scholarly journals Direct oceanic emissions unlikely to account for the missing source of atmospheric carbonyl sulfide

2017 ◽  
Vol 17 (1) ◽  
pp. 385-402 ◽  
Author(s):  
Sinikka T. Lennartz ◽  
Christa A. Marandino ◽  
Marc von Hobe ◽  
Pau Cortes ◽  
Birgit Quack ◽  
...  
Keyword(s):  
Surface Waters ◽  
Carbonyl Sulfide ◽  
Box Model ◽  
Trace Gas ◽  
Co2 Uptake ◽  
Tropical Ocean ◽  
Bottom Up ◽  
Sources And Sinks ◽  
Indirect Emission ◽  
Oceanic Emissions

Abstract. The climate active trace-gas carbonyl sulfide (OCS) is the most abundant sulfur gas in the atmosphere. A missing source in its atmospheric budget is currently suggested, resulting from an upward revision of the vegetation sink. Tropical oceanic emissions have been proposed to close the resulting gap in the atmospheric budget. We present a bottom-up approach including (i) new observations of OCS in surface waters of the tropical Atlantic, Pacific and Indian oceans and (ii) a further improved global box model to show that direct OCS emissions are unlikely to account for the missing source. The box model suggests an undersaturation of the surface water with respect to OCS integrated over the entire tropical ocean area and, further, global annual direct emissions of OCS well below that suggested by top-down estimates. In addition, we discuss the potential of indirect emission from CS2 and dimethylsulfide (DMS) to account for the gap in the atmospheric budget. This bottom-up estimate of oceanic emissions has implications for using OCS as a proxy for global terrestrial CO2 uptake, which is currently impeded by the inadequate quantification of atmospheric OCS sources and sinks.

scholarly journals Oceanic emissions unlikely to account for the missing source of atmospheric carbonyl sulfide

2016 ◽  
Author(s):  
Sinikka T. Lennartz ◽  
Christa A. Marandino ◽  
Marc von Hobe ◽  
Pau Cortes ◽  
Birgit Quack ◽  
...  
Keyword(s):  
Carbonyl Sulfide ◽  
Global Ocean ◽  
Trace Gas ◽  
Co2 Uptake ◽  
Top Down ◽  
Tropical Ocean ◽  
Bottom Up ◽  
Sources And Sinks ◽  
Net Uptake ◽  
Oceanic Emissions

Abstract. The climate active trace-gas carbonyl sulfide (OCS) is the most abundant sulfur gas in the atmosphere. A missing source in its atmospheric budget is currently suggested, resulting from an upward revision of the vegetation sink in top-down approaches. Oceanic emissions have been proposed to close the resulting gap in the atmospheric budget. We present a bottom-up approach including new observations of OCS in surface waters of the tropical Atlantic, Pacific and Indian oceans to show that direct OCS emissions are insufficient to account for the missing source. Extrapolation of our observations using a biogeochemical box model suggests oceanic net uptake instead of emission for the entire tropical ocean area and, further, a global ocean source strength well below that suggested by top-down estimates. This bottom-up estimate of oceanic emissions has implications for using OCS as a proxy for terrestrial CO2 uptake, which is currently hampered by the inadequate quantification of atmospheric OCS sources and sinks.

scholarly journals Marine carbonyl sulfide (OCS) and carbon disulfide (CS<sub>2</sub>): a compilation of measurements in seawater and the marine boundary layer

2019 ◽  
Author(s):  
Sinikka T. Lennartz ◽  
Christa A. Marandino ◽  
Marc von Hobe ◽  
Meinrat O. Andreae ◽  
Kazushi Aranami ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Carbon Disulfide ◽  
Marine Boundary Layer ◽  
Carbonyl Sulfide ◽  
The Arctic ◽  
Co2 Uptake ◽  
Aerosol Layer ◽  
Spatial And Temporal Patterns ◽  
Atmospheric Concentration ◽  
Oceanic Emissions

