scholarly journals Pollution level and risk assessment of heavy metals in sewage sludge from eight wastewater treatment plants in Wuhu City, China

2020 ◽  
Vol 18 (2) ◽  
pp. e1103
Author(s):  
Hanwen Zhang ◽  
Yuee Huang ◽  
Shu Zhou ◽  
Liangchen Wei ◽  
Zhiyuan Guo ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Correlation Analysis ◽  
Ecological Risk ◽  
Wastewater Treatment Plants ◽  
Pollution Index ◽  
Potential Ecological Risk ◽  
Potential Sources

Aim of study: To investigate the content, contamination levels and potential sources of five heavy metals (Hg, Pb, Cd, Cr, As) in sewage sludge from eight wastewater treatment plants (W1 to W8).Area of study: Wuhu, located in southeastern Anhui Province, southeastern China.Material and methods: The sewage sludge pollution assessment employed the single-factor pollution index, Nemerow’s synthetic pollution index, monomial potential ecological risk coefficient and potential ecological risk index. The potential sources among the five heavy metals were determined using the Pearson’s correlation analysis and principal component analysis (PCA).Main results: The mean concentrations of the heavy metals were 0.27 mg/kg (Hg), 70.78 mg/kg (Pb), 3.48 mg/kg (Cd), 143.65 mg/kg (Cr) and 22.17 mg/kg (As). W1, W5 and W6 sewage sludge samples showed the highest levels of heavy metal contamination, and cadmium had the highest contamination level in the study area. Pearson’s correlation analysis and PCA revealed that Pb and Cd mainly derived from traffic emissions and the manufacturing industry and that As and Cr originated from agricultural discharges.Research highlights: The pollution of cadmium in Wuhu should be controlled preferentially. The heavy metal pollution of W1, W5 and W6 sewage treatment plants is relatively high, they should be key prevention targets.

scholarly journals Assessment of Heavy Metal Pollution and Potential Ecological Risk in Sewage Sludge from Municipal Wastewater Treatment Plant Located in the Most Industrialized Region in Poland—Case Study

2019 ◽  
Vol 16 (13) ◽  
pp. 2430 ◽  
Author(s):  
Malwina Tytła
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Risk Factor ◽  
Sewage Sludge ◽  
Ecological Risk ◽  
Treatment Plant ◽  
Potential Ecological Risk ◽  
Pollution Level ◽  
Chemical Forms

This study aimed to assess the pollution and potential ecological risk of seven heavy metals (Cd, Cr, Cu, Hg, Ni, Pb, and Zn) in the sewage sludge collected from a wastewater treatment plant (WWTP), located in the most industrialized region of Poland (Silesian Voivodeship). The concentrations of heavy metals were determined using inductively coupled plasma optical spectrometry (ICP-OES) and cold vapor atomic absorption spectrometry (CVAAS). The chemical forms (chemical speciation) of heavy metals were determined using the three-step chemical sequential extraction procedure, developed by the Community Bureau of Reference (BCR). To assess the pollution level and potential ecological risk, the following indices were used: Geoaccumulation Index (Igeo), Potential Ecological Risk Factor (ER), Individual Contamination Factor (ICF), Risk Assessment Code (RAC), and Ecological Risk Factor (ERF)—the author’s index. Sludge samples were collected at successive stages of processing. The results revealed that the activated sludge process and sludge thickening have a significant impact on heavy metal distribution, while anaerobic digestion and dehydration decrease their mobility. The most dominant metals in the sludge samples were Zn and Cu. However, the content of heavy metals in sewage sludge did not exceed the permissible standards for agricultural purposes. The concentrations of heavy metals bound to the immobile fractions exhibited higher concentrations, compared to those bound to mobile fractions (except Zn). The values of the total indices indicated that sludge samples were moderately to highly contaminated with Zn, Hg, Cd, Cu, and Pb, of which only Hg, Cd, and Cu posed a potential ecological risk, while according to the speciation indices, sludge samples were moderately to very highly polluted with Zn, Cu, Cd, Cr, and Ni, of which Zn, Ni, and Cd were environmentally hazardous. The obtained results proved that assessment of the pollution level and potential ecological risk of heavy metals in sewage sludge requires knowledge on both their total concentrations and their chemical forms. Such an approach will help prevent secondary pollution of soils with heavy metals, which may influence the reduction of health risks associated with the consumption of plants characterized by a high metal content.

