The effects of waterlogging on the solubility of arsenic and ecotoxicity of soil pore water in non-fertilized and fertilized soils in historical mining sites.

Author(s):  
Katarzyna Szopka ◽  
Anna Karczewska ◽  
Agnieszka Dradrach ◽  
Bernard Gałka

<p>Soil contamination with arsenic in historical mining sites is a matter of considerable environmental concern, as the concentrations of As in those soils are locally as high as thousands mg/kg. Some of soils, particularly those affected in the past by tailings that were released from impoundments, are located in floodplains and used as grasslands. Those lands are periodically flooded, and the frequency and duration of flooding will probably increase in the future with changing climatic conditions. Reducing environment that develops upon soil flooding can cause a release of As from soil solid phase. This is an inherent effect of reductive dissolution of amorphous and crystalline iron hydroxides that are the main hosting components for metalloids. Changing redox conditions affect also the speciation of As in pore water, influencing its toxicity to soil biota. Moreover, soil fertilization with inorganic fertilizers that contain phosphates, or with organic fertilizers such as cattle manure, can accelerate As release from iron hydroxides, mainly via competitive desorption. The effects of all those processes are highly dependent on soil properties and still require a close examination.</p><p>Three kinds of soil material, containing up to 8000 mg/kg As, were collected from the tailings-affected floodplain of the Tująca river in Złoty Stok, a historical As mining centre. A laboratory incubation experiment with fertilized and non-fertilized soils was carried out to examine the changes in As concentrations in soil pore water, as well as to assess pore water ecotoxicity, determined in standard bioassays, including Microtox and Phytotox. Soil flooding resulted in a rapid release of As from soil solid phase. As concentrations in soil pore water in all samples exceeded 10 mg/L after a 2-day incubation, and tended to increase slowly with time. In some cases, after the 270-day incubation, As concentrations in pore water reached several hundred mg/L. Those effects resulted in a very high ecotoxicity of pore water, caused lethal effects to bacteria and springtails, and impeded plant germination. Soil amendment with manure was a factor that significantly enhanced those effects. The factors responsible for various effects that were reported from three soils were discussed.</p>

Author(s):  
Karolina Lewińska ◽  
Anna Karczewska ◽  
Marcin Siepak ◽  
Bernard Gałka

This study examined the changes in antimony (Sb) solubility in soils, using organic matter introduced with forest litter, in various moisture conditions. Soils containing 12.8–163 mg/kg Sb were taken from the top layers of dumps in former mining sites in the Sudetes, South-West Poland. Soils were incubated for 90 days either in oxic or waterlogged conditions, with and without the addition of 50 g/kg of beech forest litter (FL). Water concentrations of Sb in some experimental treatments greatly exceeded the threshold values for good quality underground water and drinking water, and reached a maximum of 2.8 mg/L. The changes of Sb solubility caused by application of FL and prolonged waterlogging were, in various soils, highly divergent and in fact unpredictable based on the main soil properties. In some soils, the application of forest litter prompted the release of Sb from soil solid phase, while in the others it acted contradictorily. Soil waterlogging resulted, in most cases, in the increased release of Sb compared to oxic conditions, and this effect was enhanced by the addition of forest litter. However, in two soils the presence of forest litter counteracted the effects of waterlogging and diminished the quantities of released Sb.


2006 ◽  
Vol 40 (4) ◽  
pp. 1307-1313 ◽  
Author(s):  
Thomas L. ter Laak ◽  
Stanley O. Agbo ◽  
Arjan Barendregt ◽  
Joop L. M. Hermens

