Drivers of stable water isotope variability in the cold and warm sector of extratropical cyclones from two case studies in the Southern Ocean

2020 ◽  
Author(s):  
Iris Thurnherr ◽  
Franziska Aemisegger ◽  
Lukas Jansing ◽  
Katharina Hartmuth ◽  
Josué Gehring ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Southern Ocean ◽  
Case Studies ◽  
Marine Boundary Layer ◽  
Water Cycle ◽  
Atmospheric Water ◽  
Air Masses ◽  
Warm Sector ◽  
Moisture Fluxes ◽  
Dew Deposition

<p>Dynamical processes in the atmosphere strongly influence the large temporal and spatial variability of the atmospheric branch of the water cycle. For instance, the advection of air masses by synoptic-scale weather systems induces air-sea moisture fluxes such as evaporation, precipitation and dew deposition. It is important to better investigate and quantify this linkage between dynamical phenomena and details of the atmospheric water cycle. In addition, one of the big challenges in monitoring the atmospheric water cycle is the measurement of turbulent moisture fluxes over the ocean. Stable water isotopes (SWIs) serve as a tool to trace atmospheric processes which shape the atmospheric water cycle and, thus, provide important insights into moist processes associated with weather systems, in particular air-sea fluxes.</p><p>In this study, we investigate the impact of air-sea moisture fluxes on the variability of SWI signals in the marine boundary layer. Measurements of the second-order isotope variable deuterium excess in the marine boundary layer of the Southern Ocean show positive/negative anomalies in the cold/warm sector, respectively, of extra-tropical cyclone due to opposing moisture fluxes and non-equilibrium fractionation processes in the two sectors. The drivers of these contrasting SWI signals are analysed using the isotope-enabled Consortium for Small-Scale Modelling model for two case studies. The simulated isotope signals during the case studies show excellent agreement with ship-based isotope measurements from the Southern Ocean performed during the Antarctic Circumnavigation expedition in January and February 2017.</p><p>The main driver of SWI variability in the cold sector is enhanced ocean evaporation which substantially modifies the advected SWI signal from the Antarctic continent during a cold air outbreak. In the warm sector, dew deposition on the ocean surface and cloud formation are mainly driving the observed negative deuterium excess anomaly, which can be conserved and advected over several 100 km in the warm sector of an extratropical cyclone.</p><p>The results of this study illustrate the strong dependence of the isotopic composition of water vapour in the marine boundary layer on the predominant atmospheric large-scale flow situation. In particular in the storm track regions, the variability of SWIs in marine boundary layer water vapour is largely shaped by the sign and strength of air-sea fluxes induced by the meridional transport of air masses.</p>

Disentangling the impact of air-sea interaction and boundary layer cloud formation on stable water isotope signals in the warm sector of a Southern Ocean cyclone 

2021 ◽  
Author(s):  
Iris Thurnherr ◽  
Heini Wernli ◽  
Franziska Aemisegger
Keyword(s):  
Boundary Layer ◽  
Water Vapour ◽  
Marine Boundary Layer ◽  
Cloud Formation ◽  
Stable Water Isotopes ◽  
Near Surface ◽  
Warm Sector ◽  
Moisture Fluxes ◽  
Boundary Layer Cloud ◽  
Dew Deposition

<p>Stable water isotopes in marine boundary layer water vapour are strongly influenced by the strength of air-sea moisture fluxes and are thus tracers of air-sea interaction. Air-sea moisture fluxes in the extratropics are modulated by large-scale air advection, for instance the advection of warm and moist air masses in the warm sector of extratropical cyclones. A distinct isotopic composition of water vapour in the latter environment has been observed in near-surface water vapour over the Southern Ocean during the 2016/17 Antarctic Circumnavigation coordinated by the Swiss Polar Institute. Most prominently, the second-order isotope variable d-excess shows negative values in the cyclones’ warm sector. Here, we present three single-process air parcel models, which simulate the evolution of d-excess and specific humidity in an air parcel induced by dew deposition, decreasing ocean evaporation or upstream cloud formation, respectively. The air-parcel models are combined with simulations with the isotope-enabled numerical weather prediction model COSMO<sub>iso</sub> (i) to validate the air parcel models, (ii) to study the extent of non-linear interactions between the different processes, and (iii) to quantify the relevance of the three processes for stable water isotopes in the warm sector of the investigated extratropical cyclone. This analysis reveals that dew deposition and decreasing ocean evaporation lead to the strongest d-excess decrease in near-surface water vapour in the warm sector. Furthermore, COSMO<sub>iso</sub> air parcel trajectories show that the persistent low d-excess observed in the warm sector of extratropical cyclones is not a result of material conservation of low d-excess. Instead the latter feature is sustained by the continuous production of low d-excess values in new air parcels entering the warm sector. We show that with the mechanistic approach of using single-process air parcel models we are able to simulate the evolution of d-excess during the air parcel’s transport. This improves our understanding of the effect of air-sea interaction and boundary layer cloud formation on the stable water isotope variability of marine boundary layer water vapour.</p>

