scholarly journals Enhanced tropospheric BrO concentrations over the Antarctic sea ice belt in mid winter observed from MAX-DOAS observations on board the research vessel Polarstern

2007 ◽  
Vol 7 (1) ◽  
pp. 1823-1847
Author(s):  
T. Wagner ◽  
O. Ibrahim ◽  
R. Sinreich ◽  
U. Frieß ◽  
U. Platt
Keyword(s):  
Sea Ice ◽  
Elevation Angle ◽  
Lower Troposphere ◽  
Satellite Observations ◽  
Research Vessel ◽  
Optical Absorption Spectroscopy ◽  
First Year ◽  
Polar Regions ◽  
Near Surface ◽  
The Antarctic

Abstract. We present Multi AXis-Differential Optical Absorption Spectroscopy (MAX-DOAS) observations of tropospheric BrO carried out on board the German research vessel Polarstern during the Antarctic winter 2006. Polarstern entered the area of first year sea ice around Antarctica on 24 June 2006 and stayed within this area until 15 August 2006. For the period when the ship cruised inside the first year sea ice belt, enhanced BrO concentrations were almost continuously observed. One interesting exception appeared on 7 July 2006, when the sun elevation angle was < about –2.8° indicating that for low insulation the photolysis of Br2 and/or HOBr is too slow to provide sufficient amounts of Br radicals. Before and after the period inside the first year sea ice belt, typically low BrO concentrations were observed. Our observations indicate that enhanced BrO concentrations around Antarctica exist about one month earlier than observed by satellite instruments. The small BrO concentrations over the open oceans indicate a short atmospheric lifetime of activated bromine without contact to areas of first year sea ice. From detailed radiative transfer simulations we find that MAX-DOAS observations are about one order of magnitude more sensitive to near-surface BrO than satellite observations. In contrast to satellite observations the MAX-DOAS sensitivity hardly decreases for large solar zenith angles and is almost independent from the ground albedo. Thus this technique is very well suited for observations in polar regions close to the solar terminator. Furthermore, combination of both techniques could yield additional information on the vertical distribution of BrO in the lower troposphere.

scholarly journals Enhanced tropospheric BrO over Antarctic sea ice in mid winter observed by MAX-DOAS on board the research vessel Polarstern

2007 ◽  
Vol 7 (12) ◽  
pp. 3129-3142 ◽  
Author(s):  
T. Wagner ◽  
O. Ibrahim ◽  
R. Sinreich ◽  
U. Frieß ◽  
R. von Glasow ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Sea Ice ◽  
Vertical Mixing ◽  
Satellite Observations ◽  
Research Vessel ◽  
Optical Absorption Spectroscopy ◽  
Back Trajectory ◽  
First Year ◽  
Polar Regions ◽  
Near Surface

Abstract. We present Multi AXis-Differential Optical Absorption Spectroscopy (MAX-DOAS) observations of tropospheric BrO carried out on board the German research vessel Polarstern during the Antarctic winter 2006. Polarstern entered the area of first year sea ice around Antarctica on 24 June 2006 and stayed within this area until 15 August 2006. For the period when the ship cruised inside the first year sea ice belt, enhanced BrO concentrations were almost continuously observed. Outside the first year sea ice belt, typically low BrO concentrations were found. Based on back trajectory calculations we find a positive correlation between the observed BrO differential slant column densities (ΔSCDs) and the duration for which the air masses had been in contact with the sea ice surface prior to the measurement. While we can not completely rule out that in several cases the highest BrO concentrations might be located close to the ground, our observations indicate that the maximum BrO concentrations might typically exist in a (possibly extended) layer around the upper edge of the boundary layer. Besides the effect of a decreasing pH of sea salt aerosol with altitude and therefore an increase of BrO with height, this finding might be also related to vertical mixing of air from the free troposphere with the boundary layer, probably caused by convection over the warm ocean surface at polynyas and cracks in the ice. Strong vertical gradients of BrO and O3 could also explain why we found enhanced BrO levels almost continuously for the observations within the sea ice. Based on our estimated BrO profiles we derive BrO mixing ratios of several ten ppt, which is slightly higher than many existing observations. Our observations indicate that enhanced BrO concentrations around Antarctica exist about one month earlier than observed by satellite instruments. From detailed radiative transfer simulations we find that MAX-DOAS observations are up to about one order of magnitude more sensitive to near-surface BrO than satellite observations. In contrast to satellite observations the MAX-DOAS sensitivity hardly decreases for large solar zenith angles and is almost independent from the ground albedo. Thus this technique is very well suited for observations in polar regions close to the solar terminator. For large periods of our measurements the solar elevation was very low or even below the horizon. For such conditions, most reactive Br-compounds might exist as Br2 molecules and ozone destruction and the removal of reactive bromine compounds might be substantially reduced.

