EVALUATION OF SOIL EXTRACTANTS FOR THE PREDICTION OF PLANT-AVAILABLE POTASSIUM IN ONTARIO SOILS

1990 ◽  
Vol 70 (4) ◽  
pp. 607-615 ◽  
Author(s):  
LIANGXUE LIU ◽  
THOMAS E. BATES

The effectiveness of five extractants, NaCl, AB-DTPA, NH4OAc, Mehlich 3 and HNO3 was evaluated on 72 Ontario soils for prediction of plant-available K to alfalfa (Medicago sativa L.) grown in a greenhouse. Total K uptake by four cuts of alfalfa was used to measure plant available soil K. The average amounts of K extracted were in ascending order: AB-DTPA < NaCl < = NH4OAc < Mehlich 3 < HNO3. The highest simple correlation with K uptake by alfalfa was obtained with HNO3 (r = 0.76) and the lowest with NaCl (r2 = 0.61). The K uptake by alfalfa was used as the dependent variable to develop predictive models using stepwise regression, with extractable soil K, exchangeable Mg and Ca, soil pH, organic matter, cation exchange capacity (CEC), and contents of silt and clay as independent variables. The best prediction of K uptake with extracted soil K and its square was AB-DTPA (R2 = 0.84), followed by HNO3 (0.81), NH4OAc (0.81), NaCl (0.78) and Mehlich 3 (0.77). Inclusion of soil properties improved the effectiveness of prediction. The models developed with the different extractants differ in the number of variables which contributed significantly at 5% probability. Based on the final R2 and ease of measurement of variables, the NH4OAc model is one of the best as a predictor of availability of K in Ontario soils when used along with other soil properties such as plant-available nonexchangeable K and soil organic matter. Key words: Potassium extractants, plant-available K, alfalfa

1969 ◽  
Vol 53 (4) ◽  
pp. 369-373
Author(s):  
M. A. Lugo-López ◽  
Raúl Pérez-Escolar

A study is herein reported where attempts to explain the variability in the cation exchange capacity of Lajas Valley soils in terms of other soil properties were made. The independent variables considered were percentage of particles smaller than 0.002 mm., percentage of organic matter, and the summation of the percentage of particles ranging from 0.05 to 0.002 mm. and smaller than 0.002 mm. The correlation coefficients obtained were 0.44, 0.47 and 0.46 for each respective attempt. Only 19 percent of the variability in cation exchange capacity could be explained on the basis of the percentage of particles smaller than 0.002 mm. in size. Another simple correlation where the percentage of particles between 0.05 mm. and 0.002 mm. was added to the percentage of particles smaller than 0.002 failed to explain satisfactorily any significant additional variability. A multiple correlation including the percentage of organic matter, in addition to the percentage of particles smaller than 0.002 mm. also failed to explain any significant additional variability. This failure is analyzed in view of the different nature of montmorillonitic clays that predominate in Lajas Valley soils.


2008 ◽  
Vol 53 (No. 5) ◽  
pp. 225-238 ◽  
Author(s):  
N. Finžgar ◽  
P. Tlustoš ◽  
D. Leštan

Sequential extractions, metal uptake by <i>Taraxacum officinale</i>, Ruby&rsquo;s physiologically based extraction test (PBET) and toxicity characteristic leaching procedure (TCLP), were used to assess the risk of Pb and Zn in contaminated soils, and to determine relationships among soil characteristics, heavy metals soil fractionation, bioavailability and leachability. Regression analysis using linear and 2nd order polynomial models indicated relationships between Pb and Zn contamination and soil properties, although of small significance (<i>P</i> < 0.05). Statistically highly significant correlations (<i>P</i> < 0.001) were obtained using multiple regression analysis. A correlation between soil cation exchange capacity (CEC) and soil organic matter and clay content was expected. The proportion of Pb in the PBET intestinal phase correlated with total soil Pb and Pb bound to soil oxides and the organic matter fraction. The leachable Pb, extracted with TCLP, correlated with the Pb bound to carbonates and soil organic matter content (<i>R</i><sup>2</sup> = 69%). No highly significant correlations (<i>P</i> < 0.001) for Zn with soil properties or Zn fractionation were obtained using multiple regression.


