scholarly journals Determination of Cr, Pb and Ni in water, sludge and plants from settling ponds of a sewage treatment works

Water SA ◽  
2019 ◽  
Vol 33 (5) ◽  
Author(s):  
Kandasamy G. Moodley ◽  
Himansu Baijnath ◽  
Florence A. Southway-Ajulu ◽  
Saroja Maharaj ◽  
Sathianathan R. Chetty
Author(s):  
Klaudia Kokoszka ◽  
Agnieszka Kobus ◽  
Sylwia Bajkacz

The residues of antimicrobials used in human and veterinary medicine are popular pollutants of anthropogenic origin. The main sources of introducing antimicrobials into the environment are sewage treatment plants and the agricultural industry. Antimicrobials in animal manure contaminate the surrounding soil as well as groundwater, and can be absorbed by plants. The presence of antimicrobials in food of plant origin may pose a threat to human health due to their high biological activity. As part of the research, a procedure was developed for the extraction and determination of ciprofloxacin, enrofloxacin, cefuroxime, nalidixic acid and metronidazole in environmental samples (soil and parsley root). An optimized solid-liquid extraction (SLE) method was used to separate antimicrobials from the solid samples and a mixture of citrate buffer (pH = 4): methanol (1:1; v/v) was used as the extraction solvent. Solid phase extraction (SPE) with OASIS® HLB cartridges was used to purify and pre-concentrate the sample. The recovery of the developed method was in the range of 55–108%. Analytes were determined by high-performance liquid chromatography coupled with an ultraviolet (UV) detector and a tandem mass spectrometer (HPLC-UV-MS/MS). The procedure was validated and applied to the determination of selected antimicrobials in soil and parsley root samples. Five types of soil and five types of parsley roots of different origins were analyzed. The presence of nalidixic acid in the parsley root samples was found in the concentration range of 0.14–0.72 ng g−1. It has been shown that antimicrobials are absorbed by the plant and can accumulate antimicrobials in its edible parts.


2005 ◽  
Vol 39 (10) ◽  
pp. 3421-3429 ◽  
Author(s):  
Richard H. Lindberg ◽  
Patrik Wennberg ◽  
Magnus I. Johansson ◽  
Mats Tysklind ◽  
Barbro A. V. Andersson

1973 ◽  
Vol 2 (4) ◽  
pp. 473-482 ◽  
Author(s):  
J. C. Van Loon ◽  
J. Lichwa ◽  
D. Ruttan ◽  
J. Kinrade

1993 ◽  
Vol 44 (4) ◽  
pp. 635 ◽  
Author(s):  
GW Kilby ◽  
GE Batley

The determination of recent sedimentation rates has traditionally used radiochemical dating techniques but, because of limited laboratory facilities and the costs of these techniques, alternative methods are desirable. Information on sedimentation rates and sediment history can be obtained from anthropogenic chemical components whose presence in sediments, especially near urban areas, can be used as markers to assess their chronology. More than one marker, with a known date of introduction, should be used. In this study, organosilicons first used in the early 1950s and tributyltin used in marine antifouling paints from 1972 were examined in sediments from Lake Macquarie, NSW, to supplement the known input of heavy metals from the lead-zinc smelter that has been operating at the northern end of the lake since 1897. The most reliable data were obtained at sites where all three markers were present, and use of these data allowed independent determination of the year of initial operation of a sewage treatment works.


2013 ◽  
Author(s):  
Nurfaizah Abu Tahrim ◽  
Md. Pauzi Abdullah ◽  
Yang Farina Abdul Aziz
Keyword(s):  

2001 ◽  
Vol 36 (4) ◽  
pp. 781-792 ◽  
Author(s):  
Chris Marvin ◽  
John Coakley ◽  
Tatiana Mayer ◽  
Mitra Brown ◽  
Lina Thiessen

Abstract An analytical method to determine faecal sterols was developed and applied to the analysis of samples including pig manure, sewage treatment plant sludge and combined sewer overflow effluent. Compounds including coprostanol (5β-cholestan-3β-ol), epicoprostanol (5β-cholestan-3α-ol), cholesterol (cholestan-5-en-3β-ol) and dihydrocholesterol (cholestanol, 5α-cholestan-3β-ol) were quantified in these source samples and their relative ratios calculated to investigate their potential application as source tracers. A mean coprostanol:epicoprostanol ratio of 7.6 ± 1.17 was calculated for pig manure samples from three Ontario livestock operations. This ratio was much lower (approximately 1.8) for sewage treatment plant sludge while the ratio for a combined sewer overflow effluent was very high (approximately 70). This approach, with the addition of physical measurements (e.g., current velocities) and meteorological data, may assist in determination of the influence of shore-based activities, including sewage treatment and livestock operations, on aquatic systems.


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