scholarly journals Temporal variability of sewage sludge heavy metal content from Greek wastewater treatment plants

2016 ◽  
Vol 23 (2) ◽  
pp. 271-283 ◽  
Author(s):  
Thomas Spanos ◽  
Antoaneta Ene ◽  
Chrysoula Styliani Patronidou ◽  
Christina Xatzixristou
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Temporal Variability ◽  
Metal Content ◽  
Wastewater Treatment Plants ◽  
Chromium Species ◽  
Metal Concentrations ◽  
Metal Contents

AbstractThe aim of this study was to evaluate the temporal variations of selected heavy metals level in anaerobic fermented and dewatered sewage sludge. Sewage sludge samples were collected in different seasons and years from three municipal wastewater treatment plants (WWTPs) located in Northern Greece, in Kavala (Kavala and Palio localities) and Drama (Drama locality) Prefectures. An investigation of the potential of sludge utilization in agriculture was performed, based on the comparison of average total heavy metal concentrations and of chromium species (hexavalent, trivalent) concentrations with the allowed values according to the Council Directive 86/278/EEC and Greek national legislation (Joint Cabinet Decision 80568/4225/91) guidelines. In this regard, all the investigated heavy metals (Cd, Cr, Cu, Ni, Pb, Zn, Hg) and chromium species Cr(VI) and Cr(III) have average concentrations (dry matter weight) well below the legislated thresholds for soil application, as following: 2.12 mg kg−1Cd; 103.7 mg kg−1Cr; 136.4 mg kg−1Cu; < 0.2 mg kg−1Hg; 29.1 mg kg−1Ni; 62.0 mg kg−1Pb; 1253.2 mg kg−1Zn; 1.56 mg kg−1Cr(VI) and 115.7 mg kg−1Cr(III). Values of relative standard deviation (RSD) indicate a low or moderate temporal variability for domestic-related metals Zn (10.3-14.7%), Pb (27.9-44.5%) and Cu (33.5-34.2%), and high variability for the metals of mixed origin or predominantly resulted from commercial activities, such as Ni (42.4-50.7%), Cd (44.3-85.5%) and Cr (58.2-102.0%). For some elements the seasonal occurrence pattern is the same for Kavala and Palio sludge, as following: a) Cd and Cr: spring>summer>winter; b) Cu, Ni and Pb: winter>spring>summer. On average, in summer months (dry season) metal concentrations are lower than in spring and winter (wet seasons), with the exception of Zn. For Kavala and Palio the results demonstrate that the increased number of inhabitants (almost doubled) in summer time due to tourism does not influence the metal levels in sludge. Comparing the results obtained for similar spring-summer-winter sequences in 2007 and 2010/11 and for the spring season in 2007, 2008 and 2010, it can be noticed that, in general, the average heavy metal contents show an increasing tendency towards the last year. In all the measurement periods, the Palio sludge had the highest metal contents and Kavala sludge the lowest, leading to the conclusion that the WWTP operating process rather than population has a significant effect upon the heavy metal content of sludge. Cr(VI)/Cr(total) concentration ratios are higher for Kavala sludge in the majority of sampling campaigns, followed by Drama and Palio sludge. The metals which present moderate to strong positive correlation have common origin, which could be a domestic-commercial mixed source.

