scholarly journals Quantification of toxic metals using machine learning techniques and spark emission spectroscopy

2020 ◽  
Vol 13 (10) ◽  
pp. 5369-5377
Author(s):  
Seyyed Ali Davari ◽  
Anthony S. Wexler
Keyword(s):  
Machine Learning ◽  
Real Time ◽  
Toxic Metals ◽  
Emission Spectroscopy ◽  
Cost Effective ◽  
The United States ◽  
Machine Learning Techniques ◽  
Learning Techniques ◽  
Single Feature ◽  
Us Epa

Abstract. The United States Environmental Protection Agency (US EPA) list of hazardous air pollutants (HAPs) includes toxic metal suspected or associated with development of cancer. Traditional techniques for detecting and quantifying toxic metals in the atmosphere are either not real time, hindering identification of sources, or limited by instrument costs. Spark emission spectroscopy is a promising and cost-effective technique that can be used for analyzing toxic metals in real time. Here, we have developed a cost-effective spark emission spectroscopy system to quantify the concentration of toxic metals targeted by the US EPA. Specifically, Cr, Cu, Ni, and Pb solutions were diluted and deposited on the ground electrode of the spark emission system. The least absolute shrinkage and selection operator (LASSO) was optimized and employed to detect useful features from the spark-generated plasma emissions. The optimized model was able to detect atomic emission lines along with other features to build a regression model that predicts the concentration of toxic metals from the observed spectra. The limits of detections (LODs) were estimated using the detected features and compared to the traditional single-feature approach. LASSO is capable of detecting highly sensitive features in the input spectrum; however, for some toxic metals the single-feature LOD marginally outperforms LASSO LOD. The combination of low-cost instruments with advanced machine learning techniques for data analysis could pave the path forward for data-driven solutions to costly measurements.

scholarly journals Quantification of toxic metallic elements using machine learning techniques and spark emission spectroscopy

2019 ◽  
Author(s):  
Seyyed Ali Davari ◽  
Anthony S. Wexler
Keyword(s):  
Machine Learning ◽  
Real Time ◽  
Emission Spectroscopy ◽  
Cost Effective ◽  
The United States ◽  
Machine Learning Techniques ◽  
Metallic Elements ◽  
Learning Techniques ◽  
Single Feature ◽  
Us Epa

Abstract. The United States Environmental Protection Agency (US EPA) list of Hazardous Air Pollutants (HAPs) includes metal elements suspected or associated with development of cancer. Traditional techniques for detecting and quantifying toxic metallic elements in the atmosphere are either not real time, hindering identification of sources, or limited by instrument costs. Spark emission spectroscopy is a promising and cost effective technique that can be used for analyzing toxic metallic elements in real time. Here, we have developed a cost-effective spark emission spectroscopy system to quantify the concentration of toxic metallic elements targeted by US EPA. Specifically, Cr, Cu, Ni, and Pb solutions were diluted and deposited on the ground electrode of the spark emission system. Least Absolute Shrinkage and Selection Operator (LASSO) was optimized and employed to detect useful features from the spark-generated plasma emissions. The optimized model was able to detect atomic emission lines along with other features to build a regression model that predicts the concentration of toxic metallic elements from the observed spectra. The limits of detections (LOD) were estimated using the detected features and compared to the traditional single-feature approach. LASSO is capable of detecting highly sensitive features in the input spectrum; however for some elements the single-feature LOD marginally outperforms LASSO LOD. The combination of low cost instruments with advanced machine learning techniques for data analysis could pave the path forward for data driven solutions to costly measurements.

scholarly journals Near real-time air quality forecasts using the NASA GEOS model

2021 ◽  
Author(s):  
K. Emma Knowland ◽  
Christoph Keller ◽  
Krzysztof Wargan ◽  
Brad Weir ◽  
Pamela Wales ◽  
...  
Keyword(s):  
Machine Learning ◽  
Air Quality ◽  
Real Time ◽  
Weather Forecasting ◽  
Atmospheric Composition ◽  
Machine Learning Techniques ◽  
Learning Techniques ◽  
Wide Range ◽  
Reactive Trace Gases ◽  
Assimilation System

