found in about half of the examined fields; a deficient content of exchangeable Ca was recorded in 22% of plots and that of exchangeable Mg in 16% of plots, while an unfavorable Ca/Mg ratio was measured in 44% of plots. The overall sensitivity to acidification was mainly moderate (50.6% of plots) and strong (20.2% of plots). Very high concentrations of mobile Al, which could be toxic to plants, were found in 5 field plots.


2009 ◽  
Vol 6 (6) ◽  
pp. 7247-7285 ◽  
Author(s):  
N. P. Peranginangin ◽  
B. K. Richards ◽  
T. S. Steenhuis

Abstract. Accurate soil water sampling is needed for monitoring of pesticide leaching through the vadose zone, especially in soils with significant preferential flowpaths. We assessed the effectiveness of wick and gravity pan lysimeters as well as ceramic cups (installed 45–60 cm deep) in strongly-structured silty clay loam (Hudson series) and weakly-structured fine sandy loam (Arkport series) soils. Simulated rainfall (10–14 cm in 4 d, approximately equal to a 10-yr, 24 h storm) was applied following concurrent application of agronomic rates (0.2 g m−2) of atrazine (6-chloro-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine) and 2,4-D (2,4-dichloro-phenoxy-acetic acid) immediately following application of a chloride tracer (22–44 g m−2). Preferential flow mechanisms were observed in both soils, with herbicide and tracer mobility greater than would be predicted by uniform flow. Preferential flow was more dominant in the Hudson soil, with earlier breakthroughs observed. Mean wick and gravity pan sampler percolate concentrations at 60 cm depth ranged from 96 to 223 μg L−1 for atrazine and 54 to 78 μg L−1 for 2,4-D at the Hudson site, and from 7 to 22 μg L−1 for atrazine and 0.5 to 2.8 μg L−1 for 2,4-D at the Arkport site. Gravity and wick pan lysimeters had comparably good collection efficiencies at elevated soil moisture levels, whereas wick pan samplers performed better at lower moisture contents. Cup samplers performed poorly with wide variations in collections and solute concentrations.


Soil Research ◽  
1999 ◽  
Vol 37 (4) ◽  
pp. 695 ◽  
Author(s):  
Y. Pal ◽  
R. J. Gilkes ◽  
M. T. F. Wong

This investigation was undertaken to determine the potassium (K) status and adsorption behaviour of 227 samples from horizons of 41 representative virgin soil profiles, extending from Geraldton in the north to the Great Southern district of Western Australia. X-ray diffraction analysis of random powder of whole soil indicated that quartz is the dominant mineral and some soils contain significant amounts of feldspars. Clay mineralogy is dominated by kaolinite but minor quantities of illite are present in some soils. Most south-west Australian agricultural soils contain little available K: NaHCO3-extractable K (NaHCO3-K, median value 0·09 cmol K/kg, equivalent to 35 mg K/kg soil), HNO3-extractable K (HNO3-K, median value 0·30 cmol K/kg, equivalent to 117 mg K/kg soil), and total K (XRF determined K, median value, 17 cmol K/kg, equivalent to 6630 mg K/kg soil). The proportion of water-soluble K (H2O-K) ranges from 0 to 3·5% of total K, 0 to 76% of HNO3-K, and 0 to nearly 100% of exchangeable K. Exchangeable K ranges from 0 to 100% (median value 37%) of HNO3-K. These are relatively high proportions of H2O-K and exchangeable K compared with soils from many other parts of the world. The amounts of all forms of K variously increase or decrease downwards in the soil profile depending on both clay content and mineralogy. The commonly assumed increase in K with clay content alone is invalid. The soils mostly have low-to-moderate values of K sorption capacity, ranging from 5% to 67% (median value 14%) of added K (initially 4·1 mM K/L, equivalent to 4·1 cmol K/kg). otassium sorption isotherms conform well to the Freundlich equation. The inability of the Langmuir equation to describe the data may indicate that there are several types of K sorption sites in these soils. The Gapon coefficient KG varied widely from 0·04 to 29·8 (L/mol) ½ [median value 5·4 (L/mol) ½ ].


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