scholarly journals Using on-stream X-ray fluorescence analysis to determine the chemical composition of drill cuttings

2021 ◽  
Vol 6 (4) ◽  
pp. 147-153
Author(s):  
Sergey V. Lakhtionov ◽  
Ivan S. Chumakov ◽  
Sergey G. Filinkov ◽  
Dmitry M. Chukin ◽  
Evgeny  N. Ishmetyev
Keyword(s):  
Chemical Composition ◽  
Chemical Elements ◽  
Drilling Fluid ◽  
Fluorescence Analysis ◽  
Spectral Lines ◽  
Drilling Mud ◽  
Drill Cuttings ◽  
Lack Of Information ◽  
Characteristic Lines ◽  
Main Components

Background. The authors investigate the problems arising from the lack of information on the chemical composition of the drilled rocks during the construction of a well. Aim. The aim of this study is to determine the possibilities and efficient application of the streaming XRF method for determining the elemental composition of unwashed drill cuttings. The contribution of the paper lies in the lack of experience in the world practice of using streaming XRF analyzers. Materials and methods. Furthermore, the authors evaluate the possibility to use the streaming XRF method for analyzing the chemical composition of drill cuttings for the development of the oil industry. At the same time, the application of the proposed method is justified. The basis of this study are the results of the application of the streaming XRF method using the CON-X 02 streaming spectrometer for analyzing the chemical composition of drill cuttings not washed from drilling mud. This project has been implemented according the technological project between Gazpromneft — NNGGF LLC in cooperation with Nosov Magnitogorsk State Technical University and Gazpromneft — STC LLC. Result. The article presents the results of determined main elements of the composition of drill cuttings. The authors have carried out the analysis of changes in the intensity of the characteristic lines of the main components from the sampling depth. Simultaneously, the authors show the possibilities to derive correlation curves for various elements characteristic of certain rocks in the geological section of a particular field. Moreover, the study reveals the identification and characteristics of geochemical signs of specific target layers. Conclusions. Based on the results of the study, authors may conclude that to obtain the correct results on the intensity of spectral lines of various chemical elements during streaming XRF analysis, there is no need to flush the cuttings from the drilling fluid. Finally, it is possible to qualitatively control the main elements of the composition of the drill cuttings.

Decomposition Spectrometric Data of Energy Dispersive X-Ray Fluorescence Analysis (EDXRF)

1991 ◽  
Vol 35 (B) ◽  
pp. 743-748 ◽  
Author(s):  
V. I. Smolniakov ◽  
I. A. Koltun
Keyword(s):  
Chemical Elements ◽  
Fluorescence Analysis ◽  
Spectral Lines ◽  
Semiconductor Detectors ◽  
X Ray ◽  
Spectrometric Data ◽  
Least Squares Fit ◽  
Special Software ◽  
High Level ◽  
Spectrum Decomposition

AbstractIt is well-known that in EDXRF, using high-resolution semiconductor detectors, evaluation of x-ray fluorescence radiation line intensities from multiplex spectrometric information represents definite difficulties, especially in automation of measurement-calculation procedures.A common spectrum decomposition problem is to get the following parameters: a number of spectral lines and their centroids, intensities from measured experimental data and their errors.We have developed special software for solving this problem using personal computers and high-level programming language C. It uses profiles of real-form lines of pure chemical elements produced by semiconductor detector spectrometers and these techniques: digital filters with parameters for suppression of background, multiplex structure analysis, and stable linear least-squares fit to get peak intensities. Also it established special criteria for reliability of the results.We compared our investigation with software “EDXRF” (ver.1.32) arid spectrum decomposition with Gaussian peaks.

scholarly journals Investigation into the Application of Cissus Populnea as Drilling Fluid Additive (Viscosifier) for Water Based Mud

2021 ◽  
Vol 6 (7) ◽  
pp. 33-37
Author(s):  
A. D. I. Sulaiman ◽  
M. B. Adamu ◽  
Usman Hassan ◽  
S. M. Aliyu
Keyword(s):  
Oil And Gas ◽  
Drilling Fluid ◽  
Research Work ◽  
Fluorescence Analysis ◽  
Oil And Gas Industry ◽  
Economic Benefits ◽  
Drilling Fluids ◽  
Drilling Mud ◽  
Environmental Friendliness ◽  
Water Based

