scholarly journals Calculation methods of non-stationary temperature fields influence on foundation in cryolithozone

Author(s):  
Nikolay Ivanovich Sidnyaev ◽  
Vasilii Ivanovich Vasiliev ◽  
Yuliya Sergeevna Ilina

  This article is devoted to the mathematical modeling and computing experiment in problems of temperature fields forecast in continuous foundations in cryolithozone, which will provide a qualitative approach to non-stationary thermal calculations for making design decisions to ensure the stability and reliability of bases and foundations of buildings in the Arctic zone.  The article formulates the problem of forecasting by determining changes in the temperature, areal distribution, thickness, and vertical structure of permafrost, seasonal and perennial freezing of the soil, their temperature strength state, and properties in connection with the construction of buildings. Presented mathematical calculations are based mainly on the assumption of a non-stationary process of heat exchange. Mathematical models for determining depth of thawing are considered. The problem of determining the temperature in the basement of the foundation, limited on the one side, in which the temperature depends on only one coordinate with the condition that the surface temperature of the permafrost soil undergoes periodic fluctuations around zero value under the influence of external influences, has been solved. It is demonstrated that the two-dimensional problem of permafrost ground with a semi-infinite foundation thickness can be generalized even more. The problem is formulated in the form of a differential equation of heat balance taking into account the heat flux, which varies according to the Fourier’s law.  

2009 ◽  
Vol 22 (6) ◽  
pp. 1566-1585 ◽  
Author(s):  
N. J. Matthewman ◽  
J. G. Esler ◽  
A. J. Charlton-Perez ◽  
L. M. Polvani

Abstract The evolution of the Arctic polar vortex during observed major midwinter stratospheric sudden warmings (SSWs) is investigated for the period 1957–2002, using 40-yr European Centre for Medium-Range Weather Forecasts (ECMWF) Re-Analysis (ERA-40) Ertel’s potential vorticity (PV) and temperature fields. Time-lag composites of vertically weighted PV, calculated relative to the SSW onset time, are derived for both vortex-displacement SSWs and vortex-splitting SSWs, by averaging over the 15 recorded displacement and 13 splitting events. The evolving vertical structure of the polar vortex during a typical SSW of each type is clearly illustrated by plotting an isosurface of the composite PV field, and is shown to be very close to that observed during representative individual events. Results are verified by comparison with an elliptical diagnostic vortex moment technique. For both types of SSW, little variation is found between individual events in the orientation of the developing vortex relative to the underlying topography; that is, the location of the vortex during SSWs of each type is largely fixed in relation to the earth’s surface. During each type of SSW, the vortex is found to have a distinctive vertical structure. Vortex-splitting events are typically barotropic, with the vortex split occurring near simultaneously over a large altitude range (20–40 km). In the majority of cases, of the two daughter vortices formed, it is the “Siberian” vortex that dominates over its “Canadian” counterpart. In contrast, displacement events are characterized by a very clear baroclinic structure; the vortex tilts significantly westward with height, so that the top and bottom of the vortex are separated by nearly 180° longitude before the upper vortex is sheared away and destroyed.