<p>NASA's Global Modeling and Assimilation Office (GMAO) produces high-resolution global forecasts for weather, aerosols, and air quality. The NASA Global Earth Observing System (GEOS) model has been expanded to provide global near-real-time 5-day forecasts of atmospheric composition at unprecedented horizontal resolution of 0.25 degrees (~25 km). This composition forecast system (GEOS-CF) combines the operational GEOS weather forecasting model with the state-of-the-science GEOS-Chem chemistry module (version 12) to provide detailed analysis of a wide range of air pollutants such as ozone, carbon monoxide, nitrogen oxides, and fine particulate matter (PM2.5). Satellite observations are assimilated into the system for improved representation of weather and smoke. The assimilation system is being expanded to include chemically reactive trace gases. We discuss current capabilities of the GEOS Constituent Data Assimilation System (CoDAS) to improve atmospheric composition modeling and possible future directions, notably incorporating new observations (TROPOMI, geostationary satellites) and machine learning techniques. We show how machine learning techniques can be used to correct for sub-grid-scale variability, which further improves model estimates at a given observation site.</p>

Primary Factors Influencing the Decision to Vaccinate Against COVID-19 in the United States: A Predictive Analytics Approach (Preprint)

2021 ◽  
Author(s):  
Serkan Varol ◽  
Serkan Catma ◽  
Diana Reindl ◽  
Elizabeth Serieux
Keyword(s):  
Machine Learning ◽  
Decision Making ◽  
Predictive Analytics ◽  
The United States ◽  
Machine Learning Techniques ◽  
Vaccine Hesitancy ◽  
Willingness To Accept ◽  
Perceptions And Attitudes ◽  
Learning Techniques ◽  
Vaccine Decision Making

BACKGROUND Vaccine refusal still poses a risk to reaching herd immunity in the United States. The existing literature focuses on identifying the predictors that would impact the willingness to accept (WTA) vaccines using survey data. These variables range from the socio-demographic characteristics of the participants to the perceptions and attitudes towards the vaccines so each variable’s statistical relationship with the WTA a vaccine can be investigated. However, while the results of these studies may have important implications for understanding vaccine hesitancy by offering interpretation of the statistical relationships, the prediction of vaccine decision-making has rarely been investigated OBJECTIVE We aimed to identify the factors that contribute to the prediction of COVID-19 vaccine acceptors and refusers using machine learning METHODS A nationwide survey was administered online in November, 2020 to assess American public perceptions and attitudes towards COVID-19 vaccines. Seven machine learning techniques were utilized to identify the model with the highest predictive power. Moreover, a set of variables that would contribute the most to the predictions of vaccine acceptors and refusers was identified using Gini importance based on Random Forest structure RESULTS The resulting machine learning algorithm has better prediction ability for willingness to accept (82%) versus reject (51%) a COVID-19 vaccine. In terms of predictive success, the Random Forest model outperformed the other machine learning techniques with a 69.52% accuracy rate. Worrying about (re) contracting Covid 19 and opinions regarding mandatory face covering were identified as the most important predictors of vaccine decision-making CONCLUSIONS The complexity of vaccine hesitancy needs to be investigated thoroughly before the threshold needed to reach population immunity can be achieved. Predictive analytics can help the public health officials design and deliver individually tailored vaccination programs that would increase the overall vaccine uptake.

Machine Learning Techniques to Identify and Characterize Sleep Disorders Using Biosignals

2021 ◽  
pp. 136-160
Author(s):  
Mercedes Barrachina ◽  
Laura Valenzuela López
Keyword(s):  
Machine Learning ◽  
Sleep Disorders ◽  
Adult Population ◽  
The United States ◽  
Machine Learning Techniques ◽  
Future Research ◽  
Research Directions ◽  
Learning Techniques ◽  
Control And Prevention ◽  
Future Research Directions

Sleep disorders are related to many different diseases, and they could have a significant impact in patients' health, causing an economic impact to the society and to the national health systems. In the United States, according to information from the Center for Disease Control and Prevention, those disorders are affecting 50-70 million in the adult population. Sleep disorders are causing annually around 40,000 deaths due to cardiovascular problems, and they cost the health system more than 16 billion. In other countries, such as in Spain, those disorders affect up to 48% of the adult population. The main objective of this chapter is to review and evaluate the different machine learning techniques utilized by researchers and medical professionals to identify, assess, and characterize sleep disorders. Moreover, some future research directions are proposed considering the evaluated area.

