Dissolved Metal (Fe, Mn, Zn, Ni, Cu, Co, Cd, Pb) and Metalloid (As, Sb) in Snow Water across a 2800 km Latitudinal Profile of Western Siberia: Impact of Local Pollution and Global Transfer

Snow cover is known to be an efficient and unique natural archive of atmospheric input and an indicator of ecosystem status. In high latitude regions, thawing of snow provides a sizable contribution of dissolved trace metals to the hydrological network. Towards a better understanding of natural and anthropogenic control on heavy metals and metalloid input from the atmosphere to the inland waters of Siberian arctic and subarctic regions, we measured chemical composition of dissolved (<0.22 µm) fractions of snow across a 2800 km south–north gradient in Western Siberia. Iron, Mn, Co, Ni, and Cd demonstrated sizable (by a factor of 4–7) decrease in concentration northward, which can be explained by a decrease in overall population density and the influence of dry aerosol deposition. Many elements (Mn, Ni, Cu, Cd, Pb, As, and Sb) exhibited a prominent local maximum (a factor of 2–3) in the zone of intensive oil and gas extraction (61–62° N latitudinal belt), which can be linked to gas flaring and fly ash deposition. Overall, the snow water chemical composition reflected both local and global (long-range) atmospheric transfer processes. Based on mass balance calculation, we demonstrate that the winter time atmospheric input represents sizable contribution to the riverine export fluxes of dissolved (<0.45 µm) Mn, Co, Zn, Cd, Pb, and Sb during springtime and can appreciably shape the hydrochemical composition of the Ob River main stem and tributaries.

Quality Traits and Nutritional Value of Pork and Poultry Meat from Animals Fed with Seaweeds

Seaweeds have caught the attention of the scientific community in recent years. Their production can mitigate the negative impact of anthropogenic activity and their use in animal nutrition reduces the dependency on conventional crops such as maize and soybean meal. In the context of monogastric animals, novel approaches have made it possible to optimise their use in feed, namely polysaccharide extraction, biomass fermentation, enzymatic processing, and feed supplementation with carbohydrate-active enzymes (CAZymes). Their bioactive properties make them putative candidates as feed ingredients that enhance meat quality traits, such as lipid oxidation, shelf-life, and meat colour. Indeed, they are excellent sources of essential amino acids, polyunsaturated fatty acids, minerals, and pigments that can be transferred to the meat of monogastric animals. However, their nutritional composition is highly variable, depending on species, harvesting region, local pollution, and harvesting season, among other factors. In this review, we assess the current use and challenges of using seaweeds in pig and poultry diets, envisaging to improve meat quality and its nutritional value.

Ecological state of alluvial soils of floodplain landscapes under conditions of local pollution by hydrocarbons (Western Siberia)

The paper presents an analysis of field and experimental studies of the main physicochemical parameters of oil-contaminated soils of floodplain ecosystems of the middle taiga subzone of Western Siberia. The features and main regularities of their change in different pollution zones (epicenter - impact zone) are revealed. The state of the physicochemical parameters of technogenically contaminated soils is compared with background analogs. The most important groups of chemical compounds and elements that pose an environmental hazard are considered - oil and oil products, technogenic readily soluble salts (including their toxic compounds), the ways of their migration, transformation and accumulation in contaminated soils. General recommendations are given on the use of the discovered regularities in the technical maps of reclamation measures and the system for monitoring contaminated soils.

