scholarly journals The "Lung": a software-controlled air accumulator for quasi-continuous multi-point measurement of agricultural greenhouse gases

2011 ◽  
Vol 4 (10) ◽  
pp. 2293-2303 ◽  
Author(s):  
R. J. Martin ◽  
A. M. Bromley ◽  
M. J. Harvey ◽  
R. C. Moss ◽  
E. Pattey ◽  
...  
Keyword(s):  
Sequential Analysis ◽  
Laser System ◽  
N2o Emissions ◽  
Discrete Sample ◽  
Measuring Surface ◽  
Wide Range ◽  
Current Design ◽  
Tuneable Diode Laser ◽  
N2o Fluxes ◽  
Continuous Field

Abstract. We describe the design and testing of a flexible bag ("Lung") accumulator attached to a gas chromatographic (GC) analyzer capable of measuring surface-atmosphere greenhouse gas exchange fluxes in a wide range of environmental/agricultural settings. In the design presented here, the Lung can collect up to three gas samples concurrently, each accumulated into a Tedlar bag over a period of 20 min or longer. Toggling collection between 2 sets of 3 bags enables quasi-continuous collection with sequential analysis and discarding of sample residues. The Lung thus provides a flexible "front end" collection system for interfacing to a GC or alternative analyzer and has been used in 2 main types of application. Firstly, it has been applied to micrometeorological assessment of paddock-scale N2O fluxes, discussed here. Secondly, it has been used for the automation of concurrent emission assessment from three sheep housed in metabolic crates with gas tracer addition and sampling multiplexed to a single GC. The Lung allows the same GC equipment used in laboratory discrete sample analysis to be deployed for continuous field measurement. Continuity of measurement enables spatially-averaged N2O fluxes in particular to be determined with greater accuracy, given the highly heterogeneous and episodic nature of N2O emissions. We present a detailed evaluation of the micrometeorological flux estimation alongside an independent tuneable diode laser system, reporting excellent agreement between flux estimates based on downwind vertical concentration differences. Whilst the current design is based around triplet bag sets, the basic design could be scaled up to a larger number of inlets or bags and less frequent analysis (longer accumulation times) where a greater number of sampling points are required.

scholarly journals The "Lung": a software-controlled air accumulator for quasi-continuous multi-point measurement of agricultural greenhouse gases

2011 ◽  
Vol 4 (2) ◽  
pp. 1935-1962 ◽  
Author(s):  
R. J. Martin ◽  
A. M. Bromley ◽  
M. J. Harvey ◽  
R. C. Moss ◽  
E. Pattey ◽  
...  
Keyword(s):  
Sequential Analysis ◽  
Laser System ◽  
N2o Emissions ◽  
Discrete Sample ◽  
Wide Range ◽  
Current Design ◽  
Tuneable Diode Laser ◽  
N2o Fluxes ◽  
Continuous Field ◽  
Design And Testing

Abstract. We describe the design and testing of a flexible bag ("Lung") accumulator attached to a gas chromatographic (GC) analyzer capable of measuring greenhouse gas emissive fluxes in a wide range of environmental/agricultural settings. In the design presented here, the Lung can collect up to three gas samples concurrently, each accumulated into a Tedlar® bag over a period of 20 min or longer. Toggling collection between 2 sets of 3 bags enables quasi-continuous collection with sequential analysis and discarding of sample residues. The Lung thus provides a flexible "front end" collection system for interfacing to a GC or alternative analyzer and has been used in 2 main types of application. Firstly, it has been applied to micrometeorological assessment of paddock-scale N2O fluxes. Secondly, it has been used for the automation of concurrent emission assessment from three flux chambers, multiplexed to a single GC. The Lung allows the same GC equipment used in laboratory discrete sample analysis to be deployed for continuous field measurement. Continuity of measurement enables spatially-averaged N2O fluxes in particular to be determined with greater accuracy, given the highly heterogeneous and episodic nature of N2O emissions. We present a detailed evaluation of the micrometeorological flux estimation alongside an independent tuneable diode laser system, reporting excellent agreement between flux estimates based on downwind vertical concentration differences. Whilst the current design is based around triplet bag sets, the basic design could be scaled up to a larger number of inlets or bags and less frequent analysis (longer accumulation times) where a greater number of sampling points are required.

