scholarly journals Conversion of Cellulose into Value-Added Products

2021 ◽  
Author(s):  
Lethiwe D. Mthembu ◽  
Rishi Gupta ◽  
Nirmala Deenadayalu

Rapid industrialization has led to development of various platform chemicals and fossil fuel refinery is one of the mainstreams for their production. However continuous depletion of fossil fuels reserves has led an urge to look for alternate source of feedstocks. Among various renewable sources, biomass is found to be most sustainable as it is replaced naturally. Biomass by virtue of its nature is comprised of various recalcitrant polymers and cellulose is one of them, which can be used for the generation of various platform chemicals. This chapter gives a background of cellulose and illustrate platform chemicals that can be produced from cellulose.

2021 ◽  
Vol 55 (3-4) ◽  
pp. 207-222
Author(s):  
RAMANDEEP KAUR ◽  
PUNEET KAUR

"The potential of non-edible lignocellulosic biomass paves the path to sustainable economy. A large number of valueadded products have been synthesized by the fractionation of the major components of biomass, i.e. cellulose, hemicelluloses and lignin. Cellulose, the most abundant biopolymer on earth, serves as a starting material for the synthesis of various platform chemicals, such as sorbitol, 5- hydroxylmethylfurfural (HMF), dimethylfuran and levulinic acid. Hydrogels and aerogels fabricated from cellulose, modified cellulose or nanocellulose have proved valuable in a wide range of such as biomedical, food and technological applications. Cellulose-based polymers or bioplastics also emerged as an alternative to fossil fuel-based polymers. In this review, chemical paths to valorize plant cellulose for producing various value-added products have been discussed. The major challenge for valorization is the development of novel and green synthesis methods with simultaneous focus on an integrated approach."


2021 ◽  
Vol 2 (3) ◽  
pp. 467-492
Author(s):  
Marta. E. G. Mosquera ◽  
Gerardo Jiménez ◽  
Vanessa Tabernero ◽  
Joan Vinueza-Vaca ◽  
Carlos García-Estrada ◽  
...  

Polymers are essential materials in our daily life. The synthesis of value-added polymers is mainly performed from fossil fuel-derived monomers. However, the adoption of the circular economy model based on the bioeconomy will reduce the dependence on fossil fuels. In this context, biorefineries have emerged to convert biomass into bioenergy and produce high value-added products, including molecules that can be further used as building blocks for the synthesis of biopolymers and bioplastics. The achievement of catalytic systems able to polymerize the natural monomer counterparts, such as terpenes or terpenoids, is still a challenge in the development of polymers with good mechanical, thermal, and chemical properties. This review describes the most common types of bioplastics and biopolymers and focuses specifically on the polymerization of terpenes and terpenoids, which represent a source of promising monomers to create bio-based polymers and copolymers.


Author(s):  
Ali Raza Ishaq ◽  
Faiza Jabeen ◽  
Maleeha Manzoor ◽  
Tahira Younis ◽  
Ayesha Noor ◽  
...  

Modern day civilization is dependent on energy generation by fossil fuels. But the major drawback of using fossil fuels is environmental pollution. Microalgae are potential candidate for production of various products of interest, such as proteins, mini food, pigments and triglycerides that can be converted into biofuels. Lignocellulosic feedstocks are the most abundantly available raw material of plants that can serve as a promising feedstock for cultivating bacteria, fungi, yeasts and microalgae to produce biofuels and other value-added products. Owing to the abundant availability of these low/no cost substrates, can be utilized as feedstocks for cultivating microalgae to generate biogas/biodiesel. Likewise, there is much room to exploit defatted algal biomass to be used as animal/fish feed and oil producing/accumulating genes knowledge in future to produce high and good quality biodiesel and biogas.


2016 ◽  
Vol 2 (1) ◽  
pp. 79 ◽  
Author(s):  
Bruna Steil Boneberg ◽  
Grazielle Dias Machado ◽  
Davi Friedrich Santos ◽  
Fernando Gomes ◽  
Douglas José Faria ◽  
...  

Lignocellulosic biomass has been widely investigated as a natural renewable source of feedstocks to produce high value added products which can replace energy and materials obtained from non-renewable sources. Polymers are products largely employed in industry in many different applications, which nowadays are mostly produced from petrochemical derivatives, generating huge amounts of waste of difficult treatment prior to disposal. In order to replace these polymers derived from petroleum, efforts have been made in the development of biopolymers, in the biorefinery context, derived from biomass possessing physicochemical properties similar to those derived from petroleum so that they can successfully replace these materials. A review on the different types of biopolymers obtained from biomass, as polysaccharides, lipids, proteins, polyesters produced by plants and microorganisms, and other assorted biopolymers is accomplished. An evaluation of physicochemical properties and applications of different types of biopolymers is approached. It is also discussed about the degradability of biopolymers differentiating oxo-degradability and biodegradability. A brief historic background about biopolymers is also exposed.