scholarly journals Machine learning analysis of lifeguard flag decisions and recorded rescues

2019 ◽  
Vol 19 (11) ◽  
pp. 2541-2549
Author(s):  
Chris Houser ◽  
Jacob Lehner ◽  
Nathan Cherry ◽  
Phil Wernette
Keyword(s):  
Machine Learning ◽  
The United States ◽  
Machine Learning Techniques ◽  
Public Health Issue ◽  
Rip Currents ◽  
Effective Strategies ◽  
Wave Forcing ◽  
Learning Techniques ◽  
Yellow Flag ◽  
The Impact

Abstract. Rip currents and other surf hazards are an emerging public health issue globally. Lifeguards, warning flags, and signs are important, and to varying degrees they are effective strategies to minimize risk to beach users. In the United States and other jurisdictions around the world, lifeguards use coloured flags (green, yellow, and red) to indicate whether the danger posed by the surf and rip hazard is low, moderate, or high respectively. The choice of flag depends on the lifeguard(s) monitoring the changing surf conditions along the beach and over the course of the day using both regional surf forecasts and careful observation. There is a potential that the chosen flag is not consistent with the beach user perception of the risk, which may increase the potential for rescues or drownings. In this study, machine learning is used to determine the potential for error in the flags used at Pensacola Beach and the impact of that error on the number of rescues. Results of a decision tree analysis indicate that the colour flag chosen by the lifeguards was different from what the model predicted for 35 % of days between 2004 and 2008 (n=396/1125). Days when there is a difference between the predicted and posted flag colour represent only 17 % of all rescue days, but those days are associated with ∼60 % of all rescues between 2004 and 2008. Further analysis reveals that the largest number of rescue days and total number of rescues are associated with days where the flag deployed over-estimated the surf and hazard risk, such as a red or yellow flag flying when the model predicted a green flag would be more appropriate based on the wind and wave forcing alone. While it is possible that the lifeguards were overly cautious, it is argued that they most likely identified a rip forced by a transverse-bar and rip morphology common at the study site. Regardless, the results suggest that beach users may be discounting lifeguard warnings if the flag colour is not consistent with how they perceive the surf hazard or the regional forecast. Results suggest that machine learning techniques have the potential to support lifeguards and thereby reduce the number of rescues and drownings.

A Novel Data Mining on Breast Cancer Survivability Using MLP Ensemble Learners

2019 ◽  
Vol 63 (3) ◽  
pp. 435-447
Author(s):  
Mohsen Salehi ◽  
Jafar Razmara ◽  
Shahriar Lotfi
Keyword(s):  
Breast Cancer ◽  
Machine Learning ◽  
Data Mining ◽  
Cancer Patients ◽  
Cancer Incidence ◽  
The United States ◽  
Machine Learning Techniques ◽  
Breast Cancer Patients ◽  
Stacked Generalization ◽  
Learning Techniques

Abstract Breast cancer survivability has always been an important and challenging issue for researchers. Different methods have been utilized mostly based on machine learning techniques for prediction of survivability among cancer patients. The most comprehensive available database of cancer incidence is SEER in the United States, which has been frequently used for different research purposes. In this paper, a new data mining has been performed on the SEER database in order to investigate the ability of machine learning techniques for survivability prediction of breast cancer patients. To this end, the data related to breast cancer incidence have been preprocessed to remove unusable records from the dataset. In sequel, two machine learning techniques were developed based on the Multi-Layer Perceptron (MLP) learner machine including MLP stacked generalization and mixture of MLP-experts to make predictions over the database. The machines have been evaluated using K-fold cross-validation technique. The evaluation of the predictors revealed an accuracy of 84.32% and 83.86% by the mixture of MLP-experts and MLP stacked generalization methods, respectively. This indicates that the predictors can be significantly used for survivability prediction suggesting time- and cost-effective treatment for breast cancer patients.

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