scholarly journals Water Salinity Should Be Reduced for Irrigation to Minimize Its Risk of Increased Soil N2O Emissions

2018 ◽  
Vol 15 (10) ◽  
pp. 2114 ◽  
Author(s):  
Qi Wei ◽  
Junzeng Xu ◽  
Linxian Liao ◽  
Yawei Li ◽  
Haiyu Wang ◽  
...  
Keyword(s):  
Saline Water ◽  
N2o Emission ◽  
Salinity Level ◽  
N2o Emissions ◽  
Low Salinity ◽  
Nitrogen Inputs ◽  
Salinity Levels ◽  
N2o Fluxes ◽  
Moisture Dynamics ◽  
Irrigated Soils

To reveal the effect of irrigation salinity on soil nitrous oxide (N2O) emission, pot experiments were designed with three irrigation salinity levels (NaCl and CaCl2 of 1, 2.5 and 4 g/L equivalence, Ec = 3.6, 8.1 and 12.7 ds/m), either for 0 kg N/ha (N0) or 120 kg N/ha (N120) nitrogen inputs. N2O emissions from soils irrigated at different salinity levels varied in a similar pattern which was triggered by soil moisture dynamics. Yet, the magnitudes of pulse N2O fluxes were significantly varied, with the peak flux at 5 g/L irrigation salinity level being much higher than at 2 and 8 g/L. Compared to fresh water irrigated soils, cumulative N2O fluxes were reduced by 22.7% and 39.6% (N0), 29.1% and 39.2% (N120) for soils irrigated with 2 and 8 g/L saline water, while they were increased by 87.7% (N0) and 58.3% (N120) for soils irrigated with 5 g/L saline water. These results suggested that the effect degree of salinity on consumption and production of N2O might vary among irrigation salinity ranges. As such, desalinating brackish water to a low salinity level (such as 2 g/L) before it is used for irrigation might be helpful for solving water resources crises and mitigating soil N2O emissions.

scholarly journals Spatial and temporal variability of nitrous oxide emissions in a mixed farming landscape of Denmark

2012 ◽  
Vol 9 (8) ◽  
pp. 2989-3002 ◽  
Author(s):  
K. Schelde ◽  
P. Cellier ◽  
T. Bertolini ◽  
T. Dalgaard ◽  
T. Weidinger ◽  
...  
Keyword(s):  
Land Use ◽  
Nitrous Oxide ◽  
Agricultural Land ◽  
Nitrous Oxide Emissions ◽  
Soil Conditions ◽  
Spatial And Temporal Variability ◽  
N2o Emissions ◽  
N2o Production ◽  
Mixed Farming ◽  
N2o Fluxes

Abstract. Nitrous oxide (N2O) emissions from agricultural land are variable at the landscape scale due to variability in land use, management, soil type, and topography. A field experiment was carried out in a typical mixed farming landscape in Denmark, to investigate the main drivers of variations in N2O emissions, measured using static chambers. Measurements were made over a period of 20 months, and sampling was intensified during two weeks in spring 2009 when chambers were installed at ten locations or fields to cover different crops and topography and slurry was applied to three of the fields. N2O emissions during spring 2009 were relatively low, with maximum values below 20 ng N m−2 s−1. This applied to all land use types including winter grain crops, grasslands, meadows, and wetlands. Slurry application to wheat fields resulted in short-lived two-fold increases in emissions. The moderate N2O fluxes and their moderate response to slurry application were attributed to dry soil conditions due to the absence of rain during the four previous weeks. Cumulative annual emissions from two arable fields that were both fertilized with mineral fertilizer and manure were large (17 kg N2O-N ha−1 yr−1 and 5.5 kg N2O-N ha−1 yr−1) during the previous year when soil water conditions were favourable for N2O production during the first month following fertilizer application. Our findings confirm the importance of weather conditions as well as nitrogen management on N2O fluxes.