The role of soil hydrophysical properties in the atmospheric water cycle

2021 ◽  
Author(s):  
Eli Dennis ◽  
Ernesto Berbery
Keyword(s):  
United States ◽  
Boundary Layer ◽  
Heat Flux ◽  
Grain Size ◽  
Soil Texture ◽  
Water Cycle ◽  
Surface Fluxes ◽  
Atmospheric Water ◽  
Moisture Fluxes ◽  
Soil Grain Size

<p>Soil hydrophysical properties are necessary components in weather and climate simulation; yet, the parameter inaccuracies may introduce considerable uncertainty in the representation of surface water and energy fluxes. The surface fluxes not only affect the terrestrial water and energy budgets, but through land-atmosphere interactions, they can influence the boundary layer, atmospheric stability, moisture transports, and regional precipitation characteristics. This study uses seasonal coupled simulations to examine the uncertainties in the North American atmospheric water cycle that result from the use of different soil datasets. Two soil datasets are considered: State Soil Geographic dataset (STATSGO) from the United States Department of Agriculture and Global Soil Dataset for Earth System Modeling (GSDE) from Beijing Normal University.  Each dataset's dominant soil category allocations differ significantly at the model's resolution (15 km). It is found that large coherent regional discrepancies exist in the assignments of soil category, such that, for instance, in the Midwestern United States (hereafter, Midwest), there is a systematic reduction in soil grain size. Because the soil grain size is regionally biased, it allows for analysis of the impact of soil hydrophysical properties projected onto regional scales.</p><p>The two simulations are conducted from June 1–August 31, 2016–2018 using the Weather Research and Forecasting Model (WRF) coupled with the Community Land Model (CLM) version 4. It is found that in the Midwest, where the soil grain size decreases from STATSGO to GSDE, the GSDE simulation experiences reduced mean latent heat flux (–15 W m<sup>-2</sup>), and increased sensible heat flux (+15 W m<sup>-2</sup>).  The differences in fluxes lead to differences in low-level specific humidity and 2-m temperature. The boundary layer thermodynamic structure responds to these changes resulting in differences in mean CAPE and CIN. In the GSDE simulation, there is more energy available for convection (CAPE: +200 J kg<sup>-1</sup>) in the Midwest, but it is more difficult to access that energy (CIN: +75 J kg<sup>-1</sup>). Furthermore, a reduction in low-level moisture generates a similar reduction in column-integrated moisture (i.e., precipitable water), resulting in conditions that are less conducive for precipitation.</p><p>Interestingly, the soil-texture-related surface fluxes are not confined to thermodynamic influence, but their influence extends to dynamic fields as well. Differences in the vertically-integrated wind field suggest a weakening of the continental low-pressure system (i.e., denoted by a reduction in cyclonic rotation) co-located with the decrease in latent heat flux in the Midwest. The associated vertically-integrated moisture fluxes mirror the dissimilarities in the wind fields. Consequently, the moisture fluxes yield differences in vertically-integrated moisture flux convergence in the same region, as well. This combination of thermodynamic and dynamic variable differences culminates in a reduction of average precipitation in the Midwest, which can be related to changes in the placement of soil hydrophysical properties via soil texture. Through land-atmosphere interactions, it is shown that soil parameters can affect each component of the atmospheric water budget.</p>

scholarly journals On the relationship between acetone and carbon monoxide in air masses of different origin