Progress in drilling engineering demands more sophistication from the drilling mud in order to enhance the usage of drilling fluids, hence numerous additives were introduced, and a simple fluid became a complicated mixture of liquid, solid and chemicals. Some of the challenges with the existing drilling fluid additives has to do with compatibility, degradability, safety, cost, and environmental friendliness. Studies have been carried out on the economic benefits of Cissus Populnea which includes in areas of food, medicine, shelter, and transport but much attention has been paid to its applications in the Oil and Gas industry. This study investigates the rheological properties of Cissus Populnea for application as drilling fluid additive (viscosifier) in Water Based Drilling Mud. Fresh roots, stems and leaves of cissus populnea were sourced from Bayara, Bauchi State. Some liquid exudates of cissus populnea were collected and stored for analysis while some of the samples were dried and grinded in to powdered form. Exudate of the samples were characterized by FTIR, XRD and XRF. Drilling mud was formulated with the samples cisssus populnea and bentonite at different temperatures. The rheology of the formulated drilling mud was investigated and compared with that formulated using bentonite and carboxymethyl cellulose (CMC). Results from X-ray Fluorescence analysis show that the chemical composition of Cissus populnea stem and root are similar when comparing their major components (In2O3 and CaO), while that of leaf has its major components to be In2O3 and Cl. Therefore, in this research work, experiments were conducted with only stem and leaf since stem and roots have common features. From the results of FTIR spectra, the stem of cissus populnea has an OH peak wavelength of 3487.42 cm-1 while that of leave is 3340.82 cm-1. The diffractogram of the stem of cissus populnea was observed at 2q = 22.67o which is very close to that of CMC (2θ = 20.31o) while the intense peaks of leaf were observed at around 28.65o. Viscosity of cissus populnea was investigated and found to be decreasing with the increase in temperature for stem exudate. While for leaf exudate, the viscosity was rather increasing with the increase in temperature at temperatures below 35 oC and then continue to decrease with the increase in temperature. The outcome of this research has confirmed the applicability of cissus populnea for drilling fluid additives, viscosifier.

scholarly journals Devising criteria for the authenticity of historical cold weapons based on X-ray fluorescence analysis of their surface

2021 ◽  
Vol 6 (12 (114)) ◽  
Author(s):  
Nina Merezhko ◽  
Yuliia Vovk ◽  
Volodymyr Indutnyi ◽  
Kateryna Pirkovich ◽  
Valentyna Davydiuk ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Chemical Elements ◽  
Fluorescence Analysis ◽  
Pure Material ◽  
X Ray ◽  
Subsequent Investigation ◽  
Study Results ◽  
Chronological Period ◽  
Historical Objects ◽  
History Of

This paper reports the results of studying the chemical composition of the surface of 4 objects of cold weapons of the 19th and early 20th centuries, made of iron – bayonet knives and sabers. This makes it possible to establish the signs of authenticity of cold weapon samples made of iron in that chronological period. An authentic procedure has been proposed for examining the chemical composition of the surface of historical objects of cold weapons by rubbing the samples with cotton wool swabs and their subsequent investigation. This makes it possible to explore objects of cold weapons, whose size is large, as well as simplify the very procedure for studying objects of historical and cultural value. Using the X-ray fluorescent chemical analyzer Expert Mobile, chemical elements were found at the surface of samples of cold weapons made of iron. The presence of such elements is the result of the process of re-crystallization and self-purification of metal during a long history of its life. Elements found in almost every rubbing sample were identified: calcium, ferrum, zinc, cuprum, and chlorine. The studies of cold weapons samples testify to the heterogeneity of the composition of patina formations on their surface, which confirms the authenticity of ancient objects. In addition, the studies have shown a difference in the chemical composition of surface layers of different parts of individual samples of antique cold weapons, which may indicate different times or different technology for their manufacture. The fluorescence spectra of the obtained rubbing of individual samples of cold weapons were compared with "pure" material, which made it possible to identify elements removed from the surface of objects. The study results are important indicators to confirm the authenticity of cultural monuments and the technology of their manufacture in the past.

scholarly journals Avocado-Derived Biomass: Chemical Composition and Antioxidant Potential

Proceedings ◽  
2020 ◽  
Vol 70 (1) ◽  
pp. 100
Author(s):  
Minerva C. García-Vargas ◽  
María del Mar Contreras ◽  
Irene Gómez-Cruz ◽  
Juan Miguel Romero-García ◽  
Eulogio Castro
Keyword(s):  
Chemical Composition ◽  
Phenolic Content ◽  
Antioxidant Properties ◽  
Total Phenolic ◽  
Nutritional Properties ◽  
Aqueous Fraction ◽  
Extraction Solvent ◽  
Main Components ◽  
A Minor ◽  
Derivatives Of

Avocado has become fashionable due to its great organoleptic and nutritional properties. It is consumed as a fresh product and it is also processed to obtain salad oil and guacamole. In all cases, the only usable portion is the pulp. Therefore, to be a more sustainable and profitable agribusiness, it is important to recognize which compounds from the peel and the stone waste can be converted into valuable bio-products. Therefore, their chemical composition was determined according to the National Renewable Energy Laboratory, the total phenolic content by the Folin-Ciocalteu method and the antioxidant properties by the FRAP and TEAC assays. The main components of the peel and stone were acid-insoluble lignin (35.0% and 15.3%, respectively), polymeric sugars (23.6% and 43.9%, respectively), and the aqueous extractives (15.5% and 16.9%, respectively). Both biomasses contain lipids and protein, but a minor proportion (<6%). The valorization of lignin and sugars is of interest given the high content; stones are a rich source of glucose (93.2% of the polymeric fraction), which could be used to obtain biofuels or derivatives of interest. The extractive fraction of the peel contained the highest number of phenolic compounds (4.7 g/100 g biomass), mainly concentrated in the aqueous fraction (i.e., 87%) compared to the ethanol one, which was subsequently extracted. It correlated with major antioxidant activity and, therefore, the peel can be applied to obtain antioxidants and water can be used as an environmentally friendly extraction solvent.