scholarly journals Trace gas fluxes of CO<sub>2</sub>, CH<sub>4</sub> and N<sub>2</sub>O in a permanent grassland soil exposed to elevated CO<sub>2</sub> in the Giessen FACE study

2011 ◽  
Vol 11 (17) ◽  
pp. 9333-9342 ◽  
Author(s):  
M. Kaleem Abbasi ◽  
C. Müller
Keyword(s):  
Elevated Co2 ◽  
15N Tracer ◽  
Organic N ◽  
N2o Emissions ◽  
Ch4 Oxidation ◽  
N2o Production ◽  
N Application ◽  
Oxidation Rates ◽  
Controlled Conditions ◽  
N2o Fluxes

Abstract. Long-term field observations showed that N2O fluxes observed shortly after N application were not significantly affected by elevated CO2 in the Giessen Free Air Carbon dioxide Enrichment (FACE) study. To further investigate this unexpected result a 15N tracer study was carried out under controlled conditions where in parallel treatments either the NH4+ pool (15NH4NO3) or the NO3− pool (NH415NO3) was enriched with 15N. Fluxes of CO2, CH4, and N2O as well as the 15N enrichment of the N2O were measured. Denitrifying Enzyme Activity (DEA), total denitrification (N2 + N2O) and N2-to-N2O ratios were quantified in separate experiments. Over the 57 day incubation, N2O fluxes averaged 0.090 ng N2O-N g−1 h−1 under ambient and 0.083 ng N2O-N g−1 h−1 under elevated CO2 (not significantly different). The N2O production processes were identified by a two-source model. Results showed that N2O must have also been produced by a third source – possibly related to organic N transformation – which was stimulated by elevated CO2. Soil CO2 fluxes were approximately 20 % higher under elevated CO2 than soil from ambient but the differences were not significant. CH4 oxidation rates were on average −1.75 ng CH4-C g−1 h−1 in the elevated and −1.17 ng CH4-C g−1 h−1 in the ambient indicating that elevated CO2 increased the CH4 oxidation by 49 % compared to ambient CO2 under controlled conditions. N fertilization increased CH4 oxidation by 3-fold in both CO2 treatments. CO2 did not have any significant effect on DEA while total denitrification and N2-to-N2O ratios increased by 36 and 33 %, respectively. The results indicate that shortly after N application elevated CO2 must have stimulated both the N2O production and reduction to N2 to explain the increased N2-to-N2O ratio and at the same time explain the non-responsiveness of the N2O emissions. Thus, the observed variation of the CO2 effect on N2O emissions throughout the year is possibly governed by the dynamics of the N2O reductase activity.

scholarly journals Review of key causes and sources for N<sub>2</sub>O emissions and NO<sub>3</sub>-leaching from organic arable crop rotations

2018 ◽  
Author(s):  
Sissel Hansen ◽  
Randi Berland Frøseth ◽  
Maria Stenberg ◽  
Jarosław Stalenga ◽  
Jørgen E. Olesen ◽  
...  
Keyword(s):  
Organic Matter ◽  
Nitrate Leaching ◽  
Organic Production ◽  
Crop Rotations ◽  
Organic Fertilizers ◽  
N2o Emissions ◽  
Catch Crops ◽  
Arable Crop ◽  
N2o Fluxes ◽  
The Impact