1975 ◽  
Vol 34 (02) ◽  
pp. 426-444 ◽  
Author(s):  
J Kahan ◽  
I Nohén

SummaryIn 4 collaborative trials, involving a varying number of hospital laboratories in the Stockholm area, the coagulation activity of different test materials was estimated with the one-stage prothrombin tests routinely used in the laboratories, viz. Normotest, Simplastin-A and Thrombotest. The test materials included different batches of a lyophilized reference plasma, deep-frozen specimens of diluted and undiluted normal plasmas, and fresh and deep-frozen specimens from patients on long-term oral anticoagulant therapy.Although a close relationship was found between different methods, Simplastin-A gave consistently lower values than Normotest, the difference being proportional to the estimated activity. The discrepancy was of about the same magnitude on all the test materials, and was probably due to a divergence between the manufacturers’ procedures used to set “normal percentage activity”, as well as to a varying ratio of measured activity to plasma concentration. The extent of discrepancy may vary with the batch-to-batch variation of thromboplastin reagents.The close agreement between results obtained on different test materials suggests that the investigated reference plasma could be used to calibrate the examined thromboplastin reagents, and to compare the degree of hypocoagulability estimated by the examined PIVKA-insensitive thromboplastin reagents.The assigned coagulation activity of different batches of the reference plasma agreed closely with experimentally obtained values. The stability of supplied batches was satisfactory as judged from the reproducibility of repeated measurements. The variability of test procedures was approximately the same on different test materials.


2019 ◽  
Author(s):  
Jose Julio Gutierrez Moreno ◽  
Marco Fronzi ◽  
Pierre Lovera ◽  
alan O'Riordan ◽  
Mike J Ford ◽  
...  

<p></p><p>Interfacial metal-oxide systems with ultrathin oxide layers are of high interest for their use in catalysis. In this study, we present a density functional theory (DFT) investigation of the structure of ultrathin rutile layers (one and two TiO<sub>2</sub> layers) supported on TiN and the stability of water on these interfacial structures. The rutile layers are stabilized on the TiN surface through the formation of interfacial Ti–O bonds. Charge transfer from the TiN substrate leads to the formation of reduced Ti<sup>3+</sup> cations in TiO<sub>2.</sub> The structure of the one-layer oxide slab is strongly distorted at the interface, while the thicker TiO<sub>2</sub> layer preserves the rutile structure. The energy cost for the formation of a single O vacancy in the one-layer oxide slab is only 0.5 eV with respect to the ideal interface. For the two-layer oxide slab, the introduction of several vacancies in an already non-stoichiometric system becomes progressively more favourable, which indicates the stability of the highly non-stoichiometric interfaces. Isolated water molecules dissociate when adsorbed at the TiO<sub>2</sub> layers. At higher coverages the preference is for molecular water adsorption. Our ab initio thermodynamics calculations show the fully water covered stoichiometric models as the most stable structure at typical ambient conditions. Interfacial models with multiple vacancies are most stable at low (reducing) oxygen chemical potential values. A water monolayer adsorbs dissociatively on the highly distorted 2-layer TiO<sub>1.75</sub>-TiN interface, where the Ti<sup>3+</sup> states lying above the top of the valence band contribute to a significant reduction of the energy gap compared to the stoichiometric TiO<sub>2</sub>-TiN model. Our results provide a guide for the design of novel interfacial systems containing ultrathin TiO<sub>2</sub> with potential application as photocatalytic water splitting devices.</p><p></p>


2021 ◽  
Vol 83 (3) ◽  
Author(s):  
Ginger Egberts ◽  
Fred Vermolen ◽  
Paul van Zuijlen

AbstractTo deal with permanent deformations and residual stresses, we consider a morphoelastic model for the scar formation as the result of wound healing after a skin trauma. Next to the mechanical components such as strain and displacements, the model accounts for biological constituents such as the concentration of signaling molecules, the cellular densities of fibroblasts and myofibroblasts, and the density of collagen. Here we present stability constraints for the one-dimensional counterpart of this morphoelastic model, for both the continuous and (semi-) discrete problem. We show that the truncation error between these eigenvalues associated with the continuous and semi-discrete problem is of order $${{\mathcal {O}}}(h^2)$$ O ( h 2 ) . Next we perform numerical validation to these constraints and provide a biological interpretation of the (in)stability. For the mechanical part of the model, the results show the components reach equilibria in a (non) monotonic way, depending on the value of the viscosity. The results show that the parameters of the chemical part of the model need to meet the stability constraint, depending on the decay rate of the signaling molecules, to avoid unrealistic results.