Abstract. Carbonyl sulfide (OCS) and carbon disulfide (CS2) are volatile sulfur gases that are naturally formed in seawater and exchanged with the atmosphere. OCS is the most abundant sulfur gas in the atmosphere, and CS2 is its most important precursor. They have gained interest due to their direct (OCS) or indirect (CS2 via oxidation to OCS) contribution to the stratospheric sulfate aerosol layer. Furthermore, OCS serves as a proxy to constrain terrestrial CO2 uptake by vegetation. Oceanic emissions of both gases contribute a major part to their atmospheric concentration. Here we present a database of previously published and unpublished, mainly ship-borne measurements in seawater and the marine boundary layer for both gases, available at https://doi.pangaea.de/10.1594/PANGAEA.905430 (Lennartz et al., 2019). The database contains original measurements as well as data digitalized from figures in publications from 42 measurement campaigns, i.e. cruises or time series stations, ranging from 1982 to 2019. OCS data cover all ocean basins except for the Arctic Ocean, as well as all months of the year, while the CS2 dataset shows large gaps in spatial and temporal coverage. Concentrations are consistent across different sampling and analysis techniques for OCS. The database is intended to support the identification of global spatial and temporal patterns and to facilitate the evaluation of model simulations.

scholarly journals Marine carbonyl sulfide (OCS) and carbon disulfide (CS<sub>2</sub>): a compilation of measurements in seawater and the marine boundary layer

2020 ◽  
Vol 12 (1) ◽  
pp. 591-609 ◽  
Author(s):  
Sinikka T. Lennartz ◽  
Christa A. Marandino ◽  
Marc von Hobe ◽  
Meinrat O. Andreae ◽  
Kazushi Aranami ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Carbon Disulfide ◽  
Marine Boundary Layer ◽  
Carbonyl Sulfide ◽  
The Arctic ◽  
Co2 Uptake ◽  
Aerosol Layer ◽  
Spatial And Temporal Patterns ◽  
Atmospheric Concentration ◽  
Oceanic Emissions

Abstract. Carbonyl sulfide (OCS) and carbon disulfide (CS2) are volatile sulfur gases that are naturally formed in seawater and exchanged with the atmosphere. OCS is the most abundant sulfur gas in the atmosphere, and CS2 is its most important precursor. They have attracted increased interest due to their direct (OCS) or indirect (CS2 via oxidation to OCS) contribution to the stratospheric sulfate aerosol layer. Furthermore, OCS serves as a proxy to constrain terrestrial CO2 uptake by vegetation. Oceanic emissions of both gases contribute a major part to their atmospheric concentration. Here we present a database of previously published and unpublished (mainly shipborne) measurements in seawater and the marine boundary layer for both gases, available at https://doi.org/10.1594/PANGAEA.905430 (Lennartz et al., 2019). The database contains original measurements as well as data digitalized from figures in publications from 42 measurement campaigns, i.e., cruises or time series stations, ranging from 1982 to 2019. OCS data cover all ocean basins except for the Arctic Ocean, as well as all months of the year, while the CS2 dataset shows large gaps in spatial and temporal coverage. Concentrations are consistent across different sampling and analysis techniques for OCS. The database is intended to support the identification of global spatial and temporal patterns and to facilitate the evaluation of model simulations.

scholarly journals A kinetic analysis of leaf uptake of COS and its relation to transpiration, photosynthesis and carbon isotope fractionation

2010 ◽  
Vol 7 (1) ◽  
pp. 333-341 ◽  
Author(s):  
U. Seibt ◽  
J. Kesselmeier ◽  
L. Sandoval-Soto ◽  
U. Kuhn ◽  
J. A. Berry
Keyword(s):  
Carbonyl Sulfide ◽  
Trace Gas ◽  
Great Promise ◽  
Co2 Uptake ◽  
Model Framework ◽  
Uptake Rates ◽  
Simple Kinetic Model ◽  
Leaf Level ◽  
Global Vegetation ◽  
Atmospheric Trace Gas

Abstract. Carbonyl sulfide (COS) is an atmospheric trace gas that holds great promise for studies of terrestrial carbon and water exchange. In leaves, COS follows the same pathway as CO2 during photosynthesis. Both gases are taken up in enzyme reactions, making COS and CO2 uptake closely coupled at the leaf scale. The biological background of leaf COS uptake is a hydrolysis reaction catalyzed by the enzyme carbonic anhydrase. Based on this, we derive and test a simple kinetic model of leaf COS uptake, and relate COS to CO2 and water fluxes at the leaf scale. The equation was found to predict realistic leaf COS fluxes compared to observations from field and laboratory chambers. We confirm that COS uptake at the leaf level is directly linked to stomatal conductance. As a consequence, the ratio of normalized uptake rates (uptake rates divided by ambient mole fraction) for leaf COS and CO2 fluxes can provide an estimate of Ci/Ca, the ratio of intercellular to atmospheric CO2, an important plant gas exchange parameter that cannot be measured directly. The majority of published normalized COS to CO2 uptake ratios for leaf studies on a variety of species fall in the range of 1.5 to 4, corresponding to Ci/Ca ratios of 0.5 to 0.8. In addition, we utilize the coupling of Ci/Ca and photosynthetic 13C discrimination to derive an estimate of 2.8±0.3 for the global mean normalized uptake ratio. This corresponds to a global vegetation sink of COS in the order of 900±100 Gg S yr−1. COS can now be implemented in the same model framework as CO2 and water vapour. Atmospheric COS measurements can then provide independent constraints on CO2 and water cycles at ecosystem, regional and global scales.