The Contamination Status of Heavy Metal in the Sediment of Beng River and the Protection for the Ecological Safety Engineering

2013 ◽  
Vol 726-731 ◽  
pp. 1809-1812
Author(s):  
Ji Cai Qiu
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Ecological Risk ◽  
River Sediment ◽  
Risk Index ◽  
Pollution Index ◽  
Potential Ecological Risk ◽  
Sediment Pollution ◽  
Ecological Risk Index ◽  
Rubber Dam

To find out the heavy metal pollution condition from the Beng River sediment, we see the region from Beng River Rubber Dam to the Yimeng Road Bridge as research object.We monitored and surveyed on the three kinds of metal components (Cu, Zn, Cd) in the sediments from eight sectionsthe. With reference to the relevant domestic standards, we established sediment pollution evaluation criteria suitable for the region., We conducted the evaluation of ecological risk and pollution levels with the detection results by standard index of the potential ecological risk index and Nemerow France France. The results showed that: the heavy metals ecological risk index in Sediment from Beng River Rubber Dam to the Yimeng Road bridge section, Nemerow pollution index was 6.95, It was heavily polluted. This showed that the heavy metals in river sediment pollution was very serious.

scholarly journals The Assessment of Using the Sewage Sludge in Agriculture in Romania

2018 ◽  
Vol 55 (4) ◽  
pp. 700-703
Author(s):  
Carmelia Mariana Dragomir Balanica ◽  
Aurel Gabriel Simionescu ◽  
Iulian Gabriel Birsan ◽  
Cezar Ionut Bichescu ◽  
Cristian Muntenita
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Urban Area ◽  
Metal Toxicity ◽  
Wastewater Treatment Plants ◽  
Urban Wastewater ◽  
Usage Analysis ◽  
Urban Wastewater Treatment

Sewage sludge resulted from urban wastewater treatment plants is generally accepted as a valuable source of nutrient and soil conditioner for agricultural usage. Analysis of amount of heavy metals in sewage sludge is essential previous to utilization of the sludge to agriculture considering the inevitable risk of heavy metal toxicity to soil, vegetation and humans. The present paper aims to analyse the characteristics of the sewage sludge resulted in an urban area for 5 years. Sewage sludge generated from five wastewater treatment plants in the South and South Est part of Romania were analysed.

scholarly journals Potential Ecological Risks of Heavy Metals in Agricultural Soil Alongside Highways and Their Relationship with Landscape

Agriculture ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 800
Author(s):  
Cong Xu ◽  
Jie Pu ◽  
Bo Wen ◽  
Min Xia
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Ecological Risk ◽  
Human Activities ◽  
Agricultural Soil ◽  
Risk Index ◽  
Pollution Index ◽  
Potential Ecological Risk ◽  
Ecological Risks ◽  
Ecological Risk Index

The agricultural soil alongside highways has experienced multiple potential ecological risks from human activities. In this study, 100 soil samples near the highways were collected in Lishui District, Nanjing City. Using the single-factor pollution index, the Nemerow comprehensive pollution index, and the potential ecological risk index, the study investigated the heavy metal contents and distribution in roadside agricultural soil. PCA and a multiple regression model were applied to quantitatively analyze the spatial relationships between sampling soil heavy metal accumulation and the surrounding man-made landscape. The mean contents of Cu and Pb exceeded the background, while Cd, Cr, and Zn were lower than that. The potential ecological risk index exhibited a very low ecological hazard and only Cr in soils rarely showed moderate risk. Furthermore, quantitative analysis for the sources of contamination revealed that agricultural practices were the dominant contributors to the heavy metals, including Cd, Cu, and Zn, while road and heavy industrial practices contributed to Cr and Pb. The study provides sources of heavy metal pollution from human activities in roadside agricultural land and serves as a reference for ecological restoration.

scholarly journals Assessment of Heavy Metal Pollution Levels in Sediments and of Ecological Risk by Quality Indices, Applying a Case Study: The Lower Danube River, Romania

Water ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 1801
Author(s):  
Valentina Andreea Calmuc ◽  
Madalina Calmuc ◽  
Maxim Arseni ◽  
Catalina Maria Topa ◽  
Mihaela Timofti ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Ecological Risk ◽  
Metal Pollution ◽  
Heavy Metal Pollution ◽  
Surface Sediments ◽  
Risk Index ◽  
Potential Ecological Risk ◽  
Danube River ◽  
Pollution Indices

