Heavy metal removal from wastewaters by agricultural waste low-cost adsorbents: hindrances of adsorption technology to the large scale industrial application – a review

2017 ◽  
Vol 78 ◽  
pp. 192-214 ◽  
Author(s):  
Alphonse Habineza ◽  
Jun Zhai ◽  
Theoneste Ntakirutimana ◽  
Fu Ping Qiu ◽  
Xiaoting Li ◽  
...  
2020 ◽  
Vol 1010 ◽  
pp. 489-494
Author(s):  
Abdul Hafidz Yusoff ◽  
Rosmawani Mohammad ◽  
Mardawani Mohamad ◽  
Ahmad Ziad Sulaiman ◽  
Nurul Akmar Che Zaudin ◽  
...  

Conventional methods to remove heavy metals from polluted water are expensive and not environmentally friendly. Therefore, this study was carried out to investigate the potential of agricultural waste such as pineapple peel (Ananas Cosmos) as low-cost absorbent to remove heavy metals from synthetic polluted water. The results showed that Cd, Cr and Pb were effectively removed by the biosorbent at 12g of pineapple peels in 100 mL solution. The optimum contact time for maximum adsorption was found to be 90 minutes, while the optimum pH for the heavy metal’s adsorption was 9. It was demonstrated that with the increase of adsorbent dosage, the percent of heavy metals removal was also increased due to the increasing adsorption capacity of the adsorbent. In addition, Langmuir model show maximum adsorption capacity of Cd is 1.91 mg/g. As conclusions, our findings show that pineapple peel has potential to remove heavy metal from polluted water.


2020 ◽  
Vol 997 ◽  
pp. 113-120
Author(s):  
Hafizah Binti Naihi

The extensive use of heavy metals such as copper in various industries has discharged a large amount of the metals into the environment which is toxic at higher concentrations. The use of low-cost agricultural waste of biological origin such as tea waste may be an economic solution to this problem. Tea waste is among the potential material to be developed as an adsorbent for heavy metal ions. Tea waste contains cellulose and lignin which have been reported having an excellent metal binding capacity. This study aims to use tea waste for the removal of Cu2+ ions. The effect of variation in different parameters like initial concentration of Cu2+ ions in solution, adsorbent dosage and contact time were investigated using batch adsorption method. The adsorbent, tea waste was characterized using a compound microscope and FTIR spectroscopy. Experimental results showed that the maximum removal of the copper ion by tea waste at optimum condition (pH 7, 60 min. contact time, 0.8 g adsorbent dose and 0.7 M concentration) is 74%. The adsorbent prepared from tea waste is efficient and it can be conveniently employed as a low-cost alternative in the treatment of wastewater for heavy metal removal.


2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Kashir Ali ◽  
Muhammad Ussama Javaid ◽  
Zaman Ali ◽  
Muhammad Junaid Zaghum

Wastewater has a high concentration of dyes and heavy metals, which are the two most significant contaminants. Due to their high toxicity and vulnerability, they possess a potential threat to human health as well as the ecosystem. There are many ways to eliminate these pollutants from water but adsorption has attained much interest because of its low cost, easy application, and no secondary pollutants. Biomass is considered an ecological burden and a reason for the reduction in the earth’s carrying capacity. These materials may be used as cost-effective adsorbents to remove dyes and heavy metals from wastewater. This paper highlights recent advances made in dye and heavy metal adsorption in the last 10 years. The prime focus of this review paper is on the direct application of these biomasses without any chemical or physical alteration. The removal efficiencies and adsorption capabilities of different biomass-derived adsorbents for the removal of dyes and heavy metals from wastewater are summarised in this study. Additionally, the adsorption mechanisms underlying the removal of dyes and heavy metals using biomass-derived adsorbents have been discussed, with a focus on two kinetic models: pseudofirst-order and pseudosecond-order. Furthermore, the Langmuir and Freundlich isotherms were utilised to verify the experimental findings and to quantify the amount and degree of adsorption favorability. Based on what has been covered in the literature, the conclusion has been drawn. The future research needs are proposed in the area of biomass-derived adsorbent development, their modification for improved efficiencies, and application on large-scale wastewater treatment plants.


Author(s):  
Bingbing Qiu ◽  
Xuedong Tao ◽  
Hao Wang ◽  
Wenke Li ◽  
Xiang Ding ◽  
...  

