Experimental, kinetic, equilibrium and regeneration studies for adsorption of Cr(VI) from aqueous solutions using low cost adsorbent (activated flyash)

2010 ◽  
Vol 20 (1-3) ◽  
pp. 168-178 ◽  
Author(s):  
Suresh Gupta ◽  
B.V. Babu
Keyword(s):  
Aqueous Solutions ◽  
Low Cost ◽  
Kinetic Equilibrium

scholarly journals Removal of As(V) from aqueous solutions using calcium-alginate microspheres with encapsulated iron nanoparticles

2021 ◽  
Author(s):  
María Soledad Ruiz-Mora ◽  
Ruth Alfaro-Cuevas-Villanueva ◽  
Verónica Martínez-Miranda ◽  
Orlando Hernández-Cristóbal ◽  
Raúl Cortés-Martínez
Keyword(s):  
Particle Size ◽  
Aqueous Solutions ◽  
Calcium Alginate ◽  
Iron Nanoparticles ◽  
Low Cost ◽  
Human Consumption ◽  
Batch Systems ◽  
Adsorption Capacities ◽  
Kinetic Rates ◽  
Kinetic Equilibrium

Abstract This work investigated As(V) removal from aqueous solutions using calcium alginate microspheres with encapsulated iron nanoparticles (FeNPs) in batch systems. The kinetic, equilibrium, and thermodynamic parameters of the adsorption process were evaluated. Adsorbents were characterized using Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy, and Zeta Potential techniques. The FeNPs were obtained by a simple and low-cost method and they were successfully encapsulated and uniformly dispersed over the microspheres' surface. Significantly fast adsorption kinetic rates were observed due to microspheres' particle size and FeNPs encapsulation. The chemisorption mechanism was recognized in both adsorbate-adsorbent systems. The As(V) isotherms data suggested that the process is associated with heterogeneous adsorption. Available sorption sites with different adsorption energies were related to the functional groups involved in removing As(V), such as hydroxyl and carboxyl groups. Significantly high adsorption capacities were obtained for both materials, suggesting they can be competitive compared to conventional adsorbents, even at low FeNPs concentrations. Besides FeNPs encapsulation enhancing arsenate removal, higher adsorption was obtained at slightly acidic pH values and, together with their small particle size, suggests that the microspheres have a great potential to be used as arsenate adsorbents in the water treatment for human consumption.

Comparison of the fixation of several metal ions onto a low-cost biopolymer

2002 ◽  
Vol 2 (5-6) ◽  
pp. 217-224 ◽  
Author(s):  
Z. Reddad ◽  
C. Gérente ◽  
Y. Andrès ◽  
P. Le Cloirec
Keyword(s):  
Aqueous Solutions ◽  
Metal Ions ◽  
Low Cost ◽  
Operating Conditions ◽  
Order Kinetic ◽  
Adsorption Mechanisms ◽  
Equilibrium Data ◽  
Order Kinetic Model ◽  
Beet Pulp ◽  
Removal Of Metal Ions

In the present work, sugar beet pulp, a common waste from the sugar refining industry, was studied in the removal of metal ions from aqueous solutions. The ability of this cheap biopolymer to sorb several metals namely Pb2+, Cu2+, Zn2+, Cd2+ and Ni2+ in aqueous solutions was investigated. The metal fixation capacities of the sorbent were determined according to operating conditions and the fixation mechanisms were identified. The biopolymer has shown high elimination rates and interesting metal fixation capacities. A pseudo-second-order kinetic model was tested to investigate the adsorption mechanisms. The kinetic parameters of the model were calculated and discussed. For 8 × 10-4 M initial metal concentration, the initial sorption rates (v0) ranged from 0.063 mmol.g-1.min-1 for Pb2+ to 0.275 mmol.g-1.min-1 for Ni2+ ions, with the order: Ni2+ > Cd2+ > Zn2+ > Cu2+ > Pb2+. The equilibrium data fitted well with the Langmuir model and showed the following affinity order of the material: Pb2+ > Cu2+ > Zn2+ > Cd2+ > Ni2+. Then, the kinetic and equilibrium parameters calculated qm and v0 were tentatively correlated to the properties of the metals. Finally, equilibrium experiments in multimetallic systems were performed to study the competition of the fixation of Pb2+, Zn2+ and Ni2+ cations. In all cases, the metal fixation onto the biopolymer was found to be favourable in multicomponent systems. Based on these results, it is demonstrated that this biosorbent represents a low-cost solution for the treatment of metal-polluted wastewaters.

