scholarly journals Spatial and temporal variability of iodine in aerosol

Author(s):  
Juan Carlos Gomez Martin ◽  
Alfonso Saiz-Lopez ◽  
Carlos Cuevas ◽  
Rafael Fernandez ◽  
Benjamin Gilfedder ◽  
...  

<p>In this work we describe the compilation and homogenization of an extensive dataset of aerosol total iodine field observations in the period between 1963 and 2018 and we discuss its spatial and temporal trends. Total iodine in aerosol shows a distinct latitudinal dependence, with an enhancement towards the northern hemisphere (NH) tropics and lower values towards the poles. Longitudinally, there is some indication of a wave-one profile in the Tropics, which peaks in the Atlantic and shows a minimum in the Pacific, following the well-known wave-one longitudinal variation of tropical tropospheric ozone. These spatial trends result from the global distribution of the main oceanic iodine source to the atmosphere (the reaction of surface ozone with aqueous iodide on the sea water-air interface). New data from Antarctica show that the south polar seasonal variation of iodine in aerosol mirrors that observed previously in the Arctic, with two equinoctial maxima and the dominant maximum occurring in spring. While no clear seasonal variability is observed in NH middle latitudes, there is an indication of different seasonal cycles in the NH tropical Atlantic and Pacific. A weak positive long-term trend is observed in the tropical annual averages, which is consistent with an enhancement of the anthropogenic ozone-driven global oceanic source of iodine over the last 50 years.</p>

2011 ◽  
Vol 24 (19) ◽  
pp. 5167-5186 ◽  
Author(s):  
Yehui Zhang ◽  
Dian J. Seidel ◽  
Jean-Christophe Golaz ◽  
Clara Deser ◽  
Robert A. Tomas

Surface-based inversions (SBIs) are frequent features of the Arctic and Antarctic atmospheric boundary layer. They influence vertical mixing of energy, moisture and pollutants, cloud formation, and surface ozone destruction. Their climatic variability is related to that of sea ice and planetary albedo, important factors in climate feedback mechanisms. However, climatological polar SBI properties have not been fully characterized nor have climate model simulations of SBIs been compared comprehensively to observations. Using 20 years of twice-daily observations from 39 Arctic and 6 Antarctic radiosonde stations, this study examines the spatial and temporal variability of three SBI characteristic—frequency of occurrence, depth (from the surface to the inversion top), and intensity (temperature difference over the SBI depth)—and relationships among them. In both polar regions, SBIs are more frequent, deeper, and stronger in winter and autumn than in summer and spring. In the Arctic, these tendencies increase from the Norwegian Sea eastward toward the East Siberian Sea, associated both with (seasonal and diurnal) variations in solar elevation angle at the standard radiosonde observation times and with differences between continental and maritime climates. Two state-of-the-art climate models and one reanalysis dataset show similar seasonal patterns and spatial distributions of SBI properties as the radiosonde observations, but with biases in their magnitudes that differ among the models and that are smaller in winter and autumn than in spring and summer. SBI frequency, depth, and intensity are positively correlated, both spatially and temporally, and all three are anticorrelated with surface temperature.


Author(s):  
Yelena I. Polyakova ◽  
Yekaterina I. Novichkova ◽  
Tatiana S. Klyuvitkina ◽  
Elizaveta A. Agafonova ◽  
Irina M. Kryukova

Presented the results of long-term studies of diatoms and aquatic palynomorphs in surface sediments of the Arctic seas and the possibility of their use for the reconstructions of paleocirculation water masses, advection of Atlantic and Bering sea water into the Arctic ocean, changes in the river runoff to the seas, sedimentary processes in the marginal filter of the largest rivers, seasonal sea ice cover and other hydrological parameters.