2014 ◽  
Vol 625 ◽  
pp. 889-892 ◽  
Author(s):  
Safoura Daneshfozoun ◽  
Bawadi Abdullah ◽  
Mohd Azmuddin Abdullah

This study developed an effective and economical physical pretreatment of OPEFB to be used as biosorbent for the removal of heavy metal ions such as Cu+2, Zn+2and Pb2+. The effects of fibres sizes, metal ions concentration (100-1000 ppm), initial pH (4-10) and contact time (20-150 min) were investigated in batch system. Samples were characterized with Atomic Absorption Spectrometry (AAS), Transmission Electron Microscopy (TEM) and Fourier Transmission Infra-red Spectroscopy (FTIR). Results showed pH-dependence adsorption efficiency and increased adsorption with initial metal concentrations where more than 92% adsorption efficiency achieved. We have successfully developed an eco-friendly, low cost adsorbent without any chemical modification or excessive energy disposal.


2016 ◽  
Vol 7 (4) ◽  
pp. 387-419 ◽  
Author(s):  
Renu ◽  
Madhu Agarwal ◽  
K. Singh

Heavy metals are discharged into water from various industries. They can be toxic or carcinogenic in nature and can cause severe problems for humans and aquatic ecosystems. Thus, the removal of heavy metals from wastewater is a serious problem. The adsorption process is widely used for the removal of heavy metals from wastewater because of its low cost, availability and eco-friendly nature. Both commercial adsorbents and bioadsorbents are used for the removal of heavy metals from wastewater, with high removal capacity. This review article aims to compile scattered information on the different adsorbents that are used for heavy metal removal and to provide information on the commercially available and natural bioadsorbents used for removal of chromium, cadmium and copper, in particular.


Author(s):  
E I Ugwu ◽  
O Tursunov ◽  
D Kodirov ◽  
L M Shaker ◽  
A A Al-Amiery ◽  
...  

2020 ◽  
Vol 17 (9) ◽  
pp. 4666-4670
Author(s):  
Himanshu Sekhar Rath ◽  
Mira Das ◽  
Smita Rath ◽  
U. N. Dash ◽  
Alakananda Tripathy

The goal of this research is to determine the current standard of water quality along the Brahmani River stretch in terms of physico-chemical parameters. The River Brahmani receives a substantial amount of industrial waste in the identified study area and is witness to a large amount of human and agricultural activities. Nowadays Ninety percent of Brahmani’s required water is secured with groundwater resources and it is essential to forecast pollutant content in those resources. Hence, this research aimed at using of nanoparticles such as Activated Carbons (ACs) for removal of heavy metal such as nickel and zinc in Brahmani river using the Langmuir approach. Adsorption seems to be the most widely used method for heavy metal recovery due to its low cost, easy installation and the presence of alternative adsorbents. In addition, the process of adsorption can also be made in use to recover heavy metal ions from wastewater. Despite these advantages, adsorption is hard to commercialize. Due to the strong absorption capacity, high number of pores and wide, common area, nanoparticles are treated as the effective method in removal of heavy metals in rivers. Comparative analysis shows that seventy-one percent of heavy metals can be removed using the nanotechnology model.


2013 ◽  
Vol 389 ◽  
pp. 29-35 ◽  
Author(s):  
Norzila Othman ◽  
S. Mohd-Asharuddin ◽  
M.F.H. Azizul-Rahman

Biosorption is an environmental friendly method for metal removal as it can be used as a cost effective and efficient technique for heavy metal removal. A lot of biomass can be choosed as biosorbent such as waste material from food processing and agriculture.ent. This paper will review the potential used of local fruit rind as biosorbent for heavy metal removal in wastewater. Heavy metals have been in various industries and resulted to a toxic condition in aquatic ecosystem. Therefore, various techniques have been employed for the treatment of metal-bearing industrial wastewaters including biological treatment through biosorption. Biosorption offers the advantages of low cost, good efficiency and production of sludge with high metal content is possible to avoid by the existence of metal recovery method from metal loaded biosorbent. The successful application of local fruit waste in treating wastewater containing heavy metals requires a deeper understanding of how biosorbent material proceeds.


2021 ◽  
Author(s):  
Athar Hussain ◽  
Sangeeta Madan ◽  
Richa Madan

Adsorption processes are extensively used in wastewater treatment for heavy metal removal. The most widely used adsorbent is activated carbon giving the best of results but it’s high cost limits its use. It has a high cost of production and regeneration. As the world today faces a shortage of freshwater resources, it is inevitable to look for alternatives that lessen the burden on existing resources. Also, heavy metals are toxic even in trace concentrations, so an environmentally safe method of their removal necessitated the requirement of low cost adsorbents. Adsorption is a cost-effective technique and gained recognition due to its minimum waste disposal advantage. This chapter focuses on the process of adsorption and the types of adsorbent available today. It also encompasses the low-cost adsorbents ranging from agricultural waste to industrial waste explaining the adsorption reaction condition. The cost-effectiveness, technical applicability and easy availability of raw material with low negative impact on the system are the precursors in selecting the adsorbents. The novelty of the chapter lies in covering a wide range of adsorbents with their efficiency in removal of heavy metals from wastewater.


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