scholarly journals New insights into the climatic signal from firn cores at the northern Antarctic Peninsula

2017 ◽  
Author(s):  
Francisco Fernandoy ◽  
Dieter Tetzner ◽  
Hanno Meyer ◽  
Guisella Gacitúa ◽  
Kirstin Hoffmann ◽  
...  
Keyword(s):  
Sea Ice ◽  
Antarctic Peninsula ◽  
Isotope Composition ◽  
Accumulation Rate ◽  
Regional Scale ◽  
Inversion Layer ◽  
Lower Troposphere ◽  
High Temporal Resolution ◽  
Near Surface ◽  
The Antarctic

Abstract. The Antarctic Peninsula is one of the most challenging regions of Antarctica from a climatological perspective, owing to the recent atmospheric and oceanic warming. The steep topography and a lack of long–term and in situ meteorological observations complicate extrapolation of existing climate models to the sub-regional scale. Here, we present new evidence from the northern Antarctic Peninsula to demonstrate how stable water isotopes of firn cores and recent precipitation samples can reveal climatic processes related to nearby oceanic and atmospheric conditions. A noticeable effect of the sea ice cover on local temperatures and atmospheric modes, in particular the Southern Annular Mode (SAM), is demonstrated. In years with large sea ice extension in winter (negative SAM anomaly), an inversion layer in the lower troposphere develops at the coastal zone. Therefore, an isotope–temperature relationship valid for all seasons cannot be concluded. The δ–T relationship rather depends on seasonal variability of oceanic conditions. Transitional seasons (autumn and spring) are both stable seasons with an isotope–temperature gradient of +0.69 ‰ °C−1. The firn stable isotope composition reveals that the near–surface temperature at the Antarctic Peninsula shows a decreasing trend (−0.33 °C y−1) between 2008 and 2014. Moreover, the deuterium excess (dexcess) has been demonstrated to be a reliable indicator of seasonal oceanic conditions, and therefore suitable to improve a firn age model based on seasonal dexcess variability. The annual accumulation rate in this region is highly variable, ranging between 1060 kg m−2 y−1 and 2470 kg m−2 y−1 from 2008 to 2014. The combination of isotopic and meteorological data is key for reconstructing recent climatic conditions with a high temporal resolution in polar regions where no direct observation exists

scholarly journals New insights into the use of stable water isotopes at the northern Antarctic Peninsula as a tool for regional climate studies

2018 ◽  
Vol 12 (3) ◽  
pp. 1069-1090 ◽  
Author(s):  
Francisco Fernandoy ◽  
Dieter Tetzner ◽  
Hanno Meyer ◽  
Guisella Gacitúa ◽  
Kirstin Hoffmann ◽  
...  
Keyword(s):  
Sea Ice ◽  
Antarctic Peninsula ◽  
Accumulation Rate ◽  
Meteorological Data ◽  
Regional Scale ◽  
Inversion Layer ◽  
Lower Troposphere ◽  
High Temporal Resolution ◽  
Near Surface ◽  
The Antarctic