1992 ◽  
Vol 72 (2) ◽  
pp. 159-167 ◽  
Author(s):  
Liangxue Liu ◽  
T. E. Bates ◽  
T. S. Tran

The extractions of soil K by electroultrafiltration (EUF) and by chemical methods were compared as predictors of plant-available K for greenhouse-grown alfalfa on 38 Ontario soils. The relation of soil properties to the amount of K extracted by EUF fractions was also examined. The contents of silt and clay were negatively correlated with EUF-K at 50 V and 22 °C and positively correlated with EUF-K at 400 V and 80 °C. Soil pH and organic matter were not significantly correlated with the amounts of K extracted in the EUF-K fractions. The EUF extraction of K was influenced by the presence of carbonate or high exchangeable calcium in soils. Similar correlations were obtained between K uptake and K extracted by chemical methods and the sum of EUF-K fractions. When used along with other soil properties, EUF-K fractions and K extracted by chemical methods predicted availability of soil K with roughly equal ability. The model using the sum of K extracted by EUF at 50, 200 and 400 V is the simplest one and contains three variables, K, K2 and Ca2. The use of EUF is limited due to cost of equipment and time required for analysis, unless a number of nutrients can be accurately determined on one extract. Among the chemical methods, equations developed using three nonacidic extradants, NaCl, ABDTPA and NH4OAc explained more variation in K uptake than two acidic extractants, Mehlich 3 and 0.1 M HNO3. The NaCl model, ABDTPA model and NH4OAc model contained the same variables and had similar R2 values (0.88–0.91). Key words: Available K, chemical methods, electro-ultrafiltration, EUF-K fractions, K uptake


Soil Research ◽  
2018 ◽  
Vol 56 (4) ◽  
pp. 396 ◽  
Author(s):  
Thilo Rennert

The presence of geogenic CO2 has been recently identified as a soil-forming factor in soil on mofette sites. Topsoil samples (with a maximum CO2 concentration of 52% at 10 cm depth) were studied along a transect on a mofette site in the NW Czech Republic to further understand the processes within soil and the soil properties induced by CO2 in the soil atmosphere. Geogenic CO2 negatively affected the cation exchange capacity, the ratio of exchangeable Ca and Mg, and the total contents of Al, Mg and Mn. No effect was detected on a chemical index of weathering and the mineralogical composition of the clay fractions, which might be explained by the acidic parent material and the progress of soil development. Diffuse reflectance infrared spectroscopy indicated that the composition of particulate soil organic matter was partially affected by CO2 concentrations: the higher the CO2 concentrations, the smaller the extent of oxidative transformation and the smaller the abundance of carboxyl groups. In the clay fractions, stabilisation of transformed soil organic matter (SOM) was promoted by exchangeable Al. This study quantifies, for the first time, the correlation between geogenic CO2 and several inorganic soil properties and the composition of SOM in physical fractions.


CORD ◽  
1988 ◽  
Vol 4 (01) ◽  
pp. 34
Author(s):  
Doah Dekok Tarigans

This study was conducted to investigate the effects of six co­conut cropping patterns on the soil properties and nutrient element status of coconut leaves. The experiments were carried out from August 1984 to May 1985 in Silang, Cavite, Philippines. Data on‑soil properties and nutrient element starus of coconut leaves were statistically analyzed in Randomized Block Design with three replications. Six cropping patterns in coconut with four species of perennial crops as intercrops, namely: banana, papaya, coffee and pineapple were used in this study. The organic matter, pH and cation exchange capacity of the soils did not differ significantly with cropping pattern although intensively cropped farms tended to have higher organic matter' and cation exchange capacity values. Nitrogen, phosphorus and potassium in the top soil were significantly higher in most intensive intercropped farms, but calcium and magnesium did not vary significantly. Moisture content, waterholding capacity, bulk density and particle density of the soil did not show significant difference with cropping patterns. Likewise, the number of bacteria, fungi and actinomycetes in the soil remained statistically the same. Leaf nitrogen and calcium, in­creased while potassium decreased with intensity of cropping. Phosphorus and magnesium showed no definite trend.