2020 ◽  
pp. 26-28
Author(s):  
Н.Т. Чеботарев ◽  
Н.Н. Шергина

Пахотные угодья Республики Коми в основном представлены дерново-подзолистыми почвами с низким естественным плодородием, которые без применения удобрений быстро подвергаются деградационным процессам, что резко снижает их продуктивность. Цель исследований: оценка эффективности долговременного применения органических и минеральных удобрений при выращивании картофеля в кормовом севообороте в условиях Республики Коми. Методической основой выполнения работ были комплексные исследования дерново-подзолистых почв, клубней картофеля на участках многолетнего полевого эксперимента, заложенного на землях Института агробиотехнологий ФИЦ Коми НЦ УрО РАН в соответствии с «Методическими указаниями географической сети опытов с удобрениями». Длительный период исследований (более 40 лет) характеризовался различными климатическими условиями, которые отразились на количестве урожая и качестве клубней картофеля. Было проведено 7 ротаций (14 лет) с выращиванием картофеля. Вносили органические удобрения – торфонавозный компост (ТНК) в дозах 40 и 80 т/га (1 и 2 фон, соответственно) под картофель и минеральные удобрения – NPК в дозах 1/3; 1/2 и 1 для восполнения выноса растениями элементов питания. Установлено положительное влияние комплексного применения органических и минеральных удобрений на урожайность и качество картофеля, а также на плодородие дерново-подзолистой легкосуглинистой среднеокультуренной почвы в кормовом севообороте в почвенно-климатических условиях Республики Коми. В результате применения шестипольного севооборота и комплексного внесения удобрений с 1978 года к 2019 году в почвах снизилась обменная и гидролитическая кислотность; повысилось содержание гумуса на 0,5% (в контроле); на 0,2–0,5% (с тремя дозами минеральных удобрений); на 0,3–1,1% (с ТНК); на 0,2–1,6% (при совместном применении органических и минеральных удобрений). Наибольшие урожаи картофеля получены при совместном применении органических (80 т/га) и минеральных удобрений (1 NPК) и составили 37,1 т/га клубней (8,5 тыс/га кормовых единиц). При таком соотношении удобрений показано высокое качество клубней картофеля: содержание крахмала 15,5%, витамина С – 19,4 мг%, сырого протеина – 14,1%. Количество нитратного азота не превышало ПДК (ПДК 250 мг.с.м.). Экономические расчеты показали, что при внесении ТНК 40 т/га + 1 NPК в дерново-подзолистые почвы с.-х. использования в среднетаежной зоне Республики Коми при выращивании картофеля, условный чистый доход составит 68,4 тыс. р. с 1 га, себестоимость 1 т картофеля – 2,8 тыс. р., рентабельность 188,7%. The arable land of the Republic of Komi is mainly represented by dern-sub-ground soils with low natural fertility, which without the use of fertilizers are quickly subjected to degradation processes, which dramatically reduces their productivity. The aim of the research is to evaluate the efficiency of long-term use of organic and mineral fertilizers in the growing of potatoes in feed crop rotation in the conditions of the Komi Republic. The methodological basis for carrying out the works was comprehensive studies of dern-subhead soils, potato tubers on the sites of a multi-year field experiment laid on the lands of the Institute of Agrobiotechnology of the FRC Komi SC UB RAS in accordance with the «Methodological Instructions of the Geographical Network of Experiments with Fertilizers». A long period of research (more than 40 years) was characterized by different climatic conditions, which affected the number of crops and the quality of potato tubers. There were 7 rotations (14 years) with potato cultivation. Organic fertilizers – peat-avous compost (TNK) in doses of 40 and 80 t/ha (1 and 2 background, respectively) for potatoes and mineral fertilizers – NPK in doses of 1/3; 1/2 and 1 to replenish the carry-out of food elements by plants. The positive effect of the integrated use of organic and mineral fertilizers on the yield and quality of potatoes, as well as on the fertility of soddy-podzolic light loamy medium cultivated soil in fodder crop rotation in the soil and climatic conditions of the Komi Republic, has been established. As a result of the use of six-bed crop rotation and the integrated application of fertilizers, metabolic and hydrolytic acidity decreased in soils from 1978 to 2019; humus content increased by 0.5% (in control); 0.2–0.5% (with three doses of mineral fertilizers); 0.3–1.1% (with TNCs); 0.2–1.6% (with combined use of organic and mineral fertilizers). The largest potato yields were obtained from the combined use of organic (80 t/ha) and mineral fertilizers (1 NPK) and amounted to 37.1 t/ha tubers (8.5 thousand/ha feed units). The largest potato harvests were obtained with the combined use of organic (80 t/ha) and mineral fertilizers (1 NPK) and amounted to 37.1 t/ha of tubers (8.5 thousand/ha of feed units). With this ratio of fertilizers, the high quality of potato tubers was also determined: the starch content was 15.5%, vitamin C – 19.4 mg%, crude protein – 14.1%. The amount of nitrate nitrogen did not exceed the MPC (MPC 250 mg.s.m.). Economic calculations showed that if TNK is added 40 t/ha 1 NPK to the dern-sub-ground soils of agricultural use in the medium-sized zone of the Komi Republic when growing potatoes, the conditional net income will be 68.4 thousand rubles from 1 ha, the cost of 1 t of potatoes – 2.8 thousand rubles, profitability 188.7%.