Abstract. The emissions of nitrous oxide (N2O) and leaching of nitrate (NO3) have considerable negative impacts on climate and the environment. Although these environmental burdens are on average less per unit area in organic than in non-organic production, they are not smaller per unit of product. If organic farming is to maintain its goal of being an environmentally friendly production system, these emissions should be mitigated. We discuss the impact of possible triggers within organic arable farming practice for the risk of N2O emissions and NO3 leaching under European climatic conditions, and possible strategies to reduce these. Organic arable crop rotations can be characterised as diverse with frequent use of legumes, intercropping and organic fertilizers. The soil organic matter content and share of active organic matter, microbial and faunal activity are higher, soil structure better and yields lower, than in non-organic, arable crop rotations. Soil mineral nitrogen (SMN), N2O emissions and NO3 leaching are low under growing crops, but there is high potential for SMN accumulation and losses after crop termination or crop harvest. The risk for high N2O fluxes is increased when large amounts of herbage or organic fertilizers with readily available nitrogen (N) and carbon are incorporated into the soil or left on the surface. Freezing/thawing, drying/rewetting, compacted and/or wet soil and mixing with rotary harrow further enhance the risk for high N2O fluxes. These complex soil N dynamics mask the correlation between total N-input and N2O emissions from organic arable crop rotations. Incorporation of N rich plant residues or mechanical weeding followed by bare fallow increases the risk of nitrate leaching. In contrast, strategic use of deep-rooted crops with long growing seasons in the rotation reduces nitrate leaching risk. Reduced tillage can reduce N leaching if yields are maintained. Targeted treatment and use of herbage from green manures, crop residues and catch crops will increase N efficiency and reduce N2O emissions and NO3 leaching. Continued regular use of catch crops has the potential to reduce NO3 leaching but may enhance N2O emissions. A mixture of legumes and non-legumes (for instance grasses or cereals) are as efficient a catch crop as monocultures of non-legume species.

scholarly journals Short-term effects of biogas digestate and cattle slurry application on greenhouse gas emissions from high organic carbon grasslands

2014 ◽  
Vol 11 (4) ◽  
pp. 5765-5809 ◽  
Author(s):  
T. Eickenscheidt ◽  
A. Freibauer ◽  
J. Heinichen ◽  
J. Augustin ◽  
M. Drösler
Keyword(s):  
Organic Carbon ◽  
Application Rate ◽  
Organic Fertilizers ◽  
Organic Soils ◽  
N2o Emissions ◽  
Cattle Slurry ◽  
Closed Chamber ◽  
Chamber Method ◽  
Biogas Digestate ◽  
N2o Fluxes

Abstract. The change in the German energy policy resulted in a strong development of biogas plants in Germany. As a consequence, huge amounts of nutrient rich residues remain from the fermentative process, which are used as organic fertilizers. Drained peatlands are increasingly used to satisfy the huge demand for fermentative substrates and the digestate is returned to the peatlands. However, drained organic soils are considered as hot spots for nitrous oxide (N2O) emissions and organic fertilization is additionally known to increase N2O emissions from managed grasslands. Our study addressed the questions (a) to what extent biogas digestate and cattle slurry application increase N2O, methane (CH4) and ammonia (NH3) fluxes as well as the mineral nitrogen use efficiency (NUEmin), and (b) how different soil organic matter contents (SOM) promote the production of N2O. The study was conducted at two areas within a grassland parcel, which differed in their soil organic carbon (SOC) contents. At each area (named Corg-medium and Corg-high) two sites were established, one was fertilized five times with biogas digestate and one with cattle slurry. For each treatment, fluxes of N2O and CH4 were measured over two years using the closed chamber method. For NH3 measurements we used the calibrated dynamic chamber method. On an annual basis the application of biogas digestate significantly enhanced the N2O fluxes compared to the application of cattle slurry and additionally increased the NUEmin. Furthermore, N2O fluxes from the Corg-high site significantly exceeded N2O fluxes from the Corg-medium sites. Annual cumulative emissions ranged from 0.91 ± 0.49 kg N ha−1 yr−1 to 3.14 ± 0.91 kg N ha−1 yr−1. Significantly different CH4 fluxes between the investigated treatments or the different soil types were not observed. Cumulative annual CH4 exchange rates varied between −0.21 ± 0.19 kg C ha−1 yr−1 and −1.06 ± 0.46 kg C ha−1 yr−1. Significantly higher NH3 losses from treatments fertilized with biogas digestate compared to those fertilized with cattle slurry were observed. The total NH3 losses following splash plate application were 18.17 kg N ha−1 for the digestate treatments and 3.48 kg N ha−1 for the slurry treatments (36% and 15% of applied NH4&amp;plus;-N). The observed linear increase of 16 days cumulative N2O-N exchange or rather annual N2O emissions, due to a higher mean groundwater level and a higher application rate of NH4+-N, reveal the importance of site adapted N fertilization and the avoidance of N surpluses in Corg rich grasslands.

