Geochemical fingerprints and North-African dust sources: results from a multisite network of aerosol deposition in the south-western Europe
<p><strong>Abstract</strong></p><p>The DONAIRE network (Pey et al. 2020) monitors the phenomenology of geochemical, magnetic and mineralogical variations of bulk atmospheric deposition in the Iberian Peninsula- Balearic Island. In this work we focus on recent North African dust deposition with a double objective: 1) to characterize the main geochemical fingerprints with respect to other sources of pollution; 2) to perform a source apportionment study to identify different desert-dust source areas. We used one year of data (June 2016-July 2017) from 15 monitoring sites (regional and remote, urban, industrial, or agricultural). We focus here on the impact caused by the main 4 North African dust deposition events globally affected this network.</p><p>Our results evidence that dust deposition patterns are controlled by: i) the meteorological scenario behind dust transport, ii) the occurrence/absence of wet deposition, and iii) the local-to-regional nearby topography. In general, the largest dust-deposition events occur nearby mountain barriers during low-pressure systems approaching Iberia and NW Africa.</p><p>Moderate to intense dust deposition events are well characterized by their chemical composition. The Fe/Ti, Na/Al, K/Al or (Ca+Mg)/Fe ratios reveal a number of patterns across the network. For example, Fe/Ti ratio varies from around 10-13 during warm-season events to 22-35 during cold season episodes, potentially indicating different North-African dust sources.</p><p>The best source apportionment solution extracts 10 factor/sources, from which three are mineral in composition. Two of them are interpreted as different North African dust mixture-of-sources, whereas the third mineral factor corresponds to regional dust particles. The overall contribution of such desert-dust sources may explain up to 90% of total episodic deposition during the most intense events.</p><p>These results indicate that chemical fingerprinting could be used to infer the recent North African dust deposition history. Studies on lake and peatland sequences following a similar approach are in progress and preliminary data show they be used to trace Saharan dust during the Holocene and reconstruct its relationship with climate phases.</p><p>&#160;</p><p><strong>Reference</strong></p><p>Pey J., Larrasoa&#241;a J.C., P&#233;rez N., Cerro J.C., Castillo S. <em>et al.</em> (2020). Phenomenology and geographical gradients of atmospheric deposition in southwestern Europe: results from a multi-site monitoring network. <em>Sci. Tot. Environ.</em>, 140745. https://doi.org/10.1016/j.scitotenv.2020.140745.</p><p>&#160;</p><p><strong>Acknowledgements</strong></p><p>POSAHPI (PID2019-108101RB-I00) and DONAIRE (CGL2015-68993-R) projects funded by Spanish Agencia Estatal de Investigaci&#243;n and FEDER Funds.</p>