2021 ◽  
Vol 22 (4) ◽  
pp. 2030
Author(s):  
Hela Ferjani ◽  
Hammouda Chebbi ◽  
Mohammed Fettouhi

The new organic–inorganic compound (C6H9N2)2BiCl5 (I) has been grown by the solvent evaporation method. The one-dimensional (1D) structure of the allylimidazolium chlorobismuthate (I) has been determined by single crystal X-ray diffraction. It crystallizes in the centrosymmetric space group C2/c and consists of 1-allylimidazolium cations and (1D) chains of the anion BiCl52−, built up of corner-sharing [BiCl63−] octahedra which are interconnected by means of hydrogen bonding contacts N/C–H⋯Cl. The intermolecular interactions were quantified using Hirshfeld surface analysis and the enrichment ratio established that the most important role in the stability of the crystal structure was provided by hydrogen bonding and H···H interactions. The highest value of E was calculated for the contact N⋯C (6.87) followed by C⋯C (2.85) and Bi⋯Cl (2.43). These contacts were favored and made the main contribution to the crystal packing. The vibrational modes were identified and assigned by infrared and Raman spectroscopy. The optical band gap (Eg = 3.26 eV) was calculated from the diffuse reflectance spectrum and showed that we can consider the material as a semiconductor. The density functional theory (DFT) has been used to determine the calculated gap, which was about 3.73 eV, and to explain the electronic structure of the title compound, its optical properties, and the stability of the organic part by the calculation of HOMO and LUMO energy and the Fukui indices.


2012 ◽  
Vol 12 (4) ◽  
pp. 1785-1810 ◽  
Author(s):  
Y. Qian ◽  
C. N. Long ◽  
H. Wang ◽  
J. M. Comstock ◽  
S. A. McFarlane ◽  
...  

Abstract. Cloud Fraction (CF) is the dominant modulator of radiative fluxes. In this study, we evaluate CF simulated in the IPCC AR4 GCMs against ARM long-term ground-based measurements, with a focus on the vertical structure, total amount of cloud and its effect on cloud shortwave transmissivity. Comparisons are performed for three climate regimes as represented by the Department of Energy Atmospheric Radiation Measurement (ARM) sites: Southern Great Plains (SGP), Manus, Papua New Guinea and North Slope of Alaska (NSA). Our intercomparisons of three independent measurements of CF or sky-cover reveal that the relative differences are usually less than 10% (5%) for multi-year monthly (annual) mean values, while daily differences are quite significant. The total sky imager (TSI) produces smaller total cloud fraction (TCF) compared to a radar/lidar dataset for highly cloudy days (CF > 0.8), but produces a larger TCF value than the radar/lidar for less cloudy conditions (CF < 0.3). The compensating errors in lower and higher CF days result in small biases of TCF between the vertically pointing radar/lidar dataset and the hemispheric TSI measurements as multi-year data is averaged. The unique radar/lidar CF measurements enable us to evaluate seasonal variation of cloud vertical structures in the GCMs. Both inter-model deviation and model bias against observation are investigated in this study. Another unique aspect of this study is that we use simultaneous measurements of CF and surface radiative fluxes to diagnose potential discrepancies among the GCMs in representing other cloud optical properties than TCF. The results show that the model-observation and inter-model deviations have similar magnitudes for the TCF and the normalized cloud effect, and these deviations are larger than those in surface downward solar radiation and cloud transmissivity. This implies that other dimensions of cloud in addition to cloud amount, such as cloud optical thickness and/or cloud height, have a similar magnitude of disparity as TCF within the GCMs, and suggests that the better agreement among GCMs in solar radiative fluxes could be a result of compensating effects from errors in cloud vertical structure, overlap assumption, cloud optical depth and/or cloud fraction. The internal variability of CF simulated in ensemble runs with the same model is minimal. Similar deviation patterns between inter-model and model-measurement comparisons suggest that the climate models tend to generate larger biases against observations for those variables with larger inter-model deviation. The GCM performance in simulating the probability distribution, transmissivity and vertical profiles of cloud are comprehensively evaluated over the three ARM sites. The GCMs perform better at SGP than at the other two sites in simulating the seasonal variation and probability distribution of TCF. However, the models remarkably underpredict the TCF at SGP and cloud transmissivity is less susceptible to the change of TCF than observed. In the tropics, most of the GCMs tend to underpredict CF and fail to capture the seasonal variation of CF at middle and low levels. The high-level CF is much larger in the GCMs than the observations and the inter-model variability of CF also reaches a maximum at high levels in the tropics, indicating discrepancies in the representation of ice cloud associated with convection in the models. While the GCMs generally capture the maximum CF in the boundary layer and vertical variability, the inter-model deviation is largest near the surface over the Arctic.