Author(s):  
Bao Jiang ◽  
Yibing Ma ◽  
Guangyun Zhu ◽  
Jun Li

Phytotoxicity thresholds for heavy metals are derived from dose–response curves, which show the relationships between exposure dose and toxicity response. However, the results of tests or observations are commonly based on total heavy metal concentration, not the exposure dose that causes phytotoxicity; additionally, the phytotoxicity response differs with plant species. In the present study, the ethylenediaminetetraacetic acid (EDTA)-extractable copper (Cu) concentration was determined in order to evaluate Cu extractability. As two important horticultural food crops in Asia, tomato (Lycopersicon esculentum ‘Meifen No. 1’) and bok choy (Brassica rapa var. chinensis ‘Susheng 28’) were used to investigate Cu phytotoxicity in a wide range of Chinese soils with and without leaching treatment, after which relationships between Cu phytotoxicity thresholds based on EDTA-extractions and soil properties were established. The phytotoxicity thresholds showed that biomass of bok choy was more sensitive to Cu than tomato. Multiple linear regression analyses showed that soil factors, including organic carbon (OC), citrate dithionate extractable manganese (CD-Mn), cation exchange capacity (CEC), and CaCO3 explained over 85% of the variance in Cu phytotoxicity thresholds. The EDTA-extractable Cu dose–response relationships were further improved by incorporating soil properties. The new phytotoxicity predictive models indicated soil properties (soil pH, OC, CEC, and oxalate-extractable Mn) and EDTA-extractable Cu concentration explained more than 90% of the variance in the phytotoxicity response of tomato and bok choy biomass. The new phytotoxicity predictive models could be used to develop a reasonable remediation strategy for contaminated soils.


2013 ◽  
Vol 27 (1) ◽  
pp. 57-67 ◽  
Author(s):  
S.E. Obalum ◽  
J. Oppong ◽  
C.A. Igwe ◽  
Y. Watanabe ◽  
M.E. Obi

Abstract The spatial variability of some physicochemical properties of topsoils/subsoils under secondary forest, grassland fallow, and bare-soil fallow of three locations was evaluated. The data were analyzed and described using classical statistical parameters. Based on the coefficient of variation, bulk density, total porosity, 60-cm-tension moisture content, and soil pH were of low variability. Coarse and fine sand were of moderate variability. Highly variable soil properties included silt, clay, macroporosity, saturated hydraulic conductivity, organic matter concentration, and cation exchange capacity. Overall, soil pH and silt varied the least and the most, respectively. Relative weighting showed that location dominantly influenced the soil variability, except for soil porosity and organic matter concentration influenced mostly by land use. Most of the soil data were normally distributed; others were positively skewed and/or kurtotic. The minimum number of samples (at 25 samples ha-1) required to estimate mean values of soil properties was highly soil property-specific, ranging from 1 (topsoil pH-H2O) to 246 (topsoil silt). Cation exchange capacity of subsoils related fairly strongly with cation exchange capacity of topsoils (R2 = 0.63). Spatial variability data can be used to extrapolate dynamic soil properties across a derived-savanna landscape.


Solid Earth ◽  
2017 ◽  
Vol 8 (4) ◽  
pp. 827-843 ◽  
Author(s):  
Sunday Adenrele Adeniyi ◽  
Willem Petrus de Clercq ◽  
Adriaan van Niekerk

Abstract. Cocoa agroecosystems are a major land-use type in the tropical rainforest belt of West Africa, reportedly associated with several ecological changes, including soil degradation. This study aims to develop a composite soil degradation assessment index (CSDI) for determining the degradation level of cocoa soils under smallholder agroecosystems of southwestern Nigeria. Plots where natural forests have been converted to cocoa agroecosystems of ages 1–10, 11–40, and 41–80 years, respectively representing young cocoa plantations (YCPs), mature cocoa plantations (MCPs), and senescent cocoa plantations (SCPs), were identified to represent the biological cycle of the cocoa tree. Soil samples were collected at a depth of 0 to 20 cm in each plot and analysed in terms of their physical, chemical, and biological properties. Factor analysis of soil data revealed four major interacting soil degradation processes: decline in soil nutrients, loss of soil organic matter, increase in soil acidity, and the breakdown of soil textural characteristics over time. These processes were represented by eight soil properties (extractable zinc, silt, soil organic matter (SOM), cation exchange capacity (CEC), available phosphorus, total porosity, pH, and clay content). These soil properties were subjected to forward stepwise discriminant analysis (STEPDA), and the result showed that four soil properties (extractable zinc, cation exchange capacity, SOM, and clay content) are the most useful in separating the studied soils into YCP, MCP, and SCP. In this way, we have sufficiently eliminated redundancy in the final selection of soil degradation indicators. Based on these four soil parameters, a CSDI was developed and used to classify selected cocoa soils into three different classes of degradation. The results revealed that 65 % of the selected cocoa farms are moderately degraded, while 18 % have a high degradation status. The numerical value of the CSDI as an objective index of soil degradation under cocoa agroecosystems was statistically validated. The results of this study reveal that soil management should promote activities that help to increase organic matter and reduce Zn deficiency over the cocoa growth cycle. Finally, the newly developed CSDI can provide an early warning of soil degradation processes and help farmers and extension officers to implement rehabilitation practices on degraded cocoa soils.