Abstract. Due to recent atmospheric and oceanic warming, the Antarctic Peninsula is one of the most challenging regions of Antarctica to understand in terms of both local- and regional-scale climate signals. Steep topography and a lack of long-term and in situ meteorological observations complicate the extrapolation of existing climate models to the sub-regional scale. Therefore, new techniques must be developed to better understand processes operating in the region. Isotope signals are traditionally related mainly to atmospheric conditions, but a detailed analysis of individual components can give new insight into oceanic and atmospheric processes. This paper aims to use new isotopic records collected from snow and firn cores in conjunction with existing meteorological and oceanic datasets to determine changes at the climatic scale in the northern extent of the Antarctic Peninsula. In particular, a discernible effect of sea ice cover on local temperatures and the expression of climatic modes, especially the Southern Annular Mode (SAM), is demonstrated. In years with a large sea ice extension in winter (negative SAM anomaly), an inversion layer in the lower troposphere develops at the coastal zone. Therefore, an isotope–temperature relationship (δ–T) valid for all periods cannot be obtained, and instead the δ–T depends on the seasonal variability of oceanic conditions. Comparatively, transitional seasons (autumn and spring) have a consistent isotope–temperature gradient of +0.69 ‰ °C−1. As shown by firn core analysis, the near-surface temperature in the northern-most portion of the Antarctic Peninsula shows a decreasing trend (−0.33 °C year−1) between 2008 and 2014. In addition, the deuterium excess (dexcess) is demonstrated to be a reliable indicator of seasonal oceanic conditions, and therefore suitable to improve a firn age model based on seasonal dexcess variability. The annual accumulation rate in this region is highly variable, ranging between 1060 and 2470 kg m−2 year−1 from 2008 to 2014. The combination of isotopic and meteorological data in areas where data exist is key to reconstruct climatic conditions with a high temporal resolution in polar regions where no direct observations exist.

scholarly journals The role of open lead interactions in atmospheric ozone variability between Arctic coastal and inland sites

Elem Sci Anth ◽  
2016 ◽  
Vol 4 ◽  
Author(s):  
Peter K. Peterson ◽  
Kerri A. Pratt ◽  
William R. Simpson ◽  
Son V. Nghiem ◽  
Lemuel X. Pérez Pérez ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Sea Ice ◽  
Ozone Depletion ◽  
Surface Ozone ◽  
Optical Absorption Spectroscopy ◽  
Atmospheric Ozone ◽  
Vertical Profiles ◽  
Large Spatial Scale ◽  
Near Surface ◽  
Air Masses

Abstract Boundary layer atmospheric ozone depletion events (ODEs) are commonly observed across polar sea ice regions following polar sunrise. During March-April 2005 in Alaska, the coastal site of Barrow and inland site of Atqasuk experienced ODEs (O3&lt; 10 nmol mol-1) concurrently for 31% of the observations, consistent with large spatial scale ozone depletion. However, 7% of the time ODEs were exclusively observed inland at Atqasuk. This phenomenon also occurred during one of nine flights during the BRomine, Ozone, and Mercury EXperiment (BROMEX), when atmospheric vertical profiles at both sites showed near-surface ozone depletion only at Atqasuk on 28 March 2012. Concurrent in-flight BrO measurements made using nadir scanning differential optical absorption spectroscopy (DOAS) showed the differences in ozone vertical profiles at these two sites could not be attributed to differences in locally occurring halogen chemistry. During both studies, backward air mass trajectories showed that the Barrow air masses observed had interacted with open sea ice leads, causing increased vertical mixing and recovery of ozone at Barrow and not Atqasuk, where the air masses only interacted with tundra and consolidated sea ice. These observations suggest that, while it is typical for coastal and inland sites to have similar ozone conditions, open leads may cause heterogeneity in the chemical composition of the springtime Arctic boundary layer over coastal and inland areas adjacent to sea ice regions.

scholarly journals MAX-DOAS observations of the total atmospheric water vapour column and comparison with independent observations

2013 ◽  
Vol 6 (1) ◽  
pp. 131-149 ◽  
Author(s):  
T. Wagner ◽  
M. O. Andreae ◽  
S. Beirle ◽  
S. Dörner ◽  
K. Mies ◽  
...  
Keyword(s):  
Radiative Transfer ◽  
Water Vapour ◽  
Satellite Observations ◽  
Shielding Effect ◽  
Optical Absorption Spectroscopy ◽  
Atmospheric Water ◽  
Near Surface ◽  
Atmospheric Water Vapour ◽  
Independent Observations ◽  
Good Agreement