2003 ◽  
Vol 14 (08) ◽  
pp. 1087-1105 ◽  
Author(s):  
ZHONGCHENG WANG ◽  
YONGMING DAI

A new twelfth-order four-step formula containing fourth derivatives for the numerical integration of the one-dimensional Schrödinger equation has been developed. It was found that by adding multi-derivative terms, the stability of a linear multi-step method can be improved and the interval of periodicity of this new method is larger than that of the Numerov's method. The numerical test shows that the new method is superior to the previous lower orders in both accuracy and efficiency and it is specially applied to the problem when an increasing accuracy is requested.


2011 ◽  
Vol 66 (3) ◽  
pp. 269-274
Author(s):  
Samir F. Matar

We address the changes in the electronic structure brought by the insertion of hydrogen into ThCo leading to the experimentally observed ThCoH4. Full geometry optimization positions the hydrogen in three sites stabilized in the expanded intermetallic matrix. From a Bader charge analysis, hydrogen is found to be in a narrow iono-covalent (~−0.6) to covalent (~−0.3) bonding which should enable site-selective desorption. The overall chemical picture shows a positively charged Thδ+ with the negative charge redistributed over a complex anion {CoH4}δ− with δ~1.8. Nevertheless this charge transfer remains far from the one in the more ionic hydridocobaltate anion CoH54− in Mg2CoH5, due to the largely electropositive character of Mg.


2021 ◽  
Vol 2 (11) ◽  
pp. 39-47
Author(s):  
Valentina P. Toichkina ◽  

The article examines the external (exogenous) and internal (endogenous) sources of self-development of external migration, which is the most important resource for the formation of the size and demographic structure of the population of the Arctic regions. It is proposed to consider migration flows from the standpoint of their definition as sources (external and internal) of self-development. The coefficients of the intensity of migration flows are proposed to assess the sources of self-development. The analysis of the sources of self-development of external migration and the analysis of sustainable self-development of external migration for two four-year periods are carried out. The trends of changes in the migration situation have been determined. The conditions for the influence of sources of self-development on changes in the stability of external migration are determined, the method of determining which is a mechanism for analyzing and predicting migration processes.


Author(s):  
Dianshi Feng ◽  
Sze Dai Pang ◽  
Jin Zhang

The increasing marine activities in the Arctic has resulted in a growing demand for reliable structural designs in this region. Ice loads are a major concern to the designer of a marine structure in the arctic, and are often the principal factor that governs the structural design [Palmer and Croasdale, 2013]. With the rapid advancement in computational power, numerical method is becoming a useful tool for design of offshore structures subjected to ice actions. Cohesive element method (CEM), a method which has been widely utilized to simulate fracture in various materials ranging from metals to ceramics and composites as well as bi-material systems, has been recently applied to predict ice-structure interactions. Although it shows promising future for further applications, there are also some challenging issues like high mesh dependency, large variation in cohesive properties etc., yet to be resolved. In this study, a 3D finite element model with the use of CEM was developed in LS-DYNA for simulating ice-structure interaction. The stability of the model was investigated and a parameter sensitivity analysis was carried out for a better understanding of how each material parameter affects the simulation results.


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