Deformation and reaction fabrics in eclogites from the Western Gneiss Region (Norway) - evidence of dehydration reactions attributed to episodic deformation

Author(s):  
Claudia A. Trepmann ◽  
Ane K. Engvik ◽  
Erick G. Prince Gutierrez

<p>The eclogites from Vårdalneset, Western Gneiss Region, Norway, show an exceptional large variety of reaction and deformation microfabrics that document the processes and conditions during burial and exhumation. Coarse grained eclogites comprise about 35% omphacite, 25% garnet and 20% amphibole with various amounts of white mica, zoisite, kyanite, rutile, zircon and pyrite. Their fabric is characterized by few mm long and several hundred µm wide amphibole and omphacite grains aligned in the foliation plane with zoned garnet porphyroblasts up to several mm in diameter. In contrast, finer-grained mylonitic eclogites with grain diameters of few hundred µm comprise systematically higher amounts of garnet (45%) and omphacite (35%) and generally less amphibole (< 5%) but similar amounts of zoisite, white mica, rutile and quartz. In the coarse-grained eclogite, amphibole shows evidence of dislocation creep as indicated by undulatory extinction, subgrains and recrystallized grains in necks of boudinaged coarse amphibole layers as well as in contact to garnet. The large garnet porphyroblasts generally show a complex zonation with an inclusion-rich Fe-poor and Mg-rich inner core surrounded by a zone with Fe- and Ca-rich patches and a broad Mg-rich, Ca- and Fe-poor rim. Only at contact to coarse amphibole an additional, a few tens of µm thin serrated rim further enriched in Mg can occur. At the direct contact to such serrated Mg-rich rims, amphibole is partly replaced by a fine-grained quartz-kyanite ± rutile aggregate, indicating dehydration reactions of amphibole. Quartz - kyanite ± rutile aggregates are surrounding garnet also in contact to omphacite, zoisite and to other garnet crystals. The microstructures suggest that deformation and dehydration of amphibole are coupled and played an important role during deformation of the eclogites finally leading to the mylonitic eclogites with higher amounts of garnet and omphacite. Deformation is suggested to have triggered the dehydration reaction by a slight and local increase in temperature. Furthermore, deformation provided additional pathways for the escaping fluids along the increased grain and phase boundary area, as indicated by commonly present quartz within interstitials between recrystallized amphibole grains. In all samples, few µm wide amphibole rims replacing garnets document restricted rehydration-reactions at a later stage. The large variety of the deformation and reaction microfabrics exemplarily show that both deformation and metamorphic reactions did not proceed at long-term continuous conditions, but that both are coupled and occurred episodically.</p>

Author(s):  
Ziyi Yin ◽  
Ruijin Liu ◽  
Zhiliang Xiong ◽  
Zejian Yuan

We consider the problem of forecasting the future locations of pedestrians in an ego-centric view of a moving vehicle. Current CNNs or RNNs are flawed in capturing the high dynamics of motion between pedestrians and the ego-vehicle, and suffer from the massive parameter usages due to the inefficiency of learning long-term temporal dependencies. To address these issues, we propose an efficient multimodal transformer network that aggregates the trajectory and ego-vehicle speed variations at a coarse granularity and interacts with the optical flow in a fine-grained level to fill the vacancy of highly dynamic motion. Specifically, a coarse-grained fusion stage fuses the information between trajectory and ego-vehicle speed modalities to capture the general temporal consistency. Meanwhile, a fine-grained fusion stage merges the optical flow in the center area and pedestrian area, which compensates the highly dynamic motion of ego-vehicle and target pedestrian. Besides, the whole network is only attention-based that can efficiently model long-term sequences for better capturing the temporal variations. Our multimodal transformer is validated on the PIE and JAAD datasets and achieves state-of-the-art performance with the most light-weight model size. The codes are available at https://github.com/ericyinyzy/MTN_trajectory.


