Development of a Composition Database for Selected Multicomponent Oils

2003 ◽  
Vol 2003 (1) ◽  
pp. 1131-1138 ◽  
Author(s):  
Zhendi Wang ◽  
B. Hollebone ◽  
M. Fingas ◽  
L. Sigouin ◽  
B. Fieldhouse ◽  
...  

ABSTRACT Multicomponent composition and corresponding physical properties data of crude oils and petroleum products are needed as input to environmental fate simulations. Complete sets of such data, however, are not available in the literature due to the complexity and expense of making the measurements. Environment Canada has previously developed a database of various physical and chemical properties of crude oils and petroleum products. In this cooperative project, ten “typical” crude oils and refined products in common use or transport were identified for subsequent characterization. Measured oil physical properties include API gravity, density, sulphur content, water content, flash point, pour point, viscosity, surface and interfacial tension, adhesion, the equation for predicting evaporation, emulsion formation, and simulated boiling point distribution. The chemical composition of the oils are quantified for hydrocarbon groups, volatile organic compounds, n-alkane distribution, distribution of alkylated polyaromatic hydrocarbon (PAH) homologues and other EPA priority PAHs, and biomarker concentrations. This project will provide the most complete and comprehensive database for the selected oils to date. The new composition data will