2021 ◽  
Vol 13 (12) ◽  
pp. 2283
Author(s):  
Hyangsun Han ◽  
Sungjae Lee ◽  
Hyun-Cheol Kim ◽  
Miae Kim

The Arctic sea ice concentration (SIC) in summer is a key indicator of global climate change and important information for the development of a more economically valuable Northern Sea Route. Passive microwave (PM) sensors have provided information on the SIC since the 1970s by observing the brightness temperature (TB) of sea ice and open water. However, the SIC in the Arctic estimated by operational algorithms for PM observations is very inaccurate in summer because the TB values of sea ice and open water become similar due to atmospheric effects. In this study, we developed a summer SIC retrieval model for the Pacific Arctic Ocean using Advanced Microwave Scanning Radiometer 2 (AMSR2) observations and European Reanalysis Agency-5 (ERA-5) reanalysis fields based on Random Forest (RF) regression. SIC values computed from the ice/water maps generated from the Korean Multi-purpose Satellite-5 synthetic aperture radar images from July to September in 2015–2017 were used as a reference dataset. A total of 24 features including the TB values of AMSR2 channels, the ratios of TB values (the polarization ratio and the spectral gradient ratio (GR)), total columnar water vapor (TCWV), wind speed, air temperature at 2 m and 925 hPa, and the 30-day average of the air temperatures from the ERA-5 were used as the input variables for the RF model. The RF model showed greatly superior performance in retrieving summer SIC values in the Pacific Arctic Ocean to the Bootstrap (BT) and Arctic Radiation and Turbulence Interaction STudy (ARTIST) Sea Ice (ASI) algorithms under various atmospheric conditions. The root mean square error (RMSE) of the RF SIC values was 7.89% compared to the reference SIC values. The BT and ASI SIC values had three times greater values of RMSE (20.19% and 21.39%, respectively) than the RF SIC values. The air temperatures at 2 m and 925 hPa and their 30-day averages, which indicate the ice surface melting conditions, as well as the GR using the vertically polarized channels at 23 GHz and 18 GHz (GR(23V18V)), TCWV, and GR(36V18V), which accounts for atmospheric water content, were identified as the variables that contributed greatly to the RF model. These important variables allowed the RF model to retrieve unbiased and accurate SIC values by taking into account the changes in TB values of sea ice and open water caused by atmospheric effects.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Jennifer A. MacKinnon ◽  
Harper L. Simmons ◽  
John Hargrove ◽  
Jim Thomson ◽  
Thomas Peacock ◽  
...  

AbstractUnprecedented quantities of heat are entering the Pacific sector of the Arctic Ocean through Bering Strait, particularly during summer months. Though some heat is lost to the atmosphere during autumn cooling, a significant fraction of the incoming warm, salty water subducts (dives beneath) below a cooler fresher layer of near-surface water, subsequently extending hundreds of kilometers into the Beaufort Gyre. Upward turbulent mixing of these sub-surface pockets of heat is likely accelerating sea ice melt in the region. This Pacific-origin water brings both heat and unique biogeochemical properties, contributing to a changing Arctic ecosystem. However, our ability to understand or forecast the role of this incoming water mass has been hampered by lack of understanding of the physical processes controlling subduction and evolution of this this warm water. Crucially, the processes seen here occur at small horizontal scales not resolved by regional forecast models or climate simulations; new parameterizations must be developed that accurately represent the physics. Here we present novel high resolution observations showing the detailed process of subduction and initial evolution of warm Pacific-origin water in the southern Beaufort Gyre.


Radiocarbon ◽  
1980 ◽  
Vol 22 (3) ◽  
pp. 684-692 ◽  
Author(s):  
Georgette Delibrias

14C measurements were carried out on sea water samples collected in 1973, in the Indian ocean. The results obtained for 9 vertical profiles between 27° S and 48°S are presented. In surface water, the bomb 14C content is maximum at middle latitudes. A time lag relative to the north hemisphere bomb 14C delivery is apparent. In the more southern latitudes, 14C content remains very low.