2003 ◽  
Vol 3 (1) ◽  
pp. 1017-1049
Author(s):  
M. de Reus ◽  
H. Fischer ◽  
F. Arnold ◽  
J. de Gouw ◽  
R. Holzinger ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Carbon Monoxide ◽  
Field Experiments ◽  
Marine Boundary Layer ◽  
Biogenic Emissions ◽  
Model Calculations ◽  
Single Observation ◽  
Tropical Regions ◽  
Air Masses ◽  
Clean Air

Abstract. Carbon monoxide and acetone measurements are presented for five aircraft measurement campaigns at mid-latitudes, polar and tropical regions in the northern hemisphere. Throughout all campaigns, free tropospheric air masses, which were influenced by anthropogenic emissions, showed a similar linear relation between CO and acetone, with a slope of 21–25 pptv acetone/ppbv CO. Measurements in the anthropogenically influenced marine boundary layer revealed a slope of 13–16 pptv acetone/ppbv CO. The different slopes observed in the marine boundary layer and the free troposphere indicate that acetone is emitted by the ocean in relatively clean air masses and taken up by the ocean in polluted air masses. In the lowermost stratosphere, a good correlation between CO and acetone was observed as well, however, with a much smaller slope (~5 pptv acetone/ppbv CO) compared to the troposphere. This is caused by the longer photochemical lifetime of CO compared to acetone in the lower stratosphere, due to the increasing photolytic loss of acetone and the decreasing OH concentration with altitude. No significant correlation between CO and acetone was observed over the tropical rain forest due to the large direct and indirect biogenic emissions of acetone. The common slopes of the linear acetone-CO relation in various layers of the atmosphere, during five field experiments, makes them useful for model calculations. Often a single observation of the CO-acetone correlation, determined from stratospheric measurements, has been used in box model applications. This study shows that different slopes have to be considered for marine boundary layer, free tropospheric and stratospheric air masses, and that the CO-acetone relation cannot be used for air masses which are strongly influenced by biogenic emissions.

scholarly journals Synoptic-scale controls of fog and low-cloud variability in the Namib Desert

2020 ◽  
Vol 20 (6) ◽  
pp. 3415-3438 ◽  
Author(s):  
Hendrik Andersen ◽  
Jan Cermak ◽  
Julia Fuchs ◽  
Peter Knippertz ◽  
Marco Gaetani ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Cloud Cover ◽  
Large Scale ◽  
Marine Boundary Layer ◽  
Synoptic Scale ◽  
Namib Desert ◽  
Data Set ◽  
Air Masses ◽  
Low Cloud ◽  
Low Cloud Cover

Abstract. Fog is a defining characteristic of the climate of the Namib Desert, and its water and nutrient input are important for local ecosystems. In part due to sparse observation data, the local mechanisms that lead to fog occurrence in the Namib are not yet fully understood, and to date, potential synoptic-scale controls have not been investigated. In this study, a recently established 14-year data set of satellite observations of fog and low clouds in the central Namib is analyzed in conjunction with reanalysis data in order to identify synoptic-scale patterns associated with fog and low-cloud variability in the central Namib during two seasons with different spatial fog occurrence patterns. It is found that during both seasons, mean sea level pressure and geopotential height at 500 hPa differ markedly between fog/low-cloud and clear days, with patterns indicating the presence of synoptic-scale disturbances on fog and low-cloud days. These regularly occurring disturbances increase the probability of fog and low-cloud occurrence in the central Namib in two main ways: (1) an anomalously dry free troposphere in the coastal region of the Namib leads to stronger longwave cooling of the marine boundary layer, increasing low-cloud cover, especially over the ocean where the anomaly is strongest; (2) local wind systems are modulated, leading to an onshore anomaly of marine boundary-layer air masses. This is consistent with air mass back trajectories and a principal component analysis of spatial wind patterns that point to advected marine boundary-layer air masses on fog and low-cloud days, whereas subsiding continental air masses dominate on clear days. Large-scale free-tropospheric moisture transport into southern Africa seems to be a key factor modulating the onshore advection of marine boundary-layer air masses during April, May, and June, as the associated increase in greenhouse gas warming and thus surface heating are observed to contribute to a continental heat low anomaly. A statistical model is trained to discriminate between fog/low-cloud and clear days based on information on large-scale dynamics. The model accurately predicts fog and low-cloud days, illustrating the importance of large-scale pressure modulation and advective processes. It can be concluded that regional fog in the Namib is predominantly of an advective nature and that fog and low-cloud cover is effectively maintained by increased cloud-top radiative cooling. Seasonally different manifestations of synoptic-scale disturbances act to modify its day-to-day variability and the balance of mechanisms leading to its formation and maintenance. The results are the basis for a new conceptual model of the synoptic-scale mechanisms that control fog and low-cloud variability in the Namib Desert and will guide future studies of coastal fog regimes.