2006 ◽  
Author(s):  
Stephen W. Webb ◽  
James M. Phelan ◽  
Teklu Hadgu ◽  
Joshua S. Stein ◽  
Cedric M. Sallaberry

Forests ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 355
Author(s):  
Katarzyna Szopka ◽  
Iwona Gruss ◽  
Dariusz Gruszka ◽  
Anna Karczewska ◽  
Krzysztof Gediga ◽  
...  

This study examined the effects of waterlogging and forest litter introduced to soil on chemical properties of soil pore water and ecotoxicity of soils highly enriched in As. These effects were examined in a 21-day incubation experiment. Tested soil samples were collected from Złoty Stok, a historical centre of arsenic and gold mining: from a forested part of the Orchid Dump (19,600 mg/kg As) and from a less contaminated site situated in a neighboring forest (2020 mg/kg As). An unpolluted soil was used as control. The concentrations of As, Fe and Mn in soil pore water were measured together with a redox potential Eh. A battery of ecotoxicological tests, including a bioassay with luminescence bacteria Vibrio fischeri (Microtox) and several tests on crustaceans (Rapidtox, Thamnotox and Ostracodtox tests), was used to assess soil ecotoxicity. The bioassays with crustaceans (T. platyurus, H. incongruens) were more sensitive than the bacterial test Microtox. The study confirmed that the input of forest litter into the soil may significantly increase the effects of toxicity. Waterlogged conditions facilitated a release of As into pore water, and the addition of forest litter accelerated this effect thus causing increased toxicity.


We present an overview of geochemical data from pore waters and solid phases that clarify earliest diagenetic processes affecting modern, shallow marine carbonate sediments. Acids produced by organic matter decomposition react rapidly with metastable carbonate minerals in pore waters to produce extensive syndepositional dissolution and recrystallization. Stoichiometric relations among pore water solutes suggest that dissolution is related to oxidation of H 2 S which can accumulate in these low-Fe sediments. Sulphide oxidation likely occurs by enhanced diffusion of O 2 mediated by sulphide-oxidizing bacteria which colonize oxic/anoxic interfaces invaginating these intensely bioturbated sediments. Buffering of pore water stable isotopic compositions towards values of bulk sediment and rapid 45 Ca exchange rates during sediment incubations demonstrate that carbonate recrystallization is a significant process. Comparison of average biogenic carbonate production rates with estimated rates of dissolution and recrystallization suggests that over half the gross production is dissolved and/or recrystallized. Thus isotopic and elemental composition of carbonate minerals can experience significant alteration during earliest burial driven by chemical exchange among carbonate minerals and decomposing organic matter. Temporal shifts in palaeo-ocean carbon isotope composition inferred from bulk-rocks may be seriously compromised by facies-dependent differences in dissolution and recrystallization rates.


2012 ◽  
Vol 614-615 ◽  
pp. 688-694 ◽  
Author(s):  
Yi Wang ◽  
Guo Min Shen

In this paper, at first, an effective soil thermal conductivity model was established. Single factor regression analysis for 6 uncertain factors contained in the model was then conducted respectively. Finally, the primary and secondary characters of these uncertain factors were analyzed by using the orthogonal test. The analysis results show that the effective soil thermal conductivity has linear relationships with the saturation degree of unsaturated soil and the depth of water table and has power function relationships with other 4 uncertain factors; the porosity of unsaturated soil has the greatest effect on the effective soil thermal properties, followed by saturation degree of unsaturated soil, porosity of saturated soil, solid phase thermal conductivity of unsaturated soil, solid phase thermal conductivity of saturated soil and the depth of water table.


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