scholarly journals Evaluation of Bio-Corrosion on Carbon Steel by Bacillus Megaterium in Biodiesel and Diesel Oil Mixture

Author(s):  
Yustina Metanoia Pusparizkita ◽  
Wolfgang Schmahl ◽  
Tjandra Setiadi ◽  
Bork Ilsemann ◽  
Mike Reich ◽  
...  
2021 ◽  
Vol 12 (4) ◽  
pp. 5698-5708

Microorganisms in biodiesel storage tanks may generate bio-corrosion due to their hygroscopic and susceptible fuel degradation. The organisms, including Bacillus megaterium present in the hydrocarbons, resulted from the EPS and metabolites processes that subsequently control the corrosion process of the tank. This present study examined the effect of biodiesel concentration on microbial activity through TPC analyzing growth for B. megaterium. Furthermore, this study investigated EPS formation and acid metabolites production by B. megaterium based on SEM observations and acidimetric titration. Meanwhile, this study investigated the microorganism-induced corrosion impact based on gravimetric analysis. The results explained a higher biodiesel concentration in diesel oil promoted an increase in the growth of B. megaterium and the corrosion rate. Conversely, the acid metabolites produced from bacteria under the biofilm did not significantly increase the corrosion rate. Corrosion products resulting from the B. megaterium activity on the surface of the steel included Iron (II, III) oxide (Fe2O3 and Fe3O4). The formation of oxide and pitting may control the strength of the surface tank in the course of biofuel storage, which may lead to the failure of the material.


2018 ◽  
Vol 156 ◽  
pp. 01008 ◽  
Author(s):  
Yustina M Pusparizkita ◽  
Tjandra Setiadi ◽  
Ardiyan Harimawan

Biodiesel come into being used as an alternative source of energy as the diminishing of petroleum reserves. This fuel is typically stored in tanks that are commonly made from carbon steel, which is easily corroded by microorganisms. Recent studies have shown that bacteria aside from SRB may also be involved in corrosion. Therefore, this research was aimed to evaluate the effect of biodiesel concentration (15%, 20% and 30% v/v) mixed in diesel oil on the corrosion of carbon steel by S. marcescens that dominate biocorrosion on hydrocarbon products. In this study, the corrosion process was investigated by evaluation of biofilm morphology and composition, the rate of corrosion and the corrosion product of carbon steel which was exposed in the mixture of hydrocarbons and the presence of S. marcescens. It can be concluded that higher concentration of biodiesel in diesel oil leads to higher growth of bacteria in the biofilm and higher corrosion rate.


2018 ◽  
Vol 7 (4) ◽  
pp. 2009
Author(s):  
Aida Nur Ramadhani ◽  
Ardiyan Harimawan ◽  
Hary Devianto

This study focused in the effect of water content on biofilm and bio-corrosion, and knowing its influence on biodiesel-diesel blends’ quality. Biodiesel is hygroscopic and less stable, makes this fuel needs more attention in storing. Fuel is usually stored in a storage tank of carbon steel which easily corroded by microorganisms, such as Bacillus megaterium. Corrosion occurs because microorganisms use fuel as nutrients and water content in hygroscopic biodiesel supports to grow and metabolize. Experiments were carried out by immersing carbon steel in medium 30% biodiesel (B30) for 21 days with water content variation of 0%, 5%, and 10% volume. The number of colonies in biofilms increased up to 1,3 times in a 10% water content. A uniform biofilm provides an inhibitory effect on corrosion per time, also layer of iron phosphate formed on water content variation, so the highest 0.642 ± 0.28 mm/year on 0% water content. Fe2O3, Fe3O4, and FeOOH are the corrosion product by Bacillus megaterium. The highest biodegradation efficiency achieved by variation water content both 5% and 10% were 68.5% and 67.23%, and then followed by no water content at 60.40%.  


Author(s):  
Aida Nur Ramadhani ◽  
Ardiyan Harimawan ◽  
Hary Devianto

Biodiesel is potential to blend with petroleum diesel as an alternative blended fuel. Biodiesel is usually stored in carbon steel storage tank which easily corroded by microorganisms. Microorganisms can use blended fuels as carbon source and water from biodiesel which is hygroscopic for growth and metabolism. Thus, degradation of fuel may occur and lead to biocorrosion by microorganisms such as Bacillus megaterium. This research was conducted to determine the effect of biodiesel concentration of blended fuel on biofilm formation and biocorrosion by Bacillus megaterium. The experiments were carried out by immersing carbon steel specimens in immersion medium for 21 days with variation of biodiesel concentration (B0, B20, B30, and B100). Biofilms that form on the metal surface cause areas with non-uniform oxygen concentrations and form anodic/cathodic conditions, raised to potential differences and biocorrosion occurred. The average corrosion rates were 0,035 ± 0,03; 0,533 ± 0,33; 0,642 ± 0,28; 0,109 ± 0,04 mm/year achieved by B0, B20, B30 and B100 respectively. These rates increased when compared to the control medium. Microorganism activity also caused damage to the metal surface by forming pitting corrosion on B30 and B100.


Author(s):  
Y. L. Chen ◽  
J. R. Bradley

Considerable effort has been directed toward an improved understanding of the production of the strong and stiff ∼ 1-20 μm diameter pyrolytic carbon fibers of the type reported by Koyama and, more recently, by Tibbetts. These macroscopic fibers are produced when pyrolytic carbon filaments (∼ 0.1 μm or less in diameter) are thickened by deposition of carbon during thermal decomposition of hydrocarbon gases. Each such precursor filament normally lengthens in association with an attached catalyst particle. The subject of filamentous carbon formation and much of the work on characterization of the catalyst particles have been reviewed thoroughly by Baker and Harris. However, identification of the catalyst particles remains a problem of continuing interest. The purpose of this work was to characterize the microstructure of the pyrolytic carbon filaments and the catalyst particles formed inside stainless steel and plain carbon steel tubes. For the present study, natural gas (∼; 97 % methane) was passed through type 304 stainless steel and SAE 1020 plain carbon steel tubes at 1240°K.


2001 ◽  
Vol 81 (12) ◽  
pp. 2797-2808
Author(s):  
Rustem Bagramov, Daniele Mari, Willy Benoi

1993 ◽  
Vol 90 (7-8) ◽  
pp. 917-922
Author(s):  
Y. Matsuda ◽  
M. Nishino ◽  
J. Ikeda

2018 ◽  
Vol 18 (1) ◽  
pp. 125-135
Author(s):  
Sattar H A Alfatlawi

One of ways to improve properties of materials without changing the product shape toobtain the desired engineering applications is heating and cooling under effect of controlledsequence of heat treatment. The main aim of this study was to investigate the effect ofheating and cooling on the surface roughness, microstructure and some selected propertiessuch as the hardness and impact strength of Medium Carbon Steel which treated at differenttypes of heat treatment processes. Heat treatment achieved in this work was respectively,heating, quenching and tempering. The specimens were heated to 850°C and left for 45minutes inside the furnace as a holding time at that temperature, then quenching process wasperformed in four types of quenching media (still air, cold water (2°C), oil and polymersolution), respectively. Thereafter, the samples were tempered at 200°C, 400°C, and 600°Cwith one hour as a soaking time for each temperature, then were all cooled by still air. Whenthe heat treatment process was completed, the surface roughness, hardness, impact strengthand microstructure tests were performed. The results showed a change and clearimprovement of surface roughness, mechanical properties and microstructure afterquenching was achieved, as well as the change that took place due to the increasingtoughness and ductility by reducing of brittleness of samples.


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