Chemical transformations of Hg° during Arctic mercury depletion events sampled from the NASA DC-8

Abstract. Atmospheric Mercury Depletion Events (MDEs) in Arctic springtime were investigated utilizing a box model based on airborne measurements from the NASA DC-8 during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) field campaign. Measurements showed that MDEs occurred near the surface and always over the Arctic Ocean accompanied by concurrent ozone (O3) depletion, enhancement in Br2 mixing ratios, and decreases in ethyne and light weight alkanes. Backward trajectories indicated that most air masses inside the MDEs originated at low altitude over the ocean presumably generating a halogen-rich environment. We developed a box model which considered only gas phase reactions of mercury, halogen species, and O3 chemistry. We conducted a series of sensitivity simulations to determine the factors that are of most importance to MDE formation. The box model results suggested that continuous enhancement of Br2 mixing ratios, a high intensity of solar radiation, or a relatively high NOx regime expedited Hg° depletion. These environments generated high concentrations of Br radical, and thus the model results indicated that the Br radical was very important for Hg° depletion. Utilizing different rate constants for reaction of Hg° + Br produced times to reach Hg° depletion ranging from 22 to 32 h.

Download Full-text

Characterization of Transport Regimes and the Polar Dome during Arctic Spring and Summer using in-situ Aircraft Measurements

10.5194/acp-2019-70 ◽

2019 ◽

Cited By ~ 3

Author(s):

Heiko Bozem ◽

Peter Hoor ◽

Daniel Kunkel ◽

Franziska Köllner ◽

Johannes Schneider ◽

...

Keyword(s):

Lower Troposphere ◽

High Arctic ◽

The Arctic ◽

Trace Gas ◽

Second Phase ◽

Aerosol Formation ◽

Transport Barrier ◽

Data Set ◽

Air Masses ◽

Mixing Ratios

Abstract. The springtime composition of the Arctic lower troposphere is to a large extent controlled by transport of mid-latitude air masses into the Arctic, whereas during the summer precipitation and natural sources play the most important role. Within the Arctic region, there exists a transport barrier, known as the polar dome, which results from sloping isentropes. The polar dome, which varies in space and time, exhibits a strong influence on the transport of air masses from mid-latitudes, enhancing it during winter and inhibiting it during summer. Furthermore, a definition for the location of the polar dome boundary itself is quite sparse in the literature. We analyzed aircraft based trace gas measurements in the Arctic during two NETCARE airborne field camapigns (July 2014 and April 2015) with the Polar 6 aircraft of Alfred Wegener Institute Helmholtz Center for Polar and Marine Research (AWI), Bremerhaven, Germany, covering an area from Spitsbergen to Alaska (134° W to 17° W and 68° N to 83° N). For the spring (April 2015) and summer (July 2014) season we analyzed transport regimes of mid-latitude air masses travelling to the high Arctic based on CO and CO2 measurements as well as kinematic 10-day back trajectories. The dynamical isolation of the high Arctic lower troposphere caused by the transport barrier leads to gradients of chemical tracers reflecting different local chemical life times and sources and sinks. Particularly gradients of CO and CO2 allowed for a trace gas based definition of the polar dome boundary for the two measurement periods with pronounced seasonal differences. For both campaigns a transition zone rather than a sharp boundary was derived. For July 2014 the polar dome boundary was determined to be 73.5° N latitude and 299–303.5 K potential temperature, respectively. During April 2015 the polar dome boundary was on average located at 66–68.5° N and 283.5–287.5 K. Tracer-tracer scatter plots and probability density functions confirm different air mass properties inside and outside of the polar dome for the July 2014 and April 2015 data set. Using the tracer derived polar dome boundaries the analysis of aerosol data indicates secondary aerosol formation events in the clean summertime polar dome. Synoptic-scale weather systems frequently disturb this transport barrier and foster exchange between air masses from midlatitudes and polar regions. During the second phase of the NETCARE 2014 measurements a pronounced low pressure system south of Resolute Bay brought inflow from southern latitudes that pushed the polar dome northward and significantly affected trace gas mixing ratios in the measurement region. Mean CO mixing ratios increased from 77.9 ± 2.5 ppbv to 84.9 ± 4.7 ppbv from the first period to the second period. At the same time CO2 mixing ratios significantly dropped from 398.16 ± 1.01 ppmv to 393.81 ± 2.25 ppmv. We further analysed processes controlling the recent transport history of air masses within and outside the polar dome. Air masses within the spring time polar dome mainly experienced diabatic cooling while travelling over cold surfaces. In contrast air masses in the summertime polar dome were diabatically heated due to insolation. During both seasons air masses outside the polar dome slowly descended into the Arctic lower troposphere from above caused by radiative cooling. The ascent to the middle and upper troposphere mainly took place outside the Arctic, followed by a northward motion. Our results demonstrate the successful application of a tracer based diagnostic to determine the location of the polar dome boundary.