scholarly journals A multi-variable box model approach to the soft tissue carbon pump

2010 ◽  
Vol 6 (6) ◽  
pp. 827-841 ◽  
Author(s):  
A. M. de Boer ◽  
A. J. Watson ◽  
N. R. Edwards ◽  
K. I. C. Oliver
Keyword(s):  
Soft Tissue ◽  
Numerical Models ◽  
Nutrient Utilization ◽  
Atmospheric Co2 ◽  
Box Model ◽  
Co2 Uptake ◽  
Residual Circulation ◽  
Biological Mechanisms ◽  
Export Production ◽  
Model Approach

Abstract. The canonical question of which physical, chemical or biological mechanisms were responsible for oceanic uptake of atmospheric CO2 during the last glacial is yet unanswered. Insight from paleo-proxies has led to a multitude of hypotheses but none so far have been convincingly supported in three dimensional numerical modelling experiments. The processes that influence the CO2 uptake and export production are inter-related and too complex to solve conceptually while complex numerical models are time consuming and expensive to run which severely limits the combinations of mechanisms that can be explored. Instead, an intermediate inverse box model approach of the soft tissue pump is used here in which the whole parameter space is explored. The glacial circulation and biological production states are derived from these using proxies of glacial export production and the need to draw down CO2 into the ocean. We find that circulation patterns which explain glacial observations include reduced Antarctic Bottom Water formation and high latitude upwelling and mixing of deep water and to a lesser extent reduced equatorial upwelling. The proposed mechanism of CO2 uptake by an increase of eddies in the Southern Ocean, leading to a reduced residual circulation, is not supported. Regarding biological mechanisms, an increase in the nutrient utilization in either the equatorial regions or the northern polar latitudes can reduce atmospheric CO2 and satisfy proxies of glacial export production. Consistent with previous studies, CO2 is drawn down more easily through increased productivity in the Antarctic region than the sub-Antarctic, but that violates observations of lower export production there. The glacial states are more sensitive to changes in the circulation and less sensitive to changes in nutrient utilization rates than the interglacial states.

scholarly journals Biological CO2 Uptake and Upwelling Regulate the Air-Sea CO2 Flux in the Changjiang Plume Under South Winds in Summer

2021 ◽  
Vol 8 ◽  
Author(s):  
Dewang Li ◽  
Xiaobo Ni ◽  
Kui Wang ◽  
Dingyong Zeng ◽  
Bin Wang ◽  
...  
Keyword(s):  
Surface Waters ◽  
Carbon Sink ◽  
Co2 Flux ◽  
Co2 Uptake ◽  
Short Term ◽  
Biological Production ◽  
Initial Stage ◽  
Wind Event ◽  
Wind Events ◽  
Biogeochemical Parameters

The partial pressure of CO2 (pCO2) in the sea and the air-sea CO2 flux in plume waters are subject to interactions among biological production, horizontal advection, and upwelling under wind events. In this study, time series of pCO2 and other biogeochemical parameters in the dynamic Changjiang plume were presented to illuminate the controlling factors of pCO2 and the air-sea CO2 flux after a strong south wind event (July 23–24, maximum of 11.2 ms–1). The surface pCO2 decreased by 310 μatm (to 184 μatm) from July 24 to 26. Low-pCO2 waters (&lt;200 μatm) were observed in the following 2 days. Corresponding chlorophyll a and dissolved oxygen (DO) increase, and a significant relationship between DO and npCO2 indicated that biological uptake drove the pCO2 decrease. The salinity of undersaturated-CO2 waters decreased by 3.57 (from 25.03 to 21.46) within 2 days (July 27–28), suggesting the offshore advection of plume waters in which CO2 had been biologically reduced. Four days after the wind event, the upwelling of high-CO2 waters was observed, which increased the pCO2 by 428 μatm (up to 584 μatm) within 6 days. Eight days after the onset of upwelling, the surface pCO2 started to decrease (from 661 to 346 μatm within 3 days), which was probably associated with biological production. Regarding the air-sea CO2 flux, the carbon sink of the plume was enhanced as the low-pCO2 plume waters were pushed offshore under the south winds. In its initial stage, the subsequent upwelling made the surface waters act as a carbon source to the atmosphere. However, the surface waters became a carbon sink again after a week of upwelling. Such short-term air-sea carbon fluxes driven by wind have likely occurred in other dynamic coastal waters and have probably induced significant uncertainties in flux estimations.