Abstract. We developed an algorithm for the retrieval of the atmospheric water vapour column from Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) observations in the yellow and red spectral range. The retrieval is based on the so-called geometric approximation and does not depend on explicit a priori information for individual observations, extensive radiative transfer simulations, or the construction of large look-up tables. Disturbances of the radiative transfer due to aerosols and clouds are simply corrected using the simultaneously measured absorptions of the oxygen dimer, O4. We applied our algorithm to MAX-DOAS observations made at the Max Planck Institute for Chemistry in Mainz, Germany, from March to August 2011, and compared the results to independent observations. Good agreement with Aerosol Robotic Network (AERONET) and European Centre for Medium-Range Weather Forecasting (ECMWF) H2O vertical column densities (VCDs) is found, while the agreement with satellite observations is less good, most probably caused by the shielding effect of clouds for the satellite observations. Good agreement is also found with near-surface in situ observations, and it was possible to derive average daily H2O scale heights (between 1.5 km and 3 km). MAX-DOAS measurements use cheap and simple instrumentation and can be run automatically. One important advantage of our algorithm is that the H2O VCD can be retrieved even under cloudy conditions (except clouds with very high optical thickness).

scholarly journals Albedo of the ice covered Weddell and Bellingshausen Seas

2012 ◽  
Vol 6 (2) ◽  
pp. 479-491 ◽  
Author(s):  
A. I. Weiss ◽  
J. C. King ◽  
T. A. Lachlan-Cope ◽  
R. S. Ladkin
Keyword(s):  
Sea Ice ◽  
Surface Albedo ◽  
Austral Summer ◽  
Open Water ◽  
Weddell Sea ◽  
First Year ◽  
Pack Ice ◽  
Bellingshausen Sea ◽  
The Mean ◽  
The Antarctic

Abstract. This study investigates the surface albedo of the sea ice areas adjacent to the Antarctic Peninsula during the austral summer. Aircraft measurements of the surface albedo, which were conducted in the sea ice areas of the Weddell and Bellingshausen Seas show significant differences between these two regions. The averaged surface albedo varied between 0.13 and 0.81. The ice cover of the Bellingshausen Sea consisted mainly of first year ice and the sea surface showed an averaged sea ice albedo of αi = 0.64 ± 0.2 (± standard deviation). The mean sea ice albedo of the pack ice area in the western Weddell Sea was αi = 0.75 ± 0.05. In the southern Weddell Sea, where new, young sea ice prevailed, a mean albedo value of αi = 0.38 ± 0.08 was observed. Relatively warm open water and thin, newly formed ice had the lowest albedo values, whereas relatively cold and snow covered pack ice had the highest albedo values. All sea ice areas consisted of a mixture of a large range of different sea ice types. An investigation of commonly used parameterizations of albedo as a function of surface temperature in the Weddell and Bellingshausen Sea ice areas showed that the albedo parameterizations do not work well for areas with new, young ice.

Evaluation of regional NWP results for sea ice covered Bothnia Bay (Baltic Sea) in winter 2020.

2021 ◽  
Author(s):  
Marta Wenta ◽  
Agnieszka Herman
Keyword(s):  
Boundary Layer ◽  
Wind Speed ◽  
Sea Ice ◽  
Surface Temperature ◽  
Atmospheric Boundary Layer ◽  
Baltic Sea ◽  
Polar Regions ◽  
Near Surface ◽  
Accurate Representation ◽  
Complex Processes