Download Full-text

Spectral albedo of seasonal snow during intensive melt period at Sodankylä, beyond the Arctic Circle

Atmospheric Chemistry and Physics ◽

10.5194/acp-13-3793-2013 ◽

2013 ◽

Vol 13 (7) ◽

pp. 3793-3810 ◽

Cited By ~ 37

Author(s):

O. Meinander ◽

S. Kazadzis ◽

A. Arola ◽

A. Riihelä ◽

P. Räisänen ◽

...

Keyword(s):

Spectral Irradiance ◽

The Arctic ◽

Visible Range ◽

Air Masses ◽

Clear Sky ◽

Effective Grain Size ◽

European Arctic ◽

Small Absorption ◽

High Concentrations ◽

Double Monochromator

Abstract. We have measured spectral albedo, as well as ancillary parameters, of seasonal European Arctic snow at Sodankylä, Finland (67°22' N, 26°39' E). The springtime intensive melt period was observed during the Snow Reflectance Transition Experiment (SNORTEX) in April 2009. The upwelling and downwelling spectral irradiance, measured at 290–550 nm with a double monochromator spectroradiometer, revealed albedo values of ~0.5–0.7 for the ultraviolet and visible range, both under clear sky and variable cloudiness. During the most intensive snowmelt period of four days, albedo decreased from 0.65 to 0.45 at 330 nm, and from 0.72 to 0.53 at 450 nm. In the literature, the UV and VIS albedo for clean snow are ~0.97–0.99, consistent with the extremely small absorption coefficient of ice in this spectral region. Our low albedo values were supported by two independent simultaneous broadband albedo measurements, and simulated albedo data. We explain the low albedo values to be due to (i) large snow grain sizes up to ~3 mm in diameter; (ii) meltwater surrounding the grains and increasing the effective grain size; (iii) absorption caused by impurities in the snow, with concentration of elemental carbon (black carbon) in snow of 87 ppb, and organic carbon 2894 ppb, at the time of albedo measurements. The high concentrations of carbon, detected by the thermal–optical method, were due to air masses originating from the Kola Peninsula, Russia, where mining and refining industries are located.

Download Full-text

Characterization of transport regimes and the polar dome during Arctic spring and summer using in situ aircraft measurements

Atmospheric Chemistry and Physics ◽

10.5194/acp-19-15049-2019 ◽

2019 ◽

Vol 19 (23) ◽

pp. 15049-15071

Author(s):

Heiko Bozem ◽

Peter Hoor ◽

Daniel Kunkel ◽

Franziska Köllner ◽

Johannes Schneider ◽

...

Keyword(s):

