Hydrogen Entry Into Steel Under Corrosion Products

CORROSION ◽  
10.5006/3675 ◽  
2021 ◽  
Author(s):  
Darya Rudomilova ◽  
Tomáš Prošek ◽  
Mats Strom
Keyword(s):  
Atomic Hydrogen ◽  
High Strength Steels ◽  
High Strength ◽  
Corrosion Products ◽  
Homogeneous Layer ◽  
Hydrogen Ions ◽  
Atmospheric Conditions ◽  
Kelvin Probe ◽  
Rust Layer ◽  
Corrosion Pits

Hydrogen entry into high strength steel after local sodium chloride pre-deposition and during exposure to humid air was studied using scanning Kelvin probe. Two regions with different pH, potential and red rust composition were formed on the corroding side of the specimen. Hydrogen permeating through the specimen was detected over the region with the net cathodic character, which was linked to oxygen reduction taking place on top and within the red rust layer whereas anodic dissolution progressed inside the rust covered pits creating conditions favourable for formation of hydrogen ions. No measurable hydrogen entry was detected in the area covered with an apparently homogeneous layer of corrosion products and corroding uniformly. The finding that corrosion pits were the main source of atomic hydrogen implies that the susceptibility of high strength steels to pitting corrosion is an important parameter for evaluation of the risk of hydrogen embrittlement under atmospheric conditions.

Techniques for investigation of hydrogen embrittlement of advanced high strength steels

2018 ◽  
Vol 36 (5) ◽  
pp. 413-434 ◽  
Author(s):  
Darya Rudomilova ◽  
Tomáš Prošek ◽  
Gerald Luckeneder
Keyword(s):  
Hydrogen Embrittlement ◽  
Secondary Ion Mass Spectrometry ◽  
High Strength Steels ◽  
Thermal Desorption Spectroscopy ◽  
High Strength ◽  
Atmospheric Conditions ◽  
Kelvin Probe ◽  
Advanced High Strength Steels ◽  
Scanning Kelvin Probe ◽  
Atmospheric Exposure

AbstractProduction volumes of advanced high strength steels (AHSS) are growing rapidly due to material and energy savings they provide in a number of application areas. In order to use their potential fully, it is necessary to minimize any danger of unexpected failures caused by hydrogen embrittlement. It is possible only if deeper understanding of underlying mechanisms is obtained through further research. Besides description of main grades of AHSS and mechanisms of HE, this paper reviews available tools for determination of hydrogen content and susceptibility to HE focusing on atmospheric conditions. Techniques such as slow strain rate testing, constant load testing, electrochemical permeation technique, scanning Kelvin probe and scanning Kelvin probe force microscopy have already been used to study the effect of hydrogen entered under atmospheric exposure conditions. Nanoindentation, hydrogen microprint technique, thermal desorption spectroscopy, Ag decoration or secondary ion mass spectrometry can be also conducted after atmospheric exposure.

scholarly journals Scanning Kelvin Probe Investigation of High-Strength Steel Surface after Impact of Hydrogen and Tensile Strain

2020 ◽  
Vol 1 (1) ◽  
pp. 187-197 ◽  
Author(s):  
Andrei Nazarov ◽  
Flavien Vucko ◽  
Dominique Thierry
Keyword(s):  
Tensile Deformation ◽  
Electron Work Function ◽  
High Strength Steels ◽  
High Strength ◽  
Potential Drop ◽  
Hydrogen Uptake ◽  
Surface Oxide ◽  
Kelvin Probe ◽  
Scanning Kelvin Probe ◽  
Cracking Mechanisms

Hydrogen in combination with mechanical stress can lead to rapid degradation of high-strength steels through environmentally assisted cracking mechanisms. The scanning Kelvin probe (SKP) was applied to automotive martensitic steel grade MS1500 in order to detect local reactivity of the surface after hydrogen uptake and tensile deformation. Hydrogen and stress distribution in microstructures can be characterized by SKP indirectly measuring the potential drop in the surface oxide. Thus, the links between electron work function, oxide condition, and subsurface accumulation of hydrogen and stress have to be investigated. It was shown that plastic strain can mechanically break down the oxide film creating active (low potential) locations. Hydrogen effusion from the steel bulk, after cathodic charging in aqueous electrolyte, reduced the surface oxide and also decreased potential. It was shown that surface re-oxidation was delayed as a function of the current density and duration of cathodic hydrogen pre-charging. Thus, potential evolution during exposure in air can characterize the relative amount of subsurface hydrogen. SKP mapping of martensitic microstructure with locally developed residual stress and accumulated hydrogen displayed the lowest potential.

