EnvironMICADAS C-14 AMS Gas ion source performance and its applications at HEKAL Laboratory, Debrecen, Hungary

Author(s):  
Mihály Molnár ◽  
Róbert Janovics ◽  
István Major ◽  
Katalin Hubay ◽  
Botond Buró ◽  
...  

<p>A coupled accelerator mass spectrometer - gas interface system successfully has been operating at the Hertelendi Laboratory of Environmental Studies, Debrecen, Hungary since 2013. Over the last 6 years more than 500 gas targets were measured below 100 µg carbon content for carbon isotopic composition. The system was tested with blanks, OxII, IAEA-C1, IAEA-C2 and IAEA-C7 standards. The performance of our instrumentation shows good agreement with other published gas-interface system data and also shows a quite good agreement with the nominal value of international standard samples.  There is a measurable but quite small memory effect after modern samples, but this does not significantly affect the final results. Typical ion currents at the low energy side were between 10-15 µA with a 5% CO<sub>2</sub> in He mixing ratio. The relative errors average ±6% for samples greater than or equal to 10 µgC sample with mean count rates of 300 counts per microgram C for OxII. The blank is comparable with other systems, which is 0.0050 ± 0.0018 F<sup>14</sup>C or 34000-47000 yr BP, which allows for the routine measurement of both of small environmental and archeological samples.</p><p>The research was supported by the European Union and the State of Hungary, co-financed by the European Regional Development Fund in the project of GINOP-2.3.2-15-2016- 00009 “ICER”. This work was carried out in the frame of the János Bolyai Research Scholarship (Mihály Molnár) of the Hungarian Academy of Sciences</p>

Radiocarbon ◽  
2021 ◽  
Vol 63 (2) ◽  
pp. 499-511
Author(s):  
Mihály Molnár ◽  
Marianna Mészáros ◽  
Róbert Janovics ◽  
István Major ◽  
Katalin Hubay ◽  
...  

ABSTRACTA coupled accelerator mass spectrometer–gas interface system has been successfully operating at the Hertelendi Laboratory of Environmental Studies, Debrecen, Hungary, since 2013. Over the last 6 years more than 500 gas targets were measured below 100 µg carbon content for carbon isotopic composition. The system was tested with blanks, OxII, IAEA-C1, IAEA-C2, and IAEA-C7 standards. The performance of our instrumentation shows good agreement with other published gas-interface system data and also shows a quite good agreement with the nominal value of international standard samples. There is a measurable but quite small memory effect after modern samples, but this does not significantly affect the final results. Typical ion currents at the low energy side were between 10–15 µA with a 5% CO2 in He mixing ratio. The relative errors average ±6% for samples greater than or equal to 10 µgC sample with mean count rates of 300 counts per microgram C for OxII. The blank is comparable with other systems, which is 0.0050 ± 0.0018 F14C or 34,000–47,000 yr BP, which allows for the routine measurement of both of small environmental and archeological samples.


2021 ◽  
Vol 64 (3) ◽  
pp. 470-493 ◽  
Author(s):  
Jianping Chen ◽  
Xulong Wang ◽  
Jianfa Chen ◽  
Yunyan Ni ◽  
Baoli Xiang ◽  
...  

1967 ◽  
Vol 50 (3) ◽  
pp. 568-572
Author(s):  
J Russell Bishop

Abstract titrimetric method for the assay of dry and liquid amitrole formulations was studied by 10 collaborators. In the method, acid is added to the prepared amitrole sample, the solution is titrated potentiometrically with standard alkali, and the amitrole content is measured as the amount of alkali consumed between the first and second inflection points. Collaborative results on standard samples of a dry 90% formulation, a dry 50% formulation, and a liquid 2 lb/gallon formulation showed good agreement between samples and laboratories. Statistical analyses of the results were satisfactory, and the method for the assay of amitrole formulations is recommended for adoption as official, first action


1984 ◽  
Vol 6 ◽  
pp. 665-670 ◽  
Author(s):  
I. Gilmour ◽  
P.K. Swart ◽  
C.T. Pillinger

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