1988 ◽  
Vol 25 (5) ◽  
pp. 701-709 ◽  
Author(s):  
A. E. Aksu ◽  
G. Vilks

Oxygen and carbon isotopic analyses have been performed on the tests of Planulina wuellerstorfi and three size fractions of sinistral Neogloboquadrina pachyderma recovered from 33 Arctic Ocean surface-sediment samples. Stable isotopic compositions of N. pachyderma are found to be dependent on the test size: larger specimens show considerable enrichment in both δ18O and δ18C. The difference between the isotopic compositions of the 63–125 and 125–250 μm size fractions in N. pachyderma can be explained by biogenic fractionation effects during foraminiferal test growth. Larger (250–500 μm) N. pachyderma displayed accretions of secondary calcite, i.e., the outermost shell contained significant amounts of inorganically precipitated magnesium calcite. Thus, larger foraminifera may not be suited for down-core stable isotopic studies. There is a difference of ~2‰ between δ18O values of surface samples from the eastern and western Arctic Ocean, reflecting large differences between surface-water salinity in these regions. Therefore, oxygen isotopic data may have limited use as a chronostratigraphic tool in down-core studies in the Arctic Ocean, but we can use them to infer past variations in surface-water salinities. Planulina wuellerstorfi also showed depletions of both δ18O and δ18C in its calcite tests relative to calcite precipitated in isotopic equilibrium with ambient sea water; these depletions ranged from −0.8 to −0.9‰ in δ18Oand −1.2 to −0.9‰ in δ18C. This taxon is found to deposit its shell very close to the δ18C of ΣCO2 of bottom waters.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
A. Y. Yang ◽  
C. H. Langmuir ◽  
Y. Cai ◽  
P. Michael ◽  
S. L. Goldstein ◽  
...  

AbstractThe plate tectonic cycle produces chemically distinct mid-ocean ridge basalts and arc volcanics, with the latter enriched in elements such as Ba, Rb, Th, Sr and Pb and depleted in Nb owing to the water-rich flux from the subducted slab. Basalts from back-arc basins, with intermediate compositions, show that such a slab flux can be transported behind the volcanic front of the arc and incorporated into mantle flow. Hence it is puzzling why melts of subduction-modified mantle have rarely been recognized in mid-ocean ridge basalts. Here we report the first mid-ocean ridge basalt samples with distinct arc signatures, akin to back-arc basin basalts, from the Arctic Gakkel Ridge. A new high precision dataset for 576 Gakkel samples suggests a pervasive subduction influence in this region. This influence can also be identified in Atlantic and Indian mid-ocean ridge basalts but is nearly absent in Pacific mid-ocean ridge basalts. Such a hemispheric-scale upper mantle heterogeneity reflects subduction modification of the asthenospheric mantle which is incorporated into mantle flow, and whose geographical distribution is controlled dominantly by a “subduction shield” that has surrounded the Pacific Ocean for 180 Myr. Simple modeling suggests that a slab flux equivalent to ~13% of the output at arcs is incorporated into the convecting upper mantle.


2016 ◽  
Author(s):  
Imran A. Girach ◽  
Narendra Ojha ◽  
Prabha R. Nair ◽  
Andrea Pozzer ◽  
Yogesh K. Tiwari ◽  
...  