Optimization of Metallographic Sample Preparation for AFM/SKPFM Based Phase Distinction of Complex and Dual Phase High Strength Steels

2021 ◽  
Vol 58 (6) ◽  
pp. 308-331
Author(s):  
I. Traxler ◽  
G. Schimo-Aichhorn ◽  
A. Muhr ◽  
C. Commenda ◽  
A. Jerrar ◽  
...  
Keyword(s):  
Sample Preparation ◽  
Hydrogen Permeability ◽  
High Strength Steels ◽  
High Strength ◽  
Dual Phase ◽  
Kelvin Probe ◽  
Preparation Methods ◽  
Force Microscopy ◽  
Steel Grades ◽  
The Individual

Abstract For the comprehensive investigation of advanced high strength steel grades, like complex and dual phase steels, Atomic Force Microscopy (AFM) and Scanning Kelvin Probe Force Microscopy (SKPFM) have proven to be useful tools, especially for analysis of hydrogen permeability of the individual steel phases. However, for these studies a preparation route, exposing the microstructure of the steel, is necessary. Various sample preparation methods were examined, focusing on electropolishing and sputtering, and the selected route was optimized to guarantee reproducibility and stability of the prepared surface. Electropolishing was shown to be highly efficient to selectively reveal the individual steel phases without introducing strong topographical features disturbing the AFM measurements. A subsequent sputtering step was introduced to improve the stability and preservability of the surface up to several months. Finally, distinction of the steel phases via AFM/SKPFM, was complemented and compared with results from EBSD and XRD.

Features of welding technology for pipes from high-strength steels

2017 ◽  
Vol 7 (6) ◽  
pp. 54-59
Author(s):  
Nikolay G. Goncharov ◽  
◽  
Oleg I. Kolesnikov ◽  
Alexey A. Yushin ◽  
◽  
...  
Keyword(s):  
High Strength Steels ◽  
High Strength ◽  
Welding Technology

Analysis of the Crack Initiation at Non-Metallic Inclusions in High-Strength Steels

2012 ◽  
Vol 49 (8) ◽  
pp. 468-479 ◽  
Author(s):  
P. Grad ◽  
B. Reuscher ◽  
A. Brodyanski ◽  
M. Kopnarski ◽  
E. Kerscher
Keyword(s):  
Crack Initiation ◽  
High Strength Steels ◽  
High Strength ◽  
Metallic Inclusions

DOGAL 600 and 800 DP

Alloy Digest ◽  
2010 ◽  
Vol 59 (12) ◽  
Keyword(s):  
Tensile Strength ◽  
Physical Properties ◽  
Surface Treatment ◽  
Tensile Properties ◽  
High Strength Steels ◽  
High Strength

Abstract Dogal 600 and 800 DP are high-strength steels with a microstructure that contains ferrite, which is soft and formable, and martensite, which is hard and contributes to the strength of the steel. The designation relates to the lowest tensile strength. This datasheet provides information on composition, physical properties, hardness, and tensile properties. It also includes information on forming, joining, and surface treatment. Filing Code: CS-160. Producer or source: SSAB Swedish Steel Inc. and SSAB Swedish Steel.

YOUNGSTOWN YS-T50 to YS-T140 STEELS

Alloy Digest ◽  
1977 ◽  
Vol 26 (4) ◽  
Keyword(s):  
Physical Properties ◽  
High Strength Steels ◽  
High Strength ◽  
Heat Treating ◽  
Steel Alloy ◽  
Bend Strength ◽  
Weight Saving ◽  
Cold Rolled ◽  
Hot Rolled ◽  
Minimum Yield

Abstract YS-T 50 to YS-T 140 Steels comprise a series of high-strength, cold-rolled steels designed to meet performance and weight-saving objectives. They are an extension of Youngstown's series of hot-rolled high-strength steels (see Youngstown YS-T Steel, Alloy Digest SA-261, March 1971). The YS-T 50 to YS-T 140 steels have minimum yield strengths ranging from 50,000 psi to 140,000 psi. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and bend strength. It also includes information on heat treating, machining, and joining. Filing Code: SA-331. Producer or source: Youngstown Sheet and Tube Company.

BETHLEHEM LUKENS PLATE SPARTAN

Alloy Digest ◽  
2003 ◽  
Vol 52 (8) ◽  
Keyword(s):  
Fracture Toughness ◽  
Yield Strength ◽  
Tensile Properties ◽  
High Strength Steels ◽  
High Strength ◽  
Tensile Yield Strength ◽  
Precipitation Reactions

Abstract Bethlehem Lukens Plate (BLP) offers five grades of Spartan high-strength steels with tensile yield strength over 690 MPa (100 ksi). These alloys contain copper for precipitation reactions. They also have improved weldability and toughness compared to ASTM A 514 and A 543 grades. This datasheet provides information on composition, microstructure, hardness, and tensile properties as well as fracture toughness. It also includes information on forming and joining. Filing Code: SA-518. Producer or source: Bethlehem Lukens Plate.

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