Potential Temperature ◽

Lower Troposphere ◽

High Arctic ◽

Atmospheric Composition ◽

The Arctic ◽

Trace Gas ◽

Chemical Compositions ◽

Second Phase ◽

Air Masses ◽

Mixing Ratios

Abstract. The springtime composition of the Arctic lower troposphere is to a large extent controlled by the transport of midlatitude air masses into the Arctic. In contrast, precipitation and natural sources play the most important role during summer. Within the Arctic region sloping isentropes create a barrier to horizontal transport, known as the polar dome. The polar dome varies in space and time and exhibits a strong influence on the transport of air masses from midlatitudes, enhancing transport during winter and inhibiting transport during summer. We analyzed aircraft-based trace gas measurements in the Arctic from two NETCARE airborne field campaigns (July 2014 and April 2015) with the Alfred Wegener Institute Polar 6 aircraft, covering an area from Spitsbergen to Alaska (134 to 17∘ W and 68 to 83∘ N). Using these data we characterized the transport regimes of midlatitude air masses traveling to the high Arctic based on CO and CO2 measurements as well as kinematic 10 d back trajectories. We found that dynamical isolation of the high Arctic lower troposphere leads to gradients of chemical tracers reflecting different local chemical lifetimes, sources, and sinks. In particular, gradients of CO and CO2 allowed for a trace-gas-based definition of the polar dome boundary for the two measurement periods, which showed pronounced seasonal differences. Rather than a sharp boundary, we derived a transition zone from both campaigns. In July 2014 the polar dome boundary was at 73.5∘ N latitude and 299–303.5 K potential temperature. During April 2015 the polar dome boundary was on average located at 66–68.5∘ N and 283.5–287.5 K. Tracer–tracer scatter plots confirm different air mass properties inside and outside the polar dome in both spring and summer. Further, we explored the processes controlling the recent transport history of air masses within and outside the polar dome. Air masses within the springtime polar dome mainly experienced diabatic cooling while traveling over cold surfaces. In contrast, air masses in the summertime polar dome were diabatically heated due to insolation. During both seasons air masses outside the polar dome slowly descended into the Arctic lower troposphere from above through radiative cooling. Ascent to the middle and upper troposphere mainly took place outside the Arctic, followed by a northward motion. Air masses inside and outside the polar dome were also distinguished by different chemical compositions of both trace gases and aerosol particles. We found that the fraction of amine-containing particles, originating from Arctic marine biogenic sources, is enhanced inside the polar dome. In contrast, concentrations of refractory black carbon are highest outside the polar dome, indicating remote pollution sources. Synoptic-scale weather systems frequently disturb the transport barrier formed by the polar dome and foster exchange between air masses from midlatitudes and polar regions. During the second phase of the NETCARE 2014 measurements a pronounced low-pressure system south of Resolute Bay brought inflow from southern latitudes, which pushed the polar dome northward and significantly affected trace gas mixing ratios in the measurement region. Mean CO mixing ratios increased from 77.9±2.5 to 84.9±4.7 ppbv between these two regimes. At the same time CO2 mixing ratios significantly decreased from 398.16 ± 1.01 to 393.81 ± 2.25 ppmv. Our results demonstrate the utility of applying a tracer-based diagnostic to determine the polar dome boundary for interpreting observations of atmospheric composition in the context of transport history.

Download Full-text

Middle atmospheric water vapour and dynamics in the vicinity of the polar vortex during the Hygrosonde-2 campaign

Atmospheric Chemistry and Physics ◽

10.5194/acp-9-4407-2009 ◽

2009 ◽

Vol 9 (13) ◽

pp. 4407-4417 ◽

Cited By ~ 9

Author(s):

S. Lossow ◽

M. Khaplanov ◽

J. Gumbel ◽

J. Stegman ◽

G. Witt ◽

...

Keyword(s):

Water Vapour ◽

Middle Atmosphere ◽

Polar Vortex ◽

The Arctic ◽

Small Scale ◽

Air Masses ◽

Mixing Ratios ◽

Water Vapour Concentration ◽

Wind Shears

Abstract. The Hygrosonde-2 campaign took place on 16 December 2001 at Esrange/Sweden (68° N, 21° E) with the aim to investigate the small scale distribution of water vapour in the middle atmosphere in the vicinity of the Arctic polar vortex. In situ balloon and rocket-borne measurements of water vapour were performed by means of OH fluorescence hygrometry. The combined measurements yielded a high resolution water vapour profile up to an altitude of 75 km. Using the characteristic of water vapour being a dynamical tracer it was possible to directly relate the water vapour data to the location of the polar vortex edge, which separates air masses of different character inside and outside the polar vortex. The measurements probed extra-vortex air in the altitude range between 45 km and 60 km and vortex air elsewhere. Transitions between vortex and extra-vortex usually coincided with wind shears caused by gravity waves which advect air masses with different water vapour volume mixing ratios. From the combination of the results from the Hygrosonde-2 campaign and the first flight of the optical hygrometer in 1994 (Hygrosonde-1) a clear picture of the characteristic water vapour distribution inside and outside the polar vortex can be drawn. Systematic differences in the water vapour concentration between the inside and outside of the polar vortex can be observed all the way up into the mesosphere. It is also evident that in situ measurements with high spatial resolution are needed to fully account for the small-scale exchange processes in the polar winter middle atmosphere.