Abstract. We present ship-borne measurements of surface ozone, carbon monoxide and methane over the Bay of Bengal (BoB), the first time such measurements have been taken during the summer monsoon season, as a part of the Continental Tropical Convergence Zone (CTCZ) experiment during 2009. O3, CO, and CH4 mixing ratios exhibited significant spatial and temporal variability in the ranges of 8–54 nmol mol−1, 50–200 nmol mol−1, and 1.57–2.15 µmol mol−1, with means of 29.7 ± 6.8 nmol mol−1, 96 ± 25 nmol mol−1, and 1.83 ± 0.14 µmol mol−1, respectively. The average mixing ratios of trace gases over northern BoB (O3: 30 ± 7 nmol mol−1, CO: 95 ± 25 nmol mol−1, CH4: 1.86 ± 0.12 µmol mol−1), in airmasses from northern or central India, did not differ much from those over central BoB (O3: 27 ± 5 nmol mol−1, CO: 101 ± 27 nmol mol−1, CH4: 1.72 ± 0.14 µmol mol−1), in airmasses from southern India. Spatial variability is observed to be most significant for CH4. The ship-based observations, in conjunction with backward air trajectories and ground-based measurements over the Indian region, are analyzed to estimate a net ozone production of 1.5–4 nmol mol−1 day−1 in the outflow. Ozone mixing ratios over the BoB showed large reductions (by ~ 20 nmol mol−1) during four rainfall events. Temporal changes in the meteorological parameters, in conjunction with ozone vertical profiles, indicate that these low ozone events are associated with downdrafts of free-tropospheric ozone-poor airmasses. While the observed variations in O3 and CO are successfully reproduced using the Weather Research and Forecasting model with Chemistry (WRF-Chem), this model overestimates mean concentrations by about 20 %, generally overestimating O3 mixing ratios during the rainfall events. Analysis of the chemical tendencies from model simulations for a low-O3 event on August 10, 2009, captured successfully by the model, shows the key role of horizontal advection in rapidly transporting ozone-rich airmasses across the BoB. Our study fills a gap in the availability of trace gas measurements over the BoB, and when combined with data from previous campaigns, reveals large seasonal amplitude (~ 39 and ~ 207 nmol mol−1 for O3 and CO, respectively) over the northern BoB.


2017 ◽  
Vol 30 (22) ◽  
pp. 8913-8927 ◽  
Author(s):  
Svenja H. E. Kohnemann ◽  
Günther Heinemann ◽  
David H. Bromwich ◽  
Oliver Gutjahr

The regional climate model COSMO in Climate Limited-Area Mode (COSMO-CLM or CCLM) is used with a high resolution of 15 km for the entire Arctic for all winters 2002/03–2014/15. The simulations show a high spatial and temporal variability of the recent 2-m air temperature increase in the Arctic. The maximum warming occurs north of Novaya Zemlya in the Kara Sea and Barents Sea between March 2003 and 2012 and is responsible for up to a 20°C increase. Land-based observations confirm the increase but do not cover the maximum regions that are located over the ocean and sea ice. Also, the 30-km version of the Arctic System Reanalysis (ASR) is used to verify the CCLM for the overlapping time period 2002/03–2011/12. The differences between CCLM and ASR 2-m air temperatures vary slightly within 1°C for the ocean and sea ice area. Thus, ASR captures the extreme warming as well. The monthly 2-m air temperatures of observations and ERA-Interim data show a large variability for the winters 1979–2016. Nevertheless, the air temperature rise since the beginning of the twenty-first century is up to 8 times higher than in the decades before. The sea ice decrease is identified as the likely reason for the warming. The vertical temperature profiles show that the warming has a maximum near the surface, but a 0.5°C yr−1 increase is found up to 2 km. CCLM, ASR, and also the coarser resolved ERA-Interim data show that February and March are the months with the highest 2-m air temperature increases, averaged over the ocean and sea ice area north of 70°N; for CCLM the warming amounts to an average of almost 5°C for 2002/03–2011/12.


Author(s):  
Gennady M. Kamenev

An expanded description of a little-known arctic species Montacuta spitzbergensis from the Sea of Okhotsk with new data on its morphology, ecology and geographical distribution is given. This is the first record of M. spitzbergensis from the north-western Pacific. It differs from other species of Montacuta in its large (to 8.4 mm), elongate–ovate, thick shell with wide, slightly curved hinge plate, wide, short, and shallow resilifer, and weakly developed external ligament. This species occurs in the Arctic Ocean (Spitsbergen, Barents, Kara, Laptev and Chukchi Seas) and the Pacific Ocean (Sea of Okhotsk) at depths from 9 to 232 m at a bottom temperature from −1.62°C to +2.50°C. The hinge structure of the type species of the genera Montacuta and Tellimya is also discussed.


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