2003 ◽  
Vol 27 (3) ◽  
pp. 519-525 ◽  
Author(s):  
P. J. Valarini ◽  
M. C. Díaz Alvarez ◽  
J. M. Gascó ◽  
F. Guerrero ◽  
H. Tokeshi

Properties of a claim loam soil, collected in Aranjuez (Madrid) and enriched with organic matter and microorganisms, were evaluated under controlled temperature and moisture conditions, over a period of three months. The following treatments were carried out: soil (control); soil + 50 t ha-1 of animal manure (E50); soil + 50 t ha-1 of animal manure + 30 L ha-1 of effective microorganisms (E50EM); soil + 30 t ha-1 of the combination of various green crop residues and weeds (RC30) and soil + 30 t ha-1 of the combination of various green crop residues and weeds + 30 L ha-1 of effective microorganisms (RC30EM). Soil samples were taken before and after incubation and their physical, chemical, and microbiological parameters analyzed. Significant increase was observed in the production of exopolysaccharides and basic phosphatase and esterase enzyme activities in the treatments E50EM and RC30EM, in correlation with the humification of organic matter, water retention at field capacity, and the cationic exchange capacity (CEC) of the same treatments. The conclusion was drawn that the incorporation of a mixture of effective microorganisms (EM) intensified the biological soil activity and improved physical and chemical soil properties, contributing to a quick humification of fresh organic matter. These findings were illustrated by the microbiological activities of exopolysaccharides and by alkaline phosphatase and esterase enzymes, which can be used as early and integrated soil health indicators.


SOIL ◽  
2016 ◽  
Vol 2 (1) ◽  
pp. 63-70 ◽  
Author(s):  
Alemayehu Adugna ◽  
Assefa Abegaz

Abstract. Land use change can have negative or positive effects on soil quality. Our objective was to assess the effects of land uses changes on the dynamics of selected soil physical and chemical properties. Soil samples were collected from three adjacent soil plots under different land uses, namely forestland, grazing land, and cultivated land at 0–15 cm depth. Changes in soil properties on cultivated and grazing land were computed and compared to forestland, and ANOVA (analysis of variance) was used to test the significance of the changes. Sand and silt proportions, soil organic content, total nitrogen content, acidity, cation exchange capacity, and exchangeable Ca2+ content were higher in forestlands. Exchangeable Mg2+ was highest in grazing land, while clay, available phosphorous, and exchangeable K+ were highest in cultivated land. The percentage changes in sand, clay, soil organic matter, cation exchange capacity, and exchangeable Ca2+ and Mg2+ were higher in cultivated land than in grazing land and forestland. In terms of the relation between soil properties, soil organic matter, total nitrogen, cation exchange capacity, and exchangeable Ca2+ were strongly positively correlated with most of soil properties, while available phosphorous and silt have no significant relationship with any of the other considered soil properties. Clay has a negative correlation with all soil properties. Generally, cultivated land has the least concentration of soil physical and chemical properties except clay and available phosphorous, which suggests an increasing degradation rate in soils of cultivated land. So as to increase soil organic matter and other nutrients in the soil of cultivated land, the integrated implementation of land management through compost, cover crops, manures, minimum tillage, crop rotation, and liming to decrease soil acidity are suggested.


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