scholarly journals Characterization of the South Atlantic marine boundary layer aerosol using an aerodyne aerosol mass spectrometer

2008 ◽  
Vol 8 (16) ◽  
pp. 4711-4728 ◽  
Author(s):  
S. R. Zorn ◽  
F. Drewnick ◽  
M. Schott ◽  
T. Hoffmann ◽  
S. Borrmann
Keyword(s):  
Boundary Layer ◽  
Sulfuric Acid ◽  
High Resolution ◽  
Marine Boundary Layer ◽  
Methanesulfonic Acid ◽  
Field Measurements ◽  
Size Distributions ◽  
Air Masses ◽  
Unit Mass Resolution ◽  
Mass Concentrations

Abstract. Measurements of the submicron fraction of the atmospheric aerosol in the marine boundary layer were performed from January to March 2007 (Southern Hemisphere summer) onboard the French research vessel Marion Dufresne in the Southern Atlantic and Indian Ocean (20° S–60° S, 70° W–60° E). We used an Aerodyne High-Resolution-Time-of-Flight AMS to characterize the chemical composition and to measure species-resolved size distributions of non-refractory aerosol components in the submicron range. Within the "standard" AMS compounds (ammonium, chloride, nitrate, sulfate, organics) "sulfate" is the dominant species in the marine boundary layer with concentrations ranging between 50 ng m−3 and 3 μg m−3. Furthermore, what is seen as "sulfate" by the AMS is likely comprised mostly of sulfuric acid. Another sulfur containing species that is produced in marine environments is methanesulfonic acid (MSA). There have been previously measurements of MSA using an Aerodyne AMS. However, due to the use of an instrument equipped with a quadrupole detector with unit mass resolution it was not possible to physically separate MSA from other contributions to the same m/z. In order to identify MSA within the HR-ToF-AMS raw data and to extract mass concentrations for MSA from the field measurements the standard high-resolution MSA fragmentation patterns for the measurement conditions during the ship campaign (e.g. vaporizer temperature) needed to be determined. To identify characteristic air masses and their source regions backwards trajectories were used and averaged concentrations for AMS standard compounds were calculated for each air mass type. Sulfate mass size distributions were measured for these periods showing a distinct difference between oceanic air masses and those from African outflow. While the peak in the mass distribution was roughly at 250 nm (vacuum aerodynamic diameter) in marine air masses, it was shifted to 470 nm in African outflow air. Correlations between the mass concentrations of sulfate, organics and MSA show a narrow correlation for MSA with sulfate/sulfuric acid coming from the ocean, but not with continental sulfate.

scholarly journals Ozone variability and halogen oxidation within the Arctic and sub-Arctic springtime boundary layer

2010 ◽  
Vol 10 (21) ◽  
pp. 10223-10236 ◽  
Author(s):  
J. B. Gilman ◽  
J. F. Burkhart ◽  
B. M. Lerner ◽  
E. J. Williams ◽  
W. C. Kuster ◽  
...  
Keyword(s):  
Boundary Layer ◽  
North Atlantic ◽  
Marine Boundary Layer ◽  
Transport Model ◽  
Arctic Basin ◽  
The Arctic ◽  
Arctic Boundary Layer ◽  
Air Masses ◽  
The North ◽  
The North Atlantic