scholarly journals Denitrification Rate and Its Potential to Predict Biogenic N2O Field Emissions in a Mediterranean Maize-Cropped Soil in Southern Italy

Land ◽  
2019 ◽  
Vol 8 (6) ◽  
pp. 97 ◽  
Author(s):  
Annachiara Forte ◽  
Angelo Fierro
Keyword(s):  
Pore Space ◽  
Denitrification Rate ◽  
Linear Functions ◽  
N2o Emissions ◽  
Soil Cores ◽  
High Soil ◽  
N2o Fluxes ◽  
Intact Soil Cores ◽  
Intact Soil ◽  
Soil Nitrates

The denitrification rate in C2H2-amended intact soil cores and soil N2O fluxes in closed static chambers were monitored in a Mediterranean irrigated maize-cropped field. The measurements were carried out during: (i) a standard fertilization management (SFM) activity and (ii) a manipulation experimental (ME) test on the effects of increased and reduced application rates of urea at the late fertilization. In the course of the SFM, the irrigations following early and late nitrogen fertilization led to pulses of denitrification rates (up to 1300 μg N2O-N m−2 h−1) and N2O fluxes (up to 320 μg N2O-N m−2 h−1), thanks to the combined action of high soil temperatures and not limiting nitrates and water filled pore space (WFPS). During the ME, high soil nitrates were noted in all the treatments in the first one month after the late fertilization, which promoted marked N-losses by microbial denitrification (from 500 to 1800 μg N2O-N m−2 h−1) every time the soil WFPS was not limiting. At similar maize yield responses to fertilizer treatments, this result suggested no competition for N between plant roots and soil microbial community and indicated a probable surplus of nitrogen fertilizer input at the investigated farm. Correlation and regression analyses (CRA) on the whole set of data showed significant relations between both the denitrification rates and the N2O fluxes with three soil physical-chemical parameters: nitrate concentration, WFPS and temperature. Specifically, the response functions of denitrification rate to soil nitrates, WFPS and temperature could be satisfactorily modelled according to simple Michaelis-Menten kinetic, exponential and linear functions, respectively. Furthermore, the CRA demonstrated a significant exponential relationship between N2O fluxes and denitrification and simple empirical functions to predict N2O emissions from the denitrification rate appeared more fitting (higher concordance correlation coefficient) than the predictive empirical algorithm based on soil nitrates, WFPS and temperature. In this regard, the empirically established relationships between the denitrification rate on intact soil cores under field conditions and the soil variables provided local-specific threshold values and coefficients which may effectively work to calibrate and adapt existing N2O process-based simulation models to the local pedo-climatic conditions.

scholarly journals Nitrous oxide emissions from crop rotations including wheat, oilseed rape and dry peas

2013 ◽  
Vol 10 (3) ◽  
pp. 1787-1797 ◽  
Author(s):  
M. H. Jeuffroy ◽  
E. Baranger ◽  
B. Carrouée ◽  
E. de Chezelles ◽  
M. Gosme ◽  
...  
Keyword(s):  
Oilseed Rape ◽  
Ghg Emissions ◽  
Global Scale ◽  
N Fertilizer ◽  
Nitrous Oxide Emissions ◽  
N2o Emissions ◽  
N Fixation ◽  
Biological Fixation ◽  
Mineral N ◽  
N2o Fluxes