Iron, Phosphorus and Trace Elements in Mussels’ Shells, Water, and Bottom Sediments from the Severnaya Dvina and the Onega River Basins (Northwestern Russia)

Trace elements in freshwater bivalve shells are widely used for reconstructing long-term changes in the riverine environments. However, Northern Eurasian regions, notably the European Russian North, susceptible to strong environmental impact via both local pollution and climate warming, are poorly studied. This work reports new data on trace elements accumulation by widespread species of freshwater mussels Unio spp. and Anodonta anatina in the Severnaya Dvina and the Onega River Basin, the two largest subarctic river basins in the Northeastern Europe. We revealed that iron and phosphorous accumulation in Unio spp. and Anodonta anatina shells have a strong relationship with a distance from the mouth of the studied river (the Severnaya Dvina). Based on multiparametric statistics comprising chemical composition of shells, water, and sediments, we demonstrated that the accumulation of elements in the shell depends on the environment of the biotope. Differences in the elemental composition of shells between different taxa are associated with ecological preferences of certain species to the substrate. The results set new constraints for the use of freshwater mussels’ shells for monitoring riverine environments and performing paleo-reconstructions.

Environmental Battlegrounds

This chapter opens by revisiting the Tellico Dam/snail darter controversy that pitted environmental activism against the rising tide of conservative anti-regulatory fervor. Union members joined anti-environmentalists in blaming regulation as the cause of the nation’s economic woes, especially rampant inflation. On one side, you had increasingly radical environmental groups such as Earth First!, and on the other, the Sage Brush/Wise Use rebellion that found a welcome in the Reagan administration. The Spotted Owl controversy epitomized the growing rift. Reagan appointed such arch Sage Brush rebels as James Watt as secretary of the interior and Anne Gorsuch (mother of the Supreme Court nominee) at EPA to dismantle the programs they were charged to enforce. While the Wise Use movement emerged in the Western states, it had strong followings in the East as well, as conservatives fought regulations in the Adirondacks Park, zoning in Vermont, and preservation of clean water in the Delaware River Gap. Nimbys represented a new source of activism. These were often women fighting against local pollution and other threats to their families, homes, and communities. Lois Gibbs from Love Canal and Penny Newman from California were two of the most effective leaders to emerge. Other groups such as the Clamshell and Abalone Alliances opposed new nuclear power plants.

Sedimentological and Heavy Metals Characteristics of Streets Dust in some Areas East of Baghdad for 2020

Road-side dust samples were collected during August in 2020 from selected areas of, Al-Rusafa, Baghdad, Iraq. A sedimentological and mineralogical analysis of street dust was conducted. Three areas were selected to study street dusts which are Al-Baladitat, Al-Obaidi and Ziona. The laboratory analyses were done in the Department of Geology, College of Science, University of Baghdad. The heavy metal contents were determined in the roadside dust using XRF Method. It was found that the dust is of muddy texture, and is believed to be transmitted with the various storms blowing on Baghdad or by the wheels of Cars. The results of mineralogical investigation revealed that the dust samples composed of quartz, feldspar, calcite, gypsum and sedimentary rocks fragments, as light minerals and the heavy minerals were found as garnet, epidote, chlorites, pyroxene, biotite, zircon, muscovite, hornblende, tourmaline. The heavy metals (Fe, Co, Ni, Cu, Zn and Pb) in these streets dust samples were studied and used as indicator for pollution. two o main indices are applied: contamination factor, and pollution load index. The contamination factor for Co, Zn, Pb, and Ni is classified as class 2, which indicate moderately contamination, while the contamination factor for Fe and Cu is classified as class 1, which indicate low contamination. The pollution load index values in the all of studied sites are classified as class 2 (Deterioration on site quality) indicating local pollution, as well as denote perfection with class 0 of no pollution.

Ahamer, Gilbert (2019). Mapping Global Dynamics, Geographic Perspectives from Local Pollution to Global Evolution

Ahamer, Gilbert (2019)Mapping Global Dynamics, Geographic Perspectives from Local Pollution to Global EvolutionCham: Springer Nature, 457 p.ISBN 978-3-319-51704-9

Shared Mobility in Rural Contexts: Organizational Insights from Five Mobility-as-a-Service Pilots in Sweden