2005 ◽  
Vol 69 (6) ◽  
pp. 1059-1075 ◽  
Author(s):  
G. H. Shi ◽  
B. Stöckhert ◽  
W. Y. Cui

AbstractFour distinct textures and related compositions of kosmochlor (Ko) and chromian jadeite in rocks from the Myanmar jadeitite area are described: (1) spheroidal or ellipsoidal aggregates with a corona texture surrounding relict chromite; (2) spheroidal or ellipsoidal aggregates with a core of jadeite; (3) granoblastic textures in undeformed coarse-grained clinopyroxene rocks; and (4) recrystallized fine-grained aggregates in deformed jadeitite. Nearly pure kosmochlor (97 mol.% NaCrSi2O6) was found in type 2 textures, closest to the end-member reported so far from a terrestrial rock. Sharp compositional boundaries between kosmochlor and chromian jadeite of variable composition are interpreted to be related to progressive crystallization or replacement at differing conditions. The compositions analysed plot along the kosmochlor-jadeite join. In contrast to conclusions of previous studies on the Myanmar clinopyroxenes there is no unequivocal evidence for miscibility gaps. The preservation of relict chromite in the centre of coronitic spheroidal or ellipsoidal aggregates of kosmochlor and jadeite indicates a metasomatic origin from a peridotite protolith at an inferred minimum pressure of 1.0 GPa and temperatures of 250—370°C. Recrystallization during later ductile deformation of the clinopyroxene rocks in the dislocation creep regime leads to fine-grained aggregates of chromian jadeite, which are of particular gemmological interest.


1981 ◽  
Vol 32 (6) ◽  
pp. 935 ◽  
Author(s):  
DR Hudson ◽  
RA Hunter ◽  
DW Peter

Grain size of elemental selenium is a major factor controlling the long-term effectiveness of intraruminal selenium pellets. Microscope studies of polished sections of new and used selenium pellets showed that two commercially manufactured pellets contained selenium with average grain sizes about 4 and 40 �m respectively. Plasma selenium concentrations in sheep treated with pellets containing the coarse-grained selenium were maintained at higher levels over longer periods of time than those measured for sheep treated with pellets with fine-grained selenium. Pellets removed from sheep after 2, 4, 8, 16 and 28 days showed a progressive increase in the degree of alteration of selenium to a compound of average composition (g/100 g) iron, 33.7; selenium, 51.3 ; oxygen, 15.0. After 28 days only a small percentage of elemental selenium remained in pellets with fine-grained selenium, whereas about 50% remained in pellets with coarse-grained selenium. CSIRO prototype pellets, for which long-term effectiveness had been established, also contained coarse-grained selenium, and remnants of selenium were found in pellets that had been in sheep for periods up to 3 years. Selenium, administered in gelatin capsules or as sachets containing glass-selenium mixtures, was stable under the pH-Eh conditions of the rumen, but was rendered unstable in selenium pellets or iron-selenium mixtures by the presence of iron. It is probable that the most rapid release of selenium to the sheep occurs as a result of a chemical reaction involving the oxidation of iron and concomitant alteration of elemental selenium to iron selenide.


2021 ◽  
Vol 44 (2) ◽  
pp. 134-140
Author(s):  
V. E. Glotov

The article presents and analyzes the data on ground waters of active (suprapermafrost) and hindered (subpermafrost) water exchange of geodynamically different terrains in order to prove the hydrogeological importance of their historical and tectonic characteristics. On the example of Trans-Polar Chukotka it is shown that, under suprapermafrost conditions, the ubiquitous eluvial-deluvial nappes are the most water-abundant on the terrane – a fragment of the passive continental margin, whereas they are the least water-abundant on the terrains of the active margin. Hydrogeological situation changes under subpermafrost conditions: more permeable and water-retaining rocks compose the terranes of the active margin. These differences are associated with the level of rock tectonic decompaction and, accordingly, with different intensity of weathering processes in the terrane rocks of different geodynamic origin in suprapermafrost and subpermafrost conditions. The hypergenesis zone on the terranes of the passive continental margin features coarse-grained rock weathering products accumulated in relatively calm geological and historical environments, the aggregate is sandy. The terranes of the active margin, which underwent long-term subvertical and subhorizontal displacements contain more fine-grained weathering products; the aggregate includes sandy loam and clay sand. Since the permafrost strata in both Trans-Polar Chukotka and Eastern Siberia is greater than the depth of hypergene transformations, the terranes of the active continental margin, the rocks of which were impacted by tectonic decompaction processes, mainly of a strike-slip and thrust nature, feature greater water abundance in subpermafrost conditions.


2019 ◽  
Vol 65 (252) ◽  
pp. 531-541 ◽  
Author(s):  
TOMOTAKA SARUYA ◽  
KOKI NAKAJIMA ◽  
MORIMASA TAKATA ◽  
TOMOYUKI HOMMA ◽  
NOBUHIKO AZUMA ◽  
...  

