Atmospheric bromoform at Cape Point, South Africa: a first time
series on the African continent
Abstract. Bromoform mixing ratios in marine air were measured at Cape Point Global Atmospheric Watch Station, South Africa. This represents the first ever bromoform data set recorded at this unique location. Manual daily measurements were made during a month long field campaign (austral spring 2011) using a GC-ECD with a custom built front end thermal desorption trap. The measured concentrations ranged between 2.3 ± 0.4 and 84.7 ± 10.8 ppt with a mean of 24.7 ± 3.1 ppt. Our analysis shows the concentration of bromform varies significantly according to wind direction and the trajectory of the air mass sampled. Air masses which had come into contact with multiple potential source of bromoform showed the highest average mixing ratios. The measurements reported here represent some of the highest recorded coastal bromoform concentrations globally. These high concentrations may be explained by the multiple local sources of bromoform around Cape Point.