Download Full-text

Dynamics of gaseous oxidized mercury at Villum Research Station during the High Arctic summer

Atmospheric Chemistry and Physics ◽

10.5194/acp-21-13287-2021 ◽

2021 ◽

Vol 21 (17) ◽

pp. 13287-13309

Author(s):

Jakob Boyd Pernov ◽

Bjarne Jensen ◽

Andreas Massling ◽

Daniel Charles Thomas ◽

Henrik Skov

Keyword(s):

General Pattern ◽

Ground Level ◽

High Arctic ◽

Atmospheric Mercury ◽

The Arctic ◽

Research Station ◽

Cold Temperatures ◽

Air Masses ◽

Arctic Summer ◽

Gaseous Oxidized Mercury

Abstract. While much research has been devoted to the subject of gaseous elemental mercury (GEM) and gaseous oxidized mercury (GOM) in the Arctic spring during atmospheric mercury depletion events, few studies have examined the behavior of GOM in the High Arctic summer. GOM, once deposited and incorporated into the ecosystem, can pose a threat to human and wildlife health, though there remain large uncertainties regarding the transformation, deposition, and assimilation of mercury into the food web. Therefore, to further our understanding of the dynamics of GOM in the High Arctic during the late summer, we performed measurements of GEM and GOM, along with meteorological parameters and atmospheric constituents, and utilized modeled air mass history during two summer campaigns in 2019 and 2020 at Villum Research Station (Villum) in northeastern Greenland. Seven events of enhanced GOM concentrations were identified and investigated in greater detail. In general, the common factors associated with event periods at ground level were higher levels of radiation and lower H2O mixing ratios, accumulated precipitation, and relative humidity (RH), although none were connected with cold temperatures. Non-event periods at ground level each displayed a different pattern in one or more parameters when compared to event periods. Generally, air masses during event periods for both campaigns were colder and drier, arrived from higher altitudes, and spent more time above the mixed layer and less time in a cloud compared to non-events, although some events deviated from this general pattern. Non-event air masses displayed a different pattern in one or more parameters when compared to event periods, although they were generally warmer and wetter and arrived from lower altitudes with little radiation. Coarse-mode aerosols were hypothesized to provide the heterogenous surface for halogen propagation during some of the events, while for others the source is unknown. While these general patterns were observed for event and non-event periods, analysis of individual events showed more specific origins. Five of the seven events were associated with air masses that experienced similar conditions: transported from the cold, dry, and sunlit free troposphere. However, two events experienced contrasting conditions, with air masses being warm and wet with surface layer contact under little radiation. Two episodes of extremely high levels of NCoarse and BC, which appear to originate from flaring emissions in Russia, did not contribute to enhanced GOM levels. This work aims to provide a better understanding of the dynamics of GOM during the High Arctic summer.

Download Full-text

Airborne observations and modeling of springtime stratosphere-to-troposphere transport over California

Atmospheric Chemistry and Physics Discussions ◽

10.5194/acpd-13-10157-2013 ◽

2013 ◽

Vol 13 (4) ◽

pp. 10157-10192 ◽

Cited By ~ 3

Author(s):

E. L. Yates ◽

L. T. Iraci ◽

M. C. Roby ◽

R. B. Pierce ◽

M. S. Johnson ◽

...

Keyword(s):

Air Quality ◽

Free Troposphere ◽

Air Mass ◽

Air Masses ◽

Airborne Measurements ◽

Mixing Ratios ◽

Stratospheric Intrusion ◽

Tropospheric O3 ◽

Carbon Dioxide Co2 ◽

The Impact

Abstract. Stratosphere-to-troposphere transport (STT) results in air masses of stratospheric origin intruding into the free troposphere. Once in the free troposphere, O3-rich stratospheric air can be transported and mixed with tropospheric air masses, contributing to the tropospheric O3 budget. Evidence of STT can be identified based on the differences in the trace gas composition of the two regions. Because ozone (O3) is present in such large quantities in the stratosphere compared to the troposphere, it is frequently used as a tracer for STT events. This work reports on airborne in situ measurements of O3 and other trace gases during two STT events observed over California, USA. The first, on 14 May 2012, was associated with a cut-off low, and the second, on 5 June 2012, occurred during a post-trough, building ridge event. In each STT event, airborne measurements identified high O3 within a stratospheric intrusion which was observed as low as 3 km above sea level. During both events the stratospheric air mass was characterized by elevated O3 mixing ratios and reduced carbon dioxide (CO2) and water vapor. The reproducible observation of reduced CO2 within the stratospheric air mass supports the use of non-conventional tracers as an additional method for detecting STT. A detailed meteorological analysis of each STT event is presented and observations are interpreted with the Realtime Air Quality Modeling System (RAQMS). The implications of the two STT events are discussed in terms of the impact on the total tropospheric O3 budget and the impact on air quality and policy-making.