scholarly journals The impact of improved satellite retrievals on estimates of biospheric carbon balance

2020 ◽  
Vol 20 (1) ◽  
pp. 323-331 ◽  
Author(s):  
Scot M. Miller ◽  
Anna M. Michalak
Keyword(s):  
Carbon Balance ◽  
Near Infrared ◽  
Co2 Flux ◽  
Retrieval Algorithm ◽  
Co2 Uptake ◽  
Near Infrared Radiation ◽  
Sources And Sinks ◽  
Satellite Retrievals ◽  
The Impact ◽  
Insight Into

Abstract. The Orbiting Carbon Observatory 2 (OCO-2) is NASA's first satellite dedicated to monitoring CO2 from space and could provide novel insight into CO2 fluxes across the globe. However, one continuing challenge is the development of a robust retrieval algorithm: an estimate of atmospheric CO2 from satellite observations of near-infrared radiation. The OCO-2 retrievals have undergone multiple updates since the satellite's launch, and the retrieval algorithm is now on its ninth version. Some of these retrieval updates, particularly version 8, led to marked changes in the CO2 observations, changes of 0.5 ppm or more. In this study, we evaluate the extent to which current OCO-2 observations can constrain monthly CO2 sources and sinks from the biosphere, and we particularly focus on how this constraint has evolved with improvements to the OCO-2 retrieval algorithm. We find that improvements in the CO2 retrieval are having a potentially transformative effect on satellite-based estimates of the global biospheric carbon balance. The version 7 OCO-2 retrievals formed the basis of early inverse modeling studies using OCO-2 data; these observations are best equipped to constrain the biospheric carbon balance across only continental or hemispheric regions. By contrast, newer versions of the retrieval algorithm yield a far more detailed constraint, and we are able to constrain CO2 budgets for seven global biome-based regions, particularly during the Northern Hemisphere summer when biospheric CO2 uptake is greatest. Improvements to the OCO-2 observations have had the largest impact on glint-mode observations, and we also find the largest improvements in the terrestrial CO2 flux constraint when we include both nadir and glint data.

Pulsed quantum-cascade laser-based sensor for trace-gas detection of carbonyl sulfide

2004 ◽  
Vol 43 (32) ◽  
pp. 6040 ◽  
Author(s):  
Gerard Wysocki ◽  
Matt McCurdy ◽  
Stephen So ◽  
Damien Weidmann ◽  
Chad Roller ◽  
...  
Keyword(s):  
Quantum Cascade Laser ◽  
Carbonyl Sulfide ◽  
Gas Detection ◽  
Trace Gas ◽  
Trace Gas Detection ◽  
Quantum Cascade

scholarly journals Application of quantum cascade lasers to trace gas detection

2015 ◽  
Vol 63 (2) ◽  
pp. 515-525 ◽  
Author(s):  
Z. Bielecki ◽  
T. Stacewicz ◽  
J. Wojtas ◽  
J. Mikołajczyk
Keyword(s):  
Gas Sensors ◽  
Review Paper ◽  
Quantum Cascade Lasers ◽  
Carbonyl Sulfide ◽  
Gas Detection ◽  
Trace Gas ◽  
Quantum Cascade ◽  
Compact Size ◽  
New Applications ◽  
Cascade Lasers

Abstract The potential of Quantum Cascade Laser technology has been recently harnessed in industry, medicine and military to create a range of original infrared gas sensors. These sensors have opened up many new applications due to compact size, excellent sensitivity, robust construction and low power requirements. They rely on infrared absorption spectroscopy to determine identity and quantity of gases. The measurement of these gases has relied on different technologies including multi-pass spectroscopy, photoacoustic spectroscopy, cavity ring down spectroscopy, and their various modifications. In this review paper some technologies are described in terms of its advantages/disadvantages in many application. The results of own works about methane, ammonia, nitric oxide, nitrous oxide, and carbonyl sulfide detection are presented as well

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