ABSTRACTWe investigated the effects of microparticles and grain size on the microstructural evolutions and mechanical properties of polycrystalline ice. Uniaxial compression tests were conducted using fine-grained pure ice and silica-dispersed ice under various conditions. Deformation behavior of fine-grained ice was found to be characterized by stress exponent n ≈ 2 and activation energy Q ≈ 60 kJ mol−1. The derived strain rates of fine-grained ice were ≈ 1 order of magnitude larger than those of coarse-grained ice obtained in previous studies, and they were found to be independent of particle dispersion and dependent on the mean grain size of ice, with grain size exponent p ≈ 1.4. Work hardening was observed in dislocation creep, while the strain rate continued to decrease. These results indicate that the deformation mechanism of fine-grained ice is different from typical dislocation creep, often associated with n = 3. Although microparticles restricted grain growth, there was little direct effect on the deformation of fine-grained ice. Microstructural observations of the ice samples indicated that the grain boundaries were straight and that the subgrain boundary densities increased after deformation. Our experiments suggest that grain size and boundaries play important roles in the deformation processes of polycrystalline ice.


Solid Earth ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 95-116 ◽  
Author(s):  
Felix Hentschel ◽  
Claudia A. Trepmann ◽  
Emilie Janots

Abstract. Deformation microstructures of albitic plagioclase and K-feldspar were investigated in mylonitic pegmatites from the Austroalpine basement south of the western Tauern Window by polarized light microscopy, electron microscopy and electron backscatter diffraction to evaluate feldspar deformation mechanisms at greenschist facies conditions. The main mylonitic characteristics are alternating almost monophase quartz and albite layers, surrounding porphyroclasts of deformed feldspar and tourmaline. The dominant deformation microstructures of K-feldspar porphyroclasts are intragranular fractures at a high angle to the stretching lineation. The fractures are healed or sealed by polyphase aggregates of albite, K-feldspar, quartz and mica, which also occur along intragranular fractures of tourmaline and strain shadows around other porphyroclasts. These polyphase aggregates indicate dissolution–precipitation creep. K-feldspar porphyroclasts are partly replaced by albite characterized by a cuspate interface. This replacement is interpreted to take place by interface-coupled dissolution–precipitation driven by a solubility difference between K-feldspar and albite. Albite porphyroclasts are replaced at boundaries parallel to the foliation by fine-grained monophase albite aggregates of small strain-free new grains mixed with deformed fragments. Dislocation glide is indicated by bent and twinned albite porphyroclasts with internal misorientation. An indication of effective dislocation climb with dynamic recovery, for example, by the presence of subgrains, is systematically missing. We interpret the grain size reduction of albite to be the result of coupled dislocation glide and fracturing (low-temperature plasticity). Subsequent growth is by a combination of strain-induced grain boundary migration and formation of growth rims, resulting in an aspect ratio of albite with the long axis within the foliation. This strain-induced replacement by nucleation (associated dislocation glide and microfracturing) and subsequent growth is suggested to result in the observed monophase albite layers, probably together with granular flow. The associated quartz layers show characteristics of dislocation creep by the presence of subgrains, undulatory extinction and sutured grain boundaries. We identified two endmember matrix microstructures: (i) alternating layers of a few hundred micrometres' width, with isometric, fine-grained feldspar (on average 15 µm in diameter) and coarse-grained quartz (a few hundred micrometres in diameter), representing lower strain compared to (ii) alternating thin layers of some tens of micrometres' width composed of fine-grained quartz (<20 µm in diameter) and coarse elongated albite grains (long axis of a few tens of micrometres) defining the foliation, respectively. Our observations indicate that grain size reduction by strain-induced replacement of albite (associated dislocation glide and microfracturing) followed by growth and granular flow simultaneous with dislocation creep of quartz are playing the dominating role in formation of the mylonitic microstructure.