Download Full-text

Atmospheric bromoform at Cape Point, South Africa: a first time series on the African continent

10.5194/acp-2017-244 ◽

2017 ◽

Author(s):

Brett Kuyper ◽

Carl J. Palmer ◽

Casper Labuschagne ◽

Chris J. C. Reason

Keyword(s):

South Africa ◽

Austral Spring ◽

Data Set ◽

Air Masses ◽

Mixing Ratios ◽

Front End ◽

Potential Source ◽

High Concentrations ◽

Marine Air ◽

First Time

Abstract. Bromoform mixing ratios in marine air were measured at Cape Point Global Atmospheric Watch Station, South Africa. This represents the first ever bromoform data set recorded at this unique location. Manual daily measurements were made during a month long field campaign (austral spring 2011) using a GC-ECD with a custom built front end thermal desorption trap. The measured concentrations ranged between 2.3 ± 0.4 and 84.7 ± 10.8 ppt with a mean of 24.7 ± 3.1 ppt. Our analysis shows the concentration of bromform varies significantly according to wind direction and the trajectory of the air mass sampled. Air masses which had come into contact with multiple potential source of bromoform showed the highest average mixing ratios. The measurements reported here represent some of the highest recorded coastal bromoform concentrations globally. These high concentrations may be explained by the multiple local sources of bromoform around Cape Point.

Download Full-text

Assimilation of IASI satellite CO fields into a global chemistry transport model for validation against aircraft measurements

Atmospheric Chemistry and Physics ◽

10.5194/acp-12-4493-2012 ◽

2012 ◽

Vol 12 (10) ◽

pp. 4493-4512 ◽

Cited By ~ 19

Author(s):

A. Klonecki ◽

M. Pommier ◽

C. Clerbaux ◽

G. Ancellet ◽

J.-P. Cammas ◽

...

Keyword(s):

Transport Model ◽

Source Region ◽

Specific Treatment ◽

Arctic Region ◽

The Arctic ◽

Chemistry Transport Model ◽

Mixing Ratios ◽

High Concentrations ◽

The Impact

Abstract. This work evaluates the IASI CO product against independent in-situ aircraft data from the MOZAIC program and the POLARCAT aircraft campaign. The validation is carried out by analysing the impact of assimilation of eight months of IASI CO columns retrieved for the period of May to December 2008 into the global chemistry transport model LMDz-INCA. A modelling system based on a sub-optimal Kalman filter was developed and a specific treatment that takes into account the representativeness of observations at the scale of the model grid is applied to the IASI CO columns and associated errors before their assimilation in the model. Comparisons of the assimilated CO profiles with in situ CO measurements indicate that the assimilation leads to a considerable improvement of the model simulations in the middle troposphere as compared with a control run with no assimilation. Model biases in the simulation of background values are reduced and improvement in the simulation of very high concentrations is observed. The improvement is due to the transport by the model of the information present in the IASI CO retrievals. Our analysis also shows the impact of assimilation of CO on the representation of transport into the Arctic region during the POLARCAT summer campaign. A considerable increase in CO mixing ratios over the Asian source region was observed when assimilation was used leading to much higher values of CO during the cross-pole transport episode. These higher values are in good agreement with data from the POLARCAT flights that sampled this plume.

Download Full-text

Pollution Events at the High-Altitude Mountain Site Zugspitze-Schneefernerhaus (2670 m a.s.l.), Germany

Atmosphere ◽

10.3390/atmos10060330 ◽

2019 ◽

Vol 10 (6) ◽

pp. 330 ◽

Cited By ~ 3

Author(s):

Homa Ghasemifard ◽

Felix R. Vogel ◽

Ye Yuan ◽

Marvin Luepke ◽

Jia Chen ◽

...