Investigating the equilibrium and adsorption kinetics for the removal of Ni (II) ions from aqueous solutions using adsorbents prepared from the modified waste newspapers: A low-cost and available adsorbent

2019 ◽  
Vol 146 ◽  
pp. 1043-1053 ◽  
Author(s):  
Mohammad Hadi Dehghani ◽  
Mohammad Sarmadi ◽  
Mohammad Reza Alipour ◽  
Daryoush Sanaei ◽  
Hamid Abdolmaleki ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Adsorption Kinetics ◽  
Low Cost

scholarly journals Adsorptive Removal of Phosphate from Aqueous Solutions Using Low-Cost Volcanic Rocks: Kinetics and Equilibrium Approaches

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1312
Author(s):  
Dereje Tadesse Mekonnen ◽  
Esayas Alemayehu ◽  
Bernd Lennartz
Keyword(s):  
Aqueous Solutions ◽  
Low Income ◽  
Low Cost ◽  
Volcanic Rocks ◽  
Phosphate Removal ◽  
Phosphate Adsorption ◽  
Adsorptive Capacity ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Adsorptive Removal

The contamination of surface and groundwater with phosphate originating from industrial and household wastewater remains a serious environmental issue in low-income countries. Herein, phosphate removal from aqueous solutions was studied using low-cost volcanic rocks such as pumice (VPum) and scoria (VSco), obtained from the Ethiopian Great Rift Valley. Batch adsorption experiments were conducted using phosphate solutions with concentrations of 0.5 to 25 mg·L−1 to examine the adsorption kinetic as well as equilibrium conditions. The experimental adsorption data were tested by employing various equilibrium adsorption models, and the Freundlich and Dubinin-Radushkevich (D-R) isotherms best depicted the observations. The maximum phosphate adsorption capacities of VPum and VSco were calculated and found to be 294 mg·kg−1 and 169 mg·kg−1, respectively. A pseudo-second-order kinetic model best described the experimental data with a coefficient of correlation of R2 > 0.99 for both VPum and VSco; however, VPum showed a slightly better selectivity for phosphate removal than VSco. The presence of competitive anions markedly reduced the removal efficiency of phosphate from the aqueous solution. The adsorptive removal of phosphate was affected by competitive anions in the order: HCO3− >F− > SO4−2 > NO3− > Cl− for VPum and HCO3− > F− > Cl− > SO4−2 > NO3− for VSco. The results indicate that the readily available volcanic rocks have a good adsorptive capacity for phosphate and shall be considered in future studies as test materials for phosphate removal from water in technical-scale experiments.

Development of a method for detecting trace metals in aqueous solutions based on the coordination chemistry of hexahydrotriazines

The Analyst ◽  
2015 ◽  
Vol 140 (15) ◽  
pp. 5184-5189 ◽  
Author(s):  
Rudy J. Wojtecki ◽  
Alexander Y. Yuen ◽  
Thomas G. Zimmerman ◽  
Gavin O. Jones ◽  
Hans W. Horn ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Coordination Chemistry ◽  
Trace Metals ◽  
Aqueous Solutions ◽  
Detection System ◽  
Low Cost ◽  
System P ◽  
Chemical Indicator

The detection of trace amounts (<10 ppb) of heavy metals in aqueous solutions is described using hexahydrotriazines as a chemical indicator and a low cost fluorimeter-based detection system.

scholarly journals Rapid removal of heavy metal ions from aqueous solutions by low cost adsorbents

2012 ◽  
Vol 12 (2/3/4) ◽  
pp. 318 ◽  
Author(s):  
Ali Ahmadpour ◽  
Tahereh Rohani Bastami ◽  
Masumeh Tahmasbi ◽  
Mohammad Zabihi
Keyword(s):  
Heavy Metal ◽  
Aqueous Solutions ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Low Cost ◽  
Rapid Removal

scholarly journals Adsorption of Rare Earth Elements from Aqueous Solutions Using Geopolymers

Proceedings ◽  
2018 ◽  
Vol 2 (10) ◽  
pp. 567 ◽  
Author(s):  
Željka Fiket ◽  
Ana Galović ◽  
Gordana Medunić ◽  
Martina Furdek Turk ◽  
Maja Ivanić ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Aqueous Solutions ◽  
High Efficiency ◽  
Low Cost ◽  
Coal Ash ◽  
Industrial Sector ◽  
Efficient Removal ◽  
Model Solutions ◽  
Technology Applications

Rare earth elements, i.e., lanthanides, are important components of many recently developed technology applications. However, their increasing use in the industrial sector, medicine, and agriculture over the last few decades has provided them with the title of “new pollutants”. Different methods are now applied for the removal of various pollutants from wastewaters, whereby the emphasis is placed on adsorption due to its simplicity, high efficiency, and low cost. In the present study, geopolymers prepared from coal ash were examined regarding their capacity for the adsorption of lanthanides from model solutions. The obtained results indicate the efficient removal of lanthanides by prepared geopolymers, depicting them as effective adsorbents for this group of elements.

Biosorption of basic dye from aqueous solutions by Date Stones and Palm-Trees Waste: Kinetic, equilibrium and thermodynamic studies

Desalination ◽  
2011 ◽  
Vol 271 (1-3) ◽  
pp. 80-87 ◽  
Author(s):  
Zohra Belala ◽  
Mejdi Jeguirim ◽  
Meriem Belhachemi ◽  
Fatima Addoun ◽  
Gwenaëlle Trouvé
Keyword(s):  
Aqueous Solutions ◽  
Thermodynamic Studies ◽  
Basic Dye ◽  
Palm Trees ◽  
Kinetic Equilibrium
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