It is a well–known fact that heavy metal pollution in sediments causes serious problems not only in the Danube basin, but also in the large and small adjacent river streams. A suitable method for assessing the level of heavy metals and their toxicity in sediments is the calculation of pollution indices. The present research aims to assess heavy metal pollution in the Lower Danube surface sediments collected along the Danube course (between 180 and 60 km) up to the point where the Danube River flows into the Danube Delta Biosphere Reserve (a United Nations Educational, Scientific and Cultural Organization – UNESCO, protected area). In addition, this monitored area is one of the largest European hydrographic basins. Five heavy metals (Cd, Ni, Zn, Pb, Cu) were analyzed in two different seasons, i.e., the autumn of 2018 and the spring of 2019, using the Inductively Coupled Plasma Mass Spectrometry (ICP– MS) technique. Our assessment of heavy metal pollution revealed two correlated aspects: 1. a determination of the potential risks of heavy metals in sediments by calculating the Potential Ecological Risk Index (RI), and 2. an evaluation of the influence of anthropogenic activities on the level of heavy metal contamination in the surface sediments, using three specific pollution indices, namely, the Geo–Accumulation Index (Igeo), the Contamination Factor (CF), and the Pollution Load Index (PLI). The results of this pioneering research activity in the region highlighted the presence of moderate metal (Ni and Cd) pollution and a low potential ecological risk for the aquatic environment.

PCDD/F, PAH and heavy metals in the sewage sludge from six wastewater treatment plants in Beijing, China

Chemosphere ◽  
2007 ◽  
Vol 66 (2) ◽  
pp. 353-361 ◽  
Author(s):  
Jiayin Dai ◽  
Muqi Xu ◽  
Jiping Chen ◽  
Xiangping Yang ◽  
Zhenshan Ke
Keyword(s):  
Heavy Metals ◽  
Wastewater Treatment ◽  
Sewage Sludge ◽  
Wastewater Treatment Plants ◽  
Beijing China

scholarly journals Migration and transformation of heavy metals during the microwave-assisted thermal hydrolysis of sewage sludge

2021 ◽  
Author(s):  
Chunsheng Qiu ◽  
Jinxin Zheng ◽  
Chenchen Wang ◽  
Bingbing Wang ◽  
Nannan Liu ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Sewage Sludge ◽  
Ecological Risk ◽  
Risk Index ◽  
Oxygen Demand ◽  
Microwave Treatment ◽  
Potential Ecological Risk ◽  
Ammonium Nitrogen ◽  
Thermal Hydrolysis ◽  
Microwave Assisted

Abstract The migration, transformation and ecological risk of heavy metals (Cr, As, Ni, Cu, Zn, Cd and Pb) in the sewage sludge during the microwave-assisted thermal hydrolysis process were investigated under different temperatures (80 °C, 100 °C, 120 °C, 140 °C, and 160 °C). The potential relationship between the bio-availability of heavy metals and the variables of microwave treatment, including pH, ammonium-nitrogen, soluble chemical oxygen demand, pH, soluble protein, soluble polysaccharide and volatile solid, was also explored. The results showed that the migration of heavy metals between solid-liquid phase mainly depended on the temperature. The percentage of all heavy metals (except Cu) in mobile (acid-soluble/exchangeable and reducible) forms decreased after microwave-assisted thermal hydrolysis treatment. The solubilization of compounds with C = O and O-H accompanied with the generation of organic and inorganic metal halides were also observed in the treated sludge through fourier transform infrared spectroscopy analysis. NH4+-N showed the highest negative correlation to the bio-availability of most heavy metals (except Cu and Cr) with coefficients (absolute value) over 0.87 (P &lt; 0.05). VS showed a positive correlation to the bio-availability of most heavy metals (except Cu). The total potential ecological risk index (RI) decreased by 46.65% after microwave treatment at 160 °C.

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