Abstract. Approximately 65% of anthropogenic emissions of N2O, a potent greenhouse gas (GHG), originate from soils at a global scale, and particularly after N fertilisation of the main crops in Europe. Thanks to their capacity to fix atmospheric N2 through biological fixation, legumes can reduce N fertilizer use, and possibly N2O emissions. Nevertheless, the decomposition of crop organic matter during the crop cycle and residue decomposition, and possibly the N fixation process itself, could lead to N2O emissions. The objective of this study was to quantify N2O emissions from a dry pea crop (Pisum sativum, harvested at maturity) and from the subsequent crops in comparison with N2O emissions from wheat and oilseed rape crops, fertilized or not, in various rotations. A field experiment was conducted over 4 consecutive years to compare the emissions during the pea crop, in comparison with those during the wheat (fertilized or not) or oilseed rape crops, and after the pea crop, in comparison with other preceding crops. N2O fluxes were measured using static chambers. In spite of low N2O fluxes, mainly due to the site's soil characteristics, fluxes during the crop were significantly lower for pea and unfertilized wheat than for fertilized wheat and oilseed rape. The effect of the preceding crop was not significant, while soil mineral N at harvest was higher after the pea crop. These results should be confirmed over a wider range of soil types. Nevertheless, they demonstrate the absence of N2O emissions linked to the symbiotic N fixation process, and allow us to estimate the decrease in N2O emissions by 20–25% through including one pea crop in a three-year rotation. On a larger scale, this reduction of GHG emissions at field level has to be added to the decrease due to the reduced production and transport of the N fertilizer not applied to the pea crop.

Inlet Turbulence and Off-Design Incidence Response of High Efficiency, Turbine OGV Profiles

2019 ◽  
Author(s):  
Benigno J. Lazaro ◽  
Ezequiel Gonzalez ◽  
Jorge Parra ◽  
David Cadrecha Robles
Keyword(s):  
High Efficiency ◽  
Guide Vane ◽  
Reynolds Numbers ◽  
Cfd Simulations ◽  
Pressure Distributions ◽  
Flow Response ◽  
Wide Range ◽  
Background Turbulence ◽  
Current Design ◽  
And Performance

Abstract In spite of advances in CFD prediction tools, the current design of outlet guide vane (OGV) stages for flow recovery downstream from low pressure turbines (LPT) still has to face significant flow entrance uncertainties. To ensure proper response of modern, high efficiency OGV’s, the sensitivity in the aerodynamic response of the vanes to both different levels of inlet turbulence and off-design incidence must be analyzed. To that end, a systematic experimental investigation of a current design LPT OGV airfoil has been undertaken in a low-speed linear cascade. Wall pressure distributions as well as high-resolution total pressure drop and LDV measurements have been used to determine the flow response. The experimental facility includes different boundary suction strategies for proper control of flow periodicity and endwall effects at significant off-design incidences. In addition, different inlet grids to promote an entrance flow having controlled isotropic background turbulence are included. The experimental flow response of the OGV airfoil is presented for a wide range of Reynolds numbers and different values of the inlet flow incidence and turbulence properties. Both at design and off-design incidences, different flow regimes and performance degradation mechanisms are discussed. In addition, the effect of inlet turbulence at close to design incidence is discussed, with the experimental evidence suggesting that its effect can be described by defining a properly scaled Reynolds number. The ability of CFD simulations based on currently available RANS transition models to describe the flow in high efficiency turbine OGV airfoils is finally explored.

scholarly journals Computer Control of the Spectral Composition of the Powerful Laser System Irradiation with a Wide Range of Laser Transitions on Metal Vapors

2016 ◽  
Vol 79 ◽  
pp. 01003
Author(s):  
Anatoly Soldatov ◽  
Bogdan Doroshenko ◽  
Ivan Kostadinov ◽  
Yury Polunin ◽  
Nikola Sabotinov ◽  
...  
Keyword(s):  
Computer Control ◽  
Laser System ◽  
Spectral Composition ◽  
Powerful Laser ◽  
Metal Vapors ◽  
Wide Range
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