Abstract. The influence of halogen oxidation on the variabilities of ozone (O3) and volatile organic compounds (VOCs) within the Arctic and sub-Arctic atmospheric boundary layer was investigated using field measurements from multiple campaigns conducted in March and April 2008 as part of the POLARCAT project. For the ship-based measurements, a high degree of correlation (r = 0.98 for 544 data points collected north of 68° N) was observed between the acetylene to benzene ratio, used as a marker for chlorine and bromine oxidation, and O3 signifying the vast influence of halogen oxidation throughout the ice-free regions of the North Atlantic. Concurrent airborne and ground-based measurements in the Alaskan Arctic substantiated this correlation and were used to demonstrate that halogen oxidation influenced O3 variability throughout the Arctic boundary layer during these springtime studies. Measurements aboard the R/V Knorr in the North Atlantic and Arctic Oceans provided a unique view of the transport of O3-poor air masses from the Arctic Basin to latitudes as far south as 52° N. FLEXPART, a Lagrangian transport model, was used to quantitatively determine the exposure of air masses encountered by the ship to first-year ice (FYI), multi-year ice (MYI), and total ICE (FYI+MYI). O3 anti-correlated with the modeled total ICE tracer (r = −0.86) indicating that up to 73% of the O3 variability measured in the Arctic marine boundary layer could be related to sea ice exposure.

scholarly journals On the relationship between acetone and carbon monoxide in different air masses

2003 ◽  
Vol 3 (5) ◽  
pp. 1709-1723 ◽  
Author(s):  
M. de Reus ◽  
H. Fischer ◽  
F. Arnold ◽  
J. de Gouw ◽  
R. Holzinger ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Carbon Monoxide ◽  
Field Experiments ◽  
Marine Boundary Layer ◽  
Biogenic Emissions ◽  
Model Calculations ◽  
Single Observation ◽  
Tropical Regions ◽  
Air Masses ◽  
Clean Air

Abstract. Carbon monoxide and acetone measurements are presented for five aircraft measurement campaigns at mid-latitudes, polar and tropical regions in the northern hemisphere. Throughout all campaigns, free tropospheric air masses, which were influenced by anthropogenic emissions, showed a similar linear relation between acetone and CO, with a slope of 21-25 pptv acetone/ppbv CO. Measurements in the anthropogenically influenced marine boundary layer revealed a slope of 13-16 pptv acetone/ppbv CO. The different slopes observed in the marine boundary layer and the free troposphere indicate that acetone is emitted by the ocean in relatively clean air masses and taken up by the ocean in polluted air masses. In the lowermost stratosphere, a good correlation between acetone and CO was observed as well, however, with a much smaller slope (~5 pptv acetone/ppbv CO) compared to the troposphere. This is caused by the longer photochemical lifetime of CO compared to acetone in the lower stratosphere, due to the increasing photolytic loss of acetone and the decreasing OH concentration with altitude. No significant correlation between acetone and CO was observed over the tropical rain forest due to the large direct and indirect biogenic emissions of acetone. The common slopes of the linear acetone-CO relation in various layers of the atmosphere, during five field experiments, makes them useful for model calculations. Often a single observation of the acetone-CO correlation, determined from stratospheric measurements, has been used in box model applications. This study shows that different slopes have to be considered for marine boundary layer, free tropospheric and stratospheric air masses, and that the acetone-CO relation cannot be used for air masses which are strongly influenced by biogenic emissions.

scholarly journals Unexpectedly high ultrafine aerosol concentrations above East Antarctic sea ice

2016 ◽  
Vol 16 (4) ◽  
pp. 2185-2206 ◽  
Author(s):  
R. S. Humphries ◽  
A. R. Klekociuk ◽  
R. Schofield ◽  
M. Keywood ◽  
J. Ward ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Southern Ocean ◽  
Sea Ice ◽  
Radiative Forcing ◽  
Free Troposphere ◽  
Radiative Balance ◽  
Air Masses ◽  
Antarctic Sea Ice ◽  
Ocean Region ◽  
The Antarctic