&lt;p&gt;The ongoing development of NWP (Numerical Weather Prediction) models and their increasing horizontal resolution have significantly improved forecasting capabilities. However, in the polar regions models struggle with the representation of near-surface atmospheric properties and the vertical structure of the atmospheric boundary layer (ABL) over sea ice. Particularly difficult to resolve are near-surface temperature, wind speed, and humidity, along with diurnal changes of those properties. Many of the complex processes happening at the interface of sea ice and atmosphere, i.e. vertical fluxes, turbulence, atmosphere - surface coupling are poorly parameterized or not represented in the models at all. Limited data coverage and our poor understanding of the complex processes taking place in the polar ABL limit the development of suitable parametrizations. We try to contribute to the ongoing effort to improve the forecast skill in polar regions through the analysis of unmanned aerial vehicles (UAVs) and automatic weather station (AWS) atmospheric measurements from the coastal area of Bothnia Bay (Wenta et. al., 2021), and the application of those datasets for the analysis of regional NWP models' forecasts.&amp;#160;&lt;/p&gt;&lt;p&gt;Data collected during HAOS (Hailuoto Atmospheric Observations over Sea ice) campaign (Wenta et. al., 2021) is used for the evaluation of regional NWP models results from AROME (Applications of Research to Operations at Mesoscale) - Arctic, HIRLAM (High Resolution Limited Area Model) and WRF (Weather Research and Forecasting). The presented analysis focuses on 27 Feb. 2020 - 2 Mar. 2020, the time of the HAOS campaign, shortly after the formation of new, thin sea ice off the westernmost point of Hailuoto island.&amp;#160; Throughout the studied period weather conditions changed from very cold (-14&amp;#8451;), dry and cloud-free to warmer (~ -5&amp;#8451;), more humid and opaquely cloudy. We evaluate models&amp;#8217; ability to correctly resolve near-surface temperature, humidity, and wind speed, along with vertical changes of temperature and humidity over the sea ice. It is found that generally, models struggle with an accurate representation of surface-based temperature inversions, vertical variations of humidity, and temporal wind speed changes. Furthermore, a WRF Single Columng Model (SCM) is launched to study whether specific WRF planetary boundary layer parameterizations (MYJ, YSU, MYNN, QNSE), vertical resolution, and more accurate representation of surface conditions increase the WRF model&amp;#8217;s ability to resolve the ABL above sea ice in the Bay of Bothnia. Experiments with WRF SCM are also used to determine the possible reasons behind model&amp;#8217;s biases. Preliminary results show that accurate representation of sea ice conditions, including thickness, surface temperature, albedo, and snow coverage is crucial for increasing the quality of NWP models forecasts. We emphasize the importance of further development of parametrizations focusing on the processes at the sea ice-atmosphere interface.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;Reference:&lt;/p&gt;&lt;p&gt;Wenta, M., Brus, D., Doulgeris, K., Vakkari, V., and Herman, A.: Winter atmospheric boundary layer observations over sea ice in the coastal zone of the Bay of Bothnia (Baltic Sea), Earth Syst. Sci. Data, 13, 33&amp;#8211;42, https://doi.org/10.5194/essd-13-33-2021, 2021.&amp;#160;&lt;/p&gt;&lt;p&gt;&lt;br&gt;&lt;br&gt;&lt;br&gt;&lt;br&gt;&lt;br&gt;&lt;br&gt;&lt;/p&gt;

scholarly journals Measuring the Vertical Profiles of Aerosol Extinction in the Lower Troposphere by MAX-DOAS at a Rural Site in the North China Plain

Atmosphere ◽  
2020 ◽  
Vol 11 (10) ◽  
pp. 1037
Author(s):  
Siyang Cheng ◽  
Junli Jin ◽  
Jianzhong Ma ◽  
Xiaobin Xu ◽  
Liang Ran ◽  
...  
Keyword(s):  
North China Plain ◽  
North China ◽  
Lower Troposphere ◽  
Temporal Variations ◽  
Rural Site ◽  
Optical Absorption Spectroscopy ◽  
Aerosol Extinction ◽  
Vertical Profiles ◽  
Near Surface ◽  
The North

Ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) measurements were performed during the summer (13 June–20 August) of 2014 at a rural site in North China Plain. The vertical profiles of aerosol extinction (AE) in the lower troposphere were retrieved to analyze the temporal variations of AE profiles, near-surface AE, and aerosol optical depth (AOD). The average AOD and near-surface AE over the period of study were 0.51 ± 0.26 and 0.33 ± 0.18 km−1 during the effective observation period, respectively. High AE events and elevated AE layers were identified based on the time series of hourly AE profiles, near-surface AEs and AODs. It is found that in addition to the planetary boundary layer height (PBLH) and relative humidity (RH), the variations in the wind field have large impacts on the near-surface AE, AOD, and AE profile. Among 16 wind sectors, higher AOD or AE occur mostly in the directions of the cities upstream. The diurnal variations of the AE profiles, AODs and near-surface AEs are significant and influenced mainly by the source emissions, PBLH, and RH. The AE profile shape from MAX-DOAS measurement is generally in agreement with that from light detection and ranging (lidar) observations, although the AE absolute levels are different. Overall, ground-based MAX-DOAS can serve as a supplement to measure the AE vertical profiles in the lower troposphere.