scholarly journals Chemical Composition of the RS CNn-Type Star 33 Piscium

2011 ◽  
Vol 20 (1) ◽  
Author(s):  
G. Barisevišius ◽  
G. Tautvaišienė ◽  
S. Berdyugina ◽  
Y. Chorniy ◽  
I. Ilyin
Keyword(s):  
Chemical Composition ◽  
Chemical Elements ◽  
Type Star

AbstractAbundances of 22 chemical elements, including the key elements and isotopes such as

scholarly journals Seasonal variations in PM10 inorganic composition in the Andean city

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Rasa Zalakeviciute ◽  
Katiuska Alexandrino ◽  
Yves Rybarczyk ◽  
Alexis Debut ◽  
Karla Vizuete ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Inductively Coupled Plasma ◽  
Chemical Elements ◽  
Large Fraction ◽  
Urban Pollution ◽  
Optical Emission ◽  
High Elevation ◽  
Water Soluble ◽  
Wet Season ◽  
Soluble Ions

Abstract Particulate matter (PM) is one of the key pollutants causing health risks worldwide. While the preoccupation for increased concentrations of these particles mainly depends on their sources and thus chemical composition, some regions are yet not well investigated. In this work the composition of chemical elements of atmospheric PM10 (particles with aerodynamic diameters ≤ 10 µm), collected at the urban and suburban sites in high elevation tropical city, were chemically analysed during the dry and wet seasons of 2017–2018. A large fraction (~ 68%) of PM10 composition in Quito, Ecuador is accounted for by water-soluble ions and 16 elements analysed using UV/VIS spectrophotometer and Inductively Coupled Plasma—Optical Emission Spectroscopy (ICP-OES). Hierarchical clustering analysis was performed to study a correlation between the chemical composition of urban pollution and meteorological parameters. The suburban area displays an increase in PM10 concentrations and natural elemental markers during the dry (increased wind intensity, resuspension of soil dust) season. Meanwhile, densely urbanized area shows increased total PM10 concentrations and anthropogenic elemental markers during the wet season, which may point to the worsened combustion and traffic conditions. This might indicate the prevalence of cardiovascular and respiratory problems in motorized areas of the cities in the developing world.

scholarly journals Variation of the Chemical Composition of Waste Cooking Oils upon Bentonite Filtration

Resources ◽  
2019 ◽  
Vol 8 (2) ◽  
pp. 108 ◽  
Author(s):  
Alberto Mannu ◽  
Gina Vlahopoulou ◽  
Paolo Urgeghe ◽  
Monica Ferro ◽  
Alessandra Del Caro ◽  
...  
Keyword(s):  
Particle Size ◽  
Chemical Composition ◽  
Solid Phase ◽  
Volatile Fraction ◽  
X Ray Diffraction ◽  
Specific Chemical ◽  
Waste Cooking Oils ◽  
Main Components ◽  
Cooking Oils ◽  
Chemical Groups

The chemical composition and the color of samples of waste cooking oils (WCOs) were determined prior to and after filtration on two different pads of bentonite differing in particle size. The volatile fraction was monitored by headspace solid-phase microextraction (HS-SPME) coupled with gas-chromatography, while the variation of the composition of the main components was analyzed by 1H NMR. Both techniques allowed the detection of some decomposition products, such as polymers, terpenes, and derivatives of the Maillard process. The analysis of the chemical composition prior to and after bentonite treatment revealed a tendency for the clays to retain specific chemical groups (such as carboxylic acids or double bonds), independent of their particle size. A pair comparison test was conducted in order to detect the sensory differences of the intensity of aroma between the WCO treated with the two different bentonites. In addition, characterization of the bentonite by means of powder X-ray diffraction (XRD) and thermogravimetric measurements (TG) was performed.

scholarly journals Chemical Composition and Antimicrobial Activity of the Essential Oil from Flowers of Eryngium triquetrum (Apiaceae) Collected Wild in Sicily

2016 ◽  
Vol 11 (7) ◽  
pp. 1934578X1601100
Author(s):  
Simona Casiglia ◽  
Maurizio Bruno ◽  
Sergio Rosselli ◽  
Felice Senatore
Keyword(s):  
Antimicrobial Activity ◽  
Chemical Composition ◽  
Essential Oil ◽  
Antifungal Activities ◽  
Antibacterial And Antifungal Activities ◽  
Art Works ◽  
Main Components ◽  
Antibacterial And Antifungal ◽  
Historical Art

The chemical composition of the essential oil from flowers of Eringium triquetrum Vahl. collected in Sicily was evaluated by GC and GC-MS. The main components were pulegone (50.6%), piperitenone (30.5%) and menthone (7.0%). Comparison of this oil with other studied oils of Eringium species is discussed. The oil showed good antibacterial and antifungal activities against some microorganisms that infest historical art works.

Sign in / Sign up

Export Citation Format

Share Document