Author(s):  
Chelsea Schelly

The electricity grid in the United States may be the largest, most pervasive technological system ever constructed to meet the needs and comforts of human beings (Nye 1997). Although it is less than 150 years old, the electricity infrastructure of this nation is ubiquitous; power lines stretch across deserts, forests, states, highways, and the entire nation in order to provide electricity to residences, businesses, and communities. The electricity carried by these transmission lines is generally produced using fossil fuels (mostly coal; see US Energy Information Administration 2012) and is most commonly generated at a monstrously large facility (a coal plant, a nuclear facility, or a hydropower dam). Our electricity infrastructure was constructed to carry enormous amounts of electricity across vast geographical expanses, based on the massive generation facilities and concentrated fossil fuel based energy sources that defined the system and its use. However, there are increasing concerns regarding the sources of our energy supply. Many of these concerns are related to climate change and how carbon dioxide emissions from burning fossil fuels contribute to rising global temperatures and the climate instability of the planet (Brown 2003). Additional concerns include the host of other environmental damages caused by the use of coal (Epstein et al. 2011), nuclear energy (Slovic et al. 1991), and hydro-electricity (Dincer 1998); other debates involve worries about nearing or reaching peak energy supplies (Brown 2003), energy security (Yergin 2006), and the aging transmission grid (Amin 2003). For a multitude of reasons, many would agree that it’s time to rethink our dependence on fossil fuel based forms of energy and move toward alternative, renewable energy sources (Brown 2003, pp. 116–135). The good news is, the renewable energy industry gets bigger every year, with more energy from renewable sources being produced, sold, and used (Sherwood 2011). Some US states have enacted renewable energy standards requiring that a certain percentage of their electricity supply come from renewable sources. Tax incentives, subsidies, and various forms of rebates, in financially incentivizing renewable energy adoption, also provide evidence that we are indeed moving in the direction of clean, renewable sources of energy.


2015 ◽  
Vol 2015 ◽  
pp. 1-18 ◽  
Author(s):  
Colin Awungacha Lekelefac ◽  
Nadine Busse ◽  
Michael Herrenbauer ◽  
Peter Czermak

Photocatalysis, belonging to the advanced oxidation processes (AOPs), is a potential new transformation technology for lignin derivatives to value added products (e.g., phenol, benzene, toluene, and xylene). Moreover, lignin represents the only viable source to produce aromatic compounds as fossil fuel alternative. This review covers recent advancement made in the photochemical transformation of industrial lignins. It starts with the photochemical reaction principle followed by results obtained by varying process parameters. In this context, influences of photocatalysts, metal ions, additives, lignin concentration, and illumination intensity and the influence of pH are presented and discussed. Furthermore, an overview is given on several used process analytical methods describing the results obtained from the degradation of lignin derivatives. Finally, a promising concept by coupling photocatalysis with a consecutive biocatalytic process was briefly reviewed.


2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Omotola Babajide

The production of biofuels worldwide has been significant lately due to the shift from obtaining energy from nonrenewable energy (fossil fuels) to renewable sources (biofuels). This energy shift arose as a result of the disturbing crude petroleum price fluctuations, uncertainties about fossil fuel reserves, and greenhouse gas (GHG) concerns. With the production of biofuels increasing considerably and the current global biodiesel production from different feedstock, reaching about 6 billion liters per year, biodiesel production costs have been highly dependent on feedstock prices, ranging from 70 to 25; of total production costs, and in comparison with the conventional diesel fuel, the biodiesel is currently noncompetitive. An efficient production process is, therefore, crucial to lowering biodiesel production costs. The question of sustainability, however, arises, taking into account the African diverse conditions and how vital concerns need to be addressed. The major concern about biodiesel production costs can be reduced by finding value-added applications for its glycerol byproduct. This paper, thus, provides an overview of current research trends that could overcome the major hurdles towards profitable commercialization of biodiesel and also proposes areas of opportunity probable to capitalize the surplus glycerol obtained, for numerous applications.


ChemSusChem ◽  
2017 ◽  
Vol 11 (1) ◽  
pp. 25-47 ◽  
Author(s):  
Carolina G. S. Lima ◽  
Julia L. Monteiro ◽  
Thiago de Melo Lima ◽  
Marcio Weber Paixão ◽  
Arlene G. Corrêa

2017 ◽  
Vol 12 (1) ◽  
pp. 43-48
Author(s):  
Andrew Johnson

Environmentalists continuously push for us, as a country, to decrease our fossil fuel usage and transition to a society powered by renewable energy. The money of oil companies and other corporations persuade our government to continue investing in fossil fuels as opposed to renewable energy. There are, however, other reasons which should convince us as a nation to invest in alternative energy sources. Eliminating our dependence on fossil fuels will benefit the nation economically and prepare us for a rapidly changing future. We, as Americans, should increasingly pursue renewable sources of alternative energy not only for the documented environmental reasons but also because investing in renewable energy technologies will provide jobs for Americans, decrease our dependence on other nations, and benefit the health of all Americans while decreasing our dependence on fossil fuels.


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