2013 ◽  
Vol 5 (1) ◽  
pp. 365-390 ◽  
Author(s):  
J. Bial ◽  
C. A. Trepmann

Abstract. We examine the microfabric development in high-pressure, low-temperature metamorphic serpentinite mylonites exposed in the Erro-Tobbio Unit (Voltri Massif, Italy) using polarization microscopy and electron microscopy (SEM/EBSD, EMP). The mylonites are derived from mantle peridotites, were serpentinized at the ocean floor and underwent high pressure metamorphism during Alpine subduction. They contain diopside and olivine porphyroclasts embedded in a fine-grained matrix essentially consisting of antigorite. The porphyroclasts record brittle and crystal-plastic deformation of the original peridotites in the upper mantle at stresses of a few hundred MPa. After the peridotites became serpentinized, deformation occurred mainly by dissolution-precipitation creep resulting in a foliation with flattened olivine grains at phase boundaries with antigorite, crenulation cleavages and olivine and antigorite aggregates in strain shadows next to porphyroclasts. It is suggested that the fluid was provided by dehydration reactions of antigorite forming olivine and enstatite during subduction and prograde metamorphism. At sites of stress concentration around porphyroclasts antigorite reveals an associated SPO and CPO, characteristically varying grain sizes and sutured grain boundaries, indicating deformation by dislocation creep. Stresses were probably below a few tens of MPa in the serpentinites, which was not sufficiently high to allow for crystal-plastic deformation of olivine at conditions at which antigorite is stable. Accordingly, any intragranular deformation features of the newly precipitated olivine in strain shadows are absent. The porphyroclast microstructures are not associated with the microstructures of the mylonitic matrix, but are inherited from an independent earlier deformation. The porphyroclasts record a high-stress deformation in the upper mantle of the oceanic lithosphere probably related to rifting processes, whereas the antigorite matrix records deformation at low stresses during subduction and exhumation.


2001 ◽  
Vol 34 (1) ◽  
pp. 129 ◽  
Author(s):  
Α. ΑΥΓΕΡΙΝΑΣ ◽  
Α. ΚΙΛΙΑΣ ◽  
Α. ΚΟΡΩΝΑΙΟΣ ◽  
Δ. ΜΟΥΝΤΡΑΚΗΣ ◽  
W. FRISCH ◽  
...  

The kinematic of the Cretaceous deformation and the relationship between deformation and metamorphism of the Pelagonian crystalline was studied in Voras Mt (northern Greece). The Pelagonian crystalline in this area has been subdivided into a lower, core part, consisting mainly of gneissic rocks and schists and an upper, cover part, consistine of schists and quartzites with marble intercalations. Intensely deformed granitic rocks of Upper Paleozoic age intrude the Pelagonian crystalline basement. An S j foliation is the oldest fabric recognized in the Pelagonian crystalline. Sj is mainly defined by syn-Sjgarnet(Gr1), biotite(Btj), white mica (Wnij), chloritoid, kyanite and plagioclase in the metapelitic rocks and green amphibole, epidote, plagioclase, and biotiteiBtj) in the amphibolite. Garnet grows also in some cases post-kinematically. Ilmenite and tourmaline are often found in the pelitic rocks as well. S is overprinted by an S2 foliation that developed as a crenulation cleavage. In most places, however, S2 has destroyed all earlier fabrics and a single S2 fabric is present related to, isoclinal or sheath folds intrafolial in places. S2 in the metapelitic rocks is characterized by the syn-S2 development of chlorite, white mica(Wm2) and plagioclase. In the amphibolite S2 is mainly defined by the syn-kinematic development of actinolite, plagioclase, biotite(Bt2), white mica(Wm2) and chlorite. During D2 garnet(Gr1) and biotiteiBtj) are partially replaced by chlorite, while green amphibole is replaced by actinolite and chlorite. Chloritoid remains generally stable along the S2-planes but in some places transforms to chlorite and sericite. Furthermore, D2 was locally followed by a static post-kinematic annealing indicated by polygonal quartz microfabrics with equilibrated grain boundaries and triple points. The overall orientation of S2 is dome shaped with a gentle SW-ward and NE-ward dip in the southwestern and northeastern flanks of the dome respectively. Syn-S2 minerals defined a very well exposed NW-SE trending stretching lineation. Kinematic indicators show a main top to the SE sense of movement. An S3 crenulation cleavage associated with asymmetric NW-SE trending folds is also present in most parts of the core and cover rocks, possibly, related to a constrictional type of deformation. A well developed, S4 shear band cleavage is mainly present in the upper parts of the metamorphic dome and formed under cooler conditions. S4 shear bands are associated with a NW-SE developed stretching lineation defined by elongated and dynamically recrystallized quartz grains and a preferred orientation of white mica and chlorite. Along the S4 shear bands a transformation of garnet, biotite, chloritoid and amphibole into chlorite is always observed. S4 shear bands indicate a main top to the SE sense of movement. The P-T metamorphic conditions were derived from textural equilibria and mineral assemblages, as well as from the spatial distribution of the metamorphic minerals. Syn-Dj metamorphism reached the conditions of the boundaries between greenschist and amphibolite facies. Syn-D2 retrogression took place under greenschist facie conditions. K/Ar radiometric datings on coarse-grained syn-St and younger fine-grained syn-S2 micas define an Early Cretaceous cooling age ('135Ma) for the older event and a Mid- to Late Cretaceous age ('90-80Ma) for the second event. A white mica age of ca. 65Ma correlates with S4 shear band clevage. Furthermore, the intrusion age of a granitic body into the Pelagonian crystalline is dated using the Pb/Pb single zircon evaporation method. The estimated intrusion age of 300±3Ma suggests that the Pelagonian crystalline was affected by a pre-kinematic magmatic activity relative to its Cretaceous deformation.