scholarly journals The mechanical properties of saline ice under uniaxial compression

1994 ◽  
Vol 19 ◽  
pp. 39-48 ◽  
Author(s):  
Gary A. Kuehn ◽  
Erland M. Schulson
Keyword(s):  
Mechanical Properties ◽  
Sea Ice ◽  
Strain Rate ◽  
Uniaxial Compression ◽  
Growth Direction ◽  
First Year ◽  
Polar Regions ◽  
Deformation And Fracture ◽  
Specimen Orientation ◽  
Ductile To Brittle Transition

Understanding the mechanical properties of saline ice is important for engineering design as well as for operations in polar regions. In order to gain understanding of the basic mechanisms of deformation and fracture, laboratory-grown columnar saline ice, representative of first-year sea ice, was tested in uniaxial compression under a variety of conditions of Strain rate (10−7to 10−1s−1), temper-aiure (−40°, −20°, −10° and −5°C) and orientation (loading vertically or horizontally: i.e. parallel or perpendicular to the growth direction). The range of strain rate spanned the ductile-to-brittle transition for every combination of temperature and specimen orientation. The results of over 250 tests are reported. Mechanical properties, failure mode and ice structure are analyzed with respect to the testing conditons. The results show that strength is dependent upon the ice structure, orientation, strain rate and temperature. During loading in the ductile regime the structure is altered (e.g. by recrystallization), whereas in the brittle regime the majority of the structural change is through cracking. The results are compared to results from the literature on both natural sea ice and laboratory-grown saline ice. Where possible, they are interpreted in terms of micromechanica] models.

scholarly journals MAX-DOAS measurements of NO<sub>2</sub>, SO<sub>2</sub>, HCHO, and BrO at the Mt. Waliguan WMO GAW global baseline station in the Tibetan Plateau

2020 ◽  
Vol 20 (11) ◽  
pp. 6973-6990 ◽  
Author(s):  
Jianzhong Ma ◽  
Steffen Dörner ◽  
Sebastian Donner ◽  
Junli Jin ◽  
Siyang Cheng ◽  
...  
Keyword(s):  
Tibetan Plateau ◽  
Trace Gases ◽  
Elevation Angle ◽  
Lower Troposphere ◽  
Statistical Error ◽  
Tropospheric Chemistry ◽  
Ozone Production ◽  
Optical Absorption Spectroscopy ◽  
The Tibetan Plateau ◽  
Mixing Ratios

Abstract. Mt. Waliguan Observatory (WLG) is a World Meteorological Organization (WMO) Global Atmosphere Watch (GAW) global baseline station in China. WLG is located at the northeastern part of the Tibetan Plateau (36∘17′ N, 100∘54′ E, 3816 m a.s.l.) and is representative of the pristine atmosphere over the Eurasian continent. We made long-term ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) measurements at WLG during the period 2012–2015. In this study, we retrieve the differential slant column densities (dSCDs) and estimate the tropospheric background mixing ratios of different trace gases, including NO2, SO2, HCHO, and BrO, using the measured spectra at WLG. Averaging of 10 original spectra is found to be an “optimum option” for reducing both the statistical error of the spectral retrieval and systematic errors in the analysis. The dSCDs of NO2, SO2, HCHO, and BrO under clear-sky and low-aerosol-load conditions are extracted from measured spectra at different elevation angles at WLG. By performing radiative transfer simulations with the model TRACY-2, we establish approximate relationships between the trace gas dSCDs at 1∘ elevation angle and the corresponding average tropospheric background volume mixing ratios. Mixing ratios of these trace gases in the lower troposphere over WLG are estimated to be in a range of about 7 ppt (January) to 100 ppt (May) for NO2, below 0.5 ppb for SO2, between 0.4 and 0.9 ppb for HCHO, and lower than 0.3 ppt for BrO. The chemical box model simulations constrained by the NO2 concentration from our MAX-DOAS measurements show that there is a little net ozone loss (−0.8 ppb d−1) for the free-tropospheric conditions and a little net ozone production (0.3 ppb d−1) for the boundary layer conditions over WLG during summertime. Our study provides valuable information and data sets for further investigating tropospheric chemistry in the background atmosphere and its links to anthropogenic activities.

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