Despite a growing interest in using Mobility-as-a-Service (MaaS) as a tool to address rural transport problems, the question of how to organize such a concept remains unanswered. To address this knowledge gap, this article explores organizational elements of rural MaaS pilots. The analysis, which is based on participatory observation and interviews with actors involved in five pilots in rural areas of Sweden, reveals that the motives of the actors involved in rural MaaS both overlap with and diverge from the frequently stated objectives of urban MaaS developments. Both concepts center on complementing and extending public transport, but while urban MaaS is underpinned by the fight against climate change, congestion, and local pollution, the main objective of rural MaaS is to reduce transport poverty. The analysis, moreover, illustrates that despite the geographic differences, actors involved in rural MaaS pilots face similar organizational challenges as have been reported from urban MaaS developments. In both cases, actors struggle with finding their roles, mitigating uncertainties, distributing responsibilities, and negotiating business models. Finally, the analysis finds that rural MaaS puts higher expectations on user involvement than urban MaaS and identifies a risk that rural MaaS developments might contribute to spatial injustice since the studied pilots only supported rural communities with high social capital.

High Species Richness and Extremely Low Abundance of Cumacean Communities Along the Shelf and Slope of the Gulf of Guinea (West Africa)

The Gulf of Guinea belongs to the most scarcely sampled marine basins in the oceans of the world. We have analyzed diversity and distribution patterns of cumacean communities on the shelf and slope, along the coast of Ghana. The material was collected in October and November of 2012 using a van Veen grab (0.1 m2) on nine transects. Six stations were located at each transect (25, 50, 100, 250, 500, and 1,000 m). Sixty-three species of Cumacea were recorded with Leucon and Eocuma as the most speciose genera, with 12 and eight species, respectively. Comparisons of species richness with literature data pointed that the Ghanaian coast hosts very diverse communities. About 95% of species were new to science, and the number of cumacean species known from the West Africa increased by over 100%. Nevertheless, most of the species had extremely low abundance, 13 singletons and 15 doubletons were found. Mean density of cumaceans was estimated at only 1.5 ind./0.1 m2. Species accumulation curve did not reach the asymptotic level, suggesting undersampling, despite the fact that sampling effort was high (250 samples). The highest species richness was recorded in the inner shelf (25–50 m) and on the slope (1,000 m). Cluster analysis separated shallow water communities from deeper regions on the shelf and upper slope. The most unique species composition was found at 1,000 m. Principal component analysis showed the importance of oxygen, sediments, and human-related disturbance for distribution of cumacean communities. In the shallows, oxygen content and presence of gravel were the most important factors structuring communities. In the deeper bottom areas (250–1,000 m), cumacean fauna was affected by local pollution, mainly by higher concentration of barium, other heavy metals, and THC.

Numerical analysis of kinetic mechanisms for battery thermal runaway prediction in lithium-ion batteries

The urgent need for reducing the carbon dioxide emissions has led to the powertrain electrification at different levels such as hybridization or pure electric vehicles. Despite the benefits in terms of local pollution reduction and lower carbon dioxide footprint that may be achieved with this technology, new hazards have been introduced. Among them, the combustion of the battery pack due to abuse conditions, also known as thermal runaway, is one of the biggest concerns. It can lead to the vehicle combustion under unnoticed failure conditions, threating the driver security. In this sense, different investigations have been carried out with the aim of providing a proper description of the reactions that lead to this phenomenon. Reaction mechanisms have been proposed in the literature for lithium-ion battery considering the most common battery chemistries. Nonetheless, their application leads to different results, which may hinder their utilization in modeling critical operating conditions for thermal runaway. This investigation proposes a detailed assessment of the most common reaction mechanisms, comparing their capability on reproducing the different reaction paths that lead to thermal runaway conditions to explore and depict state of the art of thermal runaway modeling. Additionally, a detailed analysis is performed to define the differences in terms of decomposition and formation reactions for each one of them. The results of this investigation demonstrate that the mechanism proposed by Kriston provides the best results trade-off considering different investigations in differential scanning calorimeter and accelerated rate calorimeter. In addition, it was found that some mechanisms have been adjusted to perform similar to the experimental results, even in the case of not having a physical meaning.