Geosciences ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 420
Author(s):  
Joseph W. Millard ◽  
Caleb W. Holyoke ◽  
Rachel K. Wells ◽  
Cole Blasko ◽  
Andreas K. Kronenberg ◽  
...  

We determined the activation volumes (V*) for polycrystalline magnesite with grain sizes of 2 and 80 µm deforming by low temperature plasticity (LTP) mechanisms (kinking and dislocation glide), diffusion creep, and dislocation creep at temperatures of 500, 750, and 900 °C, respectively, and a strain rate of 1–2 × 10−5 s−1 at effective pressures of 2.9–7.5 GPa in a D-DIA and 0.76 GPa in a Griggs apparatus. In each set of experiments performed at a given temperature, the strength of magnesite increases with increasing pressure. Microstructures of fine-grained magnesite deformed at 500 °C and 750 °C are consistent with deformation by LTP mechanisms and diffusion creep, respectively. Microstructures of coarse-grained magnesite deformed at 900 °C are consistent with deformation by dislocation creep. Pressure dependencies of magnesite flow laws for LTP, diffusion creep, and dislocation creep are given by activation volumes of 34 (± 7), 2 (± 1), and 10 (± 5) × 10−6 m3/mol, respectively. Addition of these activation volumes to previously determined flow laws predicts magnesite strength to be much lower than the flow strength of olivine at all subduction zone depths of the upper mantle. Thus, subducting oceanic lithosphere that has been partially carbonated by reaction with CO2-bearing fluids may deform at lowered stresses where magnesite is present, possibly resulting in strain localization and unstable run-away shear.


Minerals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 213 ◽  
Author(s):  
Yang Li ◽  
Yang Yang ◽  
Yi-Can Liu ◽  
Chiara Groppo ◽  
Franco Rolfo

Corundum-bearing anatectic aluminous rocks are exposed in the deeply subducted North Dabie complex zone (NDZ), of Central China. The rocks consist of corundum, biotite, K-feldspar and plagioclase, and show clear macro- and micro-structural evidence of anatexis by dehydration melting of muscovite in the absence of quartz. Mineral textures and chemical data integrated with phase equilibria modeling, indicate that coarse-grained corundum in leucosome domains is a peritectic phase, reflecting dehydration melting of muscovite through the reaction: Muscovite = Corundum + K-feldspar + Melt. Aggregates of fine-grained, oriented, corundum grains intergrown with alkali feldspar in the mesosome domains are, instead, formed by the dehydration melting of muscovite with aluminosilicate, through the reaction: Muscovite + Al-silicate = Corundum + K-feldspar + Melt. P-T pseudosections modeling in the Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O-TiO2 system constrains peak pressure-temperature (P-T) conditions at 900–950 °C, 9–14 kbar. The formation of peritectic corundum in the studied rocks is a robust petrographic evidence of white mica decompression melting that has occurred during the near-isothermal exhumation of the NDZ. Combined with P-T estimates for the other metamorphic rocks in the area, these new results further confirm that the NDZ experienced a long-lived high-T evolution with a near-isothermal decompression path from mantle depths to lower-crustal levels. Furthermore, our new data suggest that white mica decompression melting during exhumation of the NDZ was a long-lasting process occurring on a depth interval of more than 30 km.


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