Abstract. Better characterisation of aerosol processes in pristine, natural environments, such as Antarctica, have recently been shown to lead to the largest reduction in uncertainties in our understanding of radiative forcing. Our understanding of aerosols in the Antarctic region is currently based on measurements that are often limited to boundary layer air masses at spatially sparse coastal and continental research stations, with only a handful of studies in the vast sea-ice region. In this paper, the first observational study of sub-micron aerosols in the East Antarctic sea ice region is presented. Measurements were conducted aboard the icebreaker Aurora Australis in spring 2012 and found that boundary layer condensation nuclei (CN3) concentrations exhibited a five-fold increase moving across the polar front, with mean polar cell concentrations of 1130 cm−3 – higher than any observed elsewhere in the Antarctic and Southern Ocean region. The absence of evidence for aerosol growth suggested that nucleation was unlikely to be local. Air parcel trajectories indicated significant influence from the free troposphere above the Antarctic continent, implicating this as the likely nucleation region for surface aerosol, a similar conclusion to previous Antarctic aerosol studies. The highest aerosol concentrations were found to correlate with low-pressure systems, suggesting that the passage of cyclones provided an accelerated pathway, delivering air masses quickly from the free troposphere to the surface. After descent from the Antarctic free troposphere, trajectories suggest that sea-ice boundary layer air masses travelled equatorward into the low-albedo Southern Ocean region, transporting with them emissions and these aerosol nuclei which, after growth, may potentially impact on the region's radiative balance. The high aerosol concentrations and their transport pathways described here, could help reduce the discrepancy currently present between simulations and observations of cloud and aerosol over the Southern Ocean.

scholarly journals Synoptic-scale controls of fog and low clouds in the Namib Desert

2019 ◽  
Author(s):  
Hendrik Andersen ◽  
Jan Cermak ◽  
Julia Fuchs ◽  
Peter Knippertz ◽  
Marco Gaetani ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Large Scale ◽  
Marine Boundary Layer ◽  
Synoptic Scale ◽  
Namib Desert ◽  
Sea Level Pressure ◽  
Mean Sea Level ◽  
Air Masses ◽  
Low Clouds ◽  
Low Cloud

Abstract. Fog is a defining characteristic of the climate of the Namib Desert and its water and nutrient input are important for local ecosystems. In part due to sparse observation data, the local mechanisms that lead to fog occurrence in the Namib are not yet fully understood, and to date, potential synoptic-scale controls have not been investigated. In this study, a recently established 14-year data set of satellite observations of fog and low clouds in the central Namib is analyzed in conjunction with reanalysis data to identify typical synoptic-scale conditions associated with fog and low-cloud occurrence in the central Namib during two seasons that characterize seasonal fog variability. It is found that during both seasons, mean sea level pressure and geopotential height at 500 hPa differ significantly between fog/low-cloud and clear days, with patterns indicating seasonally different synoptic-scale disturbances on fog and low-cloud days: cut-off lows during September, October, and November, and breaking Rossby waves during April, May, and June. These regularly occurring disturbances increase the probability of fog and low-cloud occurrence in the central Namib in two main ways: 1) an anomalously dry free troposphere in the coastal region of the Namib leads to stronger longwave cooling, especially over the ocean, facilitating low-cloud formation, and 2) local wind systems are modulated, leading to an onshore anomaly of marine boundary-layer air masses. This is consistent with air mass backtrajectories and a principal component analysis of spatial wind patterns that point to advected marine boundary- layer air masses on fog and low-cloud days, whereas subsiding continental air masses dominate on clear days. Large-scale free-tropospheric moisture transport into southern Africa seems to be a key factor modulating the onshore advection of marine boundary-layer air masses during April, May, and June, as the associated increase in greenhouse gas warming and thus surface heating is observed to contribute to a continental heat low anomaly. A statistical model is trained to discriminate between fog/low-cloud and clear days based on large-scale mean sea level pressure fields. The model accurately predicts fog and low-cloud days, illustrating the importance of large-scale pressure modulation and advective processes. It can be concluded that Namib-region fog is predominantly of advective nature, but also facilitated by increased radiative cooling. Seasonally different manifestations of synoptic-scale disturbances act to modify its day-to-day variability and the balance of mechanisms leading to its formation. The results are the basis for a new conceptual model on the synoptic-scale mechanisms that control fog and low clouds in the Namib Desert, and will guide future studies of coastal fog regimes.

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