Keyword(s):

Isotopic Signature ◽

Environmental Research ◽

The Arctic ◽

Research Station ◽

Mean Values ◽

Air Masses ◽

Mixing Ratios ◽

Clean Air ◽

Pollution Events ◽

Keeling Plots

Within the CO2 time series measured at the Environmental Research Station Schneefernerhaus (UFS), Germany, as part of the Global Atmospheric Watch (GAW) program, pollution episodes are traced back to local and regional emissions, identified by δ13C(CO2) as well as ratios of CO and CH4 to CO2 mixing ratios. Seven episodes of sudden enhancements in the tropospheric CO2 mixing ratio are identified in the measurements of mixing/isotopic ratios during five winter months from October 2012 to February 2013. The short-term CO2 variations are closely correlated with changes in CO and CH4 mixing ratios, achieving mean values of 6.0 ± 0.2 ppb/ppm for CO/CO2 and 6.0 ± 0.1 ppb/ppm for CH4/CO2. The estimated isotopic signature of CO2 sources (δs) ranges between −35‰ and −24‰, with higher values indicating contributions from coal combustion or wood burning, and lower values being the result of natural gas or gasoline. Moving Keeling plots with site-specific data selection criteria are applied to detect these pollution events. Furthermore, the HYSPLIT trajectory model is utilized to identify the trajectories during periods with CO2 peak events. Short trajectories are found covering Western and Central Europe, while clean air masses flow from the Atlantic Ocean and the Arctic Ocean.

Download Full-text

Reactive nitrogen, ozone and ozone production in the Arctic troposphere and the impact of stratosphere-troposphere exchange

Atmospheric Chemistry and Physics ◽

10.5194/acp-11-13181-2011 ◽

2011 ◽

Vol 11 (24) ◽

pp. 13181-13199 ◽

Cited By ~ 29

Author(s):

Q. Liang ◽

J. M. Rodriguez ◽

A. R. Douglass ◽

J. H. Crawford ◽

J. R. Olson ◽

...

Keyword(s):

Biomass Burning ◽

Stratospheric Ozone ◽

Arctic Region ◽

Ozone Production ◽

The Arctic ◽

Subsequent Formation ◽

Air Masses ◽

Upper Troposphere ◽

Mixing Ratios ◽

The Impact

Abstract. We use aircraft observations obtained during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) mission to examine the distributions and source attributions of O3 and NOy in the Arctic and sub-Arctic region. Using a number of marker tracers, we distinguish various air masses from the background troposphere and examine their contributions to NOx, O3, and O3 production in the Arctic troposphere. The background Arctic troposphere has a mean O3 of ~60 ppbv and NOx of ~25 pptv throughout spring and summer with CO decreasing from ~145 ppbv in spring to ~100 ppbv in summer. These observed mixing ratios are not notably different from the values measured during the 1988 ABLE-3A and the 2002 TOPSE field campaigns despite the significant changes in emissions and stratospheric ozone layer in the past two decades that influence Arctic tropospheric composition. Air masses associated with stratosphere-troposphere exchange are present throughout the mid and upper troposphere during spring and summer. These air masses, with mean O3 concentrations of 140–160 ppbv, are significant direct sources of O3 in the Arctic troposphere. In addition, air of stratospheric origin displays net O3 formation in the Arctic due to its sustainable, high NOx (75 pptv in spring and 110 pptv in summer) and NOy (~800 pptv in spring and ~1100 pptv in summer). The air masses influenced by the stratosphere sampled during ARCTAS-B also show conversion of HNO3 to PAN. This active production of PAN is the result of increased degradation of ethane in the stratosphere-troposphere mixed air mass to form CH3CHO, followed by subsequent formation of PAN under high NOx conditions. These findings imply that an adequate representation of stratospheric NOy input, in addition to stratospheric O3 influx, is essential to accurately simulate tropospheric Arctic O3, NOx and PAN in chemistry transport models. Plumes influenced by recent anthropogenic and biomass burning emissions observed during ARCTAS show highly elevated levels of hydrocarbons and NOy (mostly in the form of NOx and PAN), but do not contain O3 higher than that in the Arctic tropospheric background except some aged biomass burning plumes sampled during spring. Convection and/or lightning influences are negligible sources of O3 in the Arctic troposphere but can have significant impacts in the upper troposphere in the continental sub-Arctic during summer.

Download Full-text