scholarly journals Removal of COD in wastewaters by activated charcoal from rice husk

2017 ◽  
Vol 29 (3) ◽  
pp. 265-277 ◽  
Author(s):  
Yacouba Sanou ◽  
Samuel Pare ◽  
Gnon Baba ◽  
Nyonuwosro Kwamivi Segbeaya ◽  
Libona Yvonne Bonzi-Coulibaly

The discharge of industrial wastewater and domestic sewage from Kara city affects the quality of Kara river water. To mitigate this water pollution, the capacity of mesoporous charcoal prepared from rice husk (RH) to remove the chemical oxygen demand (COD) in wastewater samples from five sites of Kara City was investigated. The temperature, pH, conductivity, total suspended solids (TSS), biochemical oxygen demand (BOD5), chemical oxygen demand (COD) and oxidizable matters (OM) of samples were analyzed. Batch experiments were applied to study the COD reduction by using powdered RH and two types of activated charcoals (AC). The experimental parameters used to identify optimal conditions for COD abatement are solution pH, contact time, mass of adsorbent and initial value of COD including the nature of wastewater. Activated charcoals showed a higher attenuation capacity of the COD in comparison with the rice husk powder. Maximal abatement rate (100%) of COD removal was obtained for the wastewater sample with a COD of 1 060 mg O2∙L-1 treated at pH 8 with the charcoal GAC-Base using an adsorbent concentration of 10 g∙L-1 with a contact time of 60 min.

Author(s):  
Mahmood Al Ramahi ◽  
Sándor Beszédes ◽  
Gábor Keszthelyi-Szabó

AbstractIndustrial wastewater is a growing environmental challenge due to its high concentrations of organics and its limited biological degradability. Up to date, however, no published work discussed industrial wastewater characterization, which is the focus of this study. Moreover, the effect of hydrothermal treatment on the chemical oxygen demand (COD) removal and the soluble chemical oxygen demand (SCOD) release was investigated in this work. Wastewater samples were collected from different industrial sites and characterized in order to determine their initial properties. It was summarized that the salinity of wastewater estimated by EC was relatively low, and its pH values were in the acceptable range. On the other hand, however, high values of sodium absorption ratio (SAR) were obtained in all samples post to hydrothermal treatment. Nonetheless, our results revealed higher SCOD release post to hydrothermal treatment suggesting better efficiency of COD removal obtained by this treatment technique.


2014 ◽  
Vol 13 (1) ◽  
pp. 43-50 ◽  
Author(s):  
Ghasem Najafpour Darzi ◽  
Reza Katal ◽  
Hossein Zare ◽  
Seyed Omid Rastegar ◽  
Poorya Mavaddat

2010 ◽  
Vol 2010 ◽  
pp. 1-6 ◽  
Author(s):  
Patricia A. Terry

A pilot study was performed at the Fox River Fiber recovered paper processing company in DePere, Wisconsin, to determine the extent to which injection of oxygen and ozone could reduce the high chemical oxygen demand, COD, in the effluent and the effectiveness of the ozone/oxygen stream in suppressing production of hydrogen sulfide gas in downstream sewage lines. Adaptive Ozone Solutions, LLC, supplied the oxygen/ozone generation and injection system. Samples were analyzed both before and after oxygen/ozone injection. Hydrogen sulfide gas was continuously monitored at sewer stations downstream of Fox River Fiber. Results showed that with a very short contact time, effluent COD was reduced by over 15%. A simple kinetic model predicts that a contact time of fewer than 30 minutes could reduce COD by as much as 60%. In addition, downstream hydrogen sulfide gas production in the sewage mains was also better controlled, such that costly Bioxide applications could be reduced.


2010 ◽  
Vol 62 (11) ◽  
pp. 2669-2677 ◽  
Author(s):  
Lizhang Wang ◽  
Yuemin Zhao

Experiments were performed to reduce chemical oxygen demand (COD) from 4,4′-diaminostilbene-2,2′-disulfonic (DSD) acid manufacturing wastewater using electrochemical oxidation coupled with adsorption by granular activated carbon. The COD removal is affected by the residence time and applied voltage. When the residence time is increased, lower value of COD effluent could be obtained, however, the average current efficiency (ACE) decreased rapidly, and so does the applied voltage. In addition, aeration could effectively enhance COD removal efficiency and protect anodes from corrosion. Furthermore, the acidic condition is beneficial to the rapid decrease of COD and the values of pH effluent are independent of the initial solution pH. The optimization conditions obtained from these experiments are applied voltage of 4.8 V, residence time of 180 min and air–liquid ratio of 4.2 with the COD effluent of about 690 mg L−1. In these cases, the ACE and energy consumption are 388% and 4.144 kW h kg−1 COD, respectively. These perfect results from the experiments illustrate that the combined process is a considerable alternative for the treatment of industrial wastewater containing high concentration of organic pollutants and salinity.


Author(s):  
Bisekwa E ◽  
Njogu PM ◽  
Kufa-Obso T

Arabica coffee is cultivated by smallholders for commercial purposes, and it is commonly processed using wet Coffee Processing Technology. Burundi has more than 250 Coffee Processing factories which discharge their effluents to water bodies. The goal of this study was to determine the levels of physicochemical parameters in wastewater from Coffee Processing Technology factories in major coffee growing ecological zones in Burundi. Wastewater samples were collected from 19 sites representing private, public and cooperative owned coffee processing stations. Physicochemical analyses were determined in-situ field and laboratory conditions using standard procedures. Results indicate that the wastewater does not meet Burundi Effluent Discharge standards for Total Suspended solids, Chemical Oxygen Demand, Biochemical Oxygen Demand, pH. The data revealed that the wet coffee processing pollutes the environment in terms of pH, Total Suspended solids, Chemical Oxygen Demand, Biochemical Oxygen Demand. There is need to install quality polishing technologies to treat the water before disposal.


2017 ◽  
Vol 9 (2) ◽  
pp. 21-25
Author(s):  
N Sultana ◽  
H Muktadir ◽  
MAH Chowdhury ◽  
MA Baten

This study was conducted to assess the quality of different industrial wastewater. Some physicochemical parameters viz., pH, EC, TDS, Na+, K+, Ca++, Mg++, CO32-, HCO3-, Cl-, SO42-, PO43- including heavy metal contents like Pb, Cd, Ni, Cr, As, Zn and Cu concentration from collected wastewater samples were analyzed. Atomic Absorption Spectrophotometer was used for analyzing the heavy metals in the wastewater samples. The results revealed that, the values of pH, EC, TDS ranged between 6.44-9.0, 471-4307 ?S cm-1, 1952-5209 mg L-1, respectively. The higher mean concentrations of Na+, K+, Ca++, Mg++, CO3-, HCO3-, Cl-, SO42-, PO43- were 1407.8, 27.9, 69.9, 76.6, 2.7, 11.7, 1688, 76.6, 6.1 mg L-1, respectively. The mean concentration of Cd, Ni, Cr, Zn, and Cu was 0.17, 0.87, 85.73, 0.80, and 1.56 mg L-1, respectively. Among trace elements Ni and Cd, Zn and Cd, Zn and Cr showed a positive relationship. To avoid the harmful effects of wastewater on environment it is imperative to treat industrial effluents before discharge into open environment.J. Environ. Sci. & Natural Resources, 9(2): 21-25 2016


2017 ◽  
Vol 8 (1) ◽  
pp. 86-93
Author(s):  
Mang Lu ◽  
Lin He ◽  
Yue Cheng

Abstract In this study, ZSM-5 zeolite was synthesized using diatomaceous mud as the raw material, and then doped with different amounts of Nd2O3. The orthogonal experiments were performed to investigate the influence of Nd:Si molar ratio, zeolite dosage, contact time, solution pH and temperature on the removal of humic acid (HA). The removal of HA was comprehensively evaluated by chemical oxygen demand (COD), UV254 and UV410 of the solution. The results demonstrate that solution pH and zeolite dosage are the two most important factors influencing HA adsorption. The optimum experimental conditions were determined to be: 35 °C, Nd:Si molar ratio of 1:100, 2.0 g/L zeolite, pH 4 and 50 min contact time. Under these conditions, the removal efficiencies of UV254, UV410 and COD are 82.70%, 76.00% and 82.10%, respectively, corresponding to a comprehensive removal of 81.02%.


1994 ◽  
Vol 30 (10) ◽  
pp. 179-187 ◽  
Author(s):  
I. T. Miettinen ◽  
P. J. Martikainen ◽  
T. Vartiainen

Transformations in the amount and quality of organic matter (humus) during bank filtration of surface water were studied by analyzing the changes in total organic carbon (TOC), non-purgeable organic carbon (NPOC), chemical oxygen demand (COD), color of water, and UV absorbing humus fractions. The amount of organic matter expressed as TOC, NPOC, and COD depended on temperature and filtration distance from lake water. The color of water and the UV absorbing humus peaks presenting different humus molecule fractions decreased more effectively than other parameters measuring the amount of organic matter in water. The ratio of COD to TOC decreased when the filtration distance of water increased. Our observations indicated that bank filtration of humus-rich lake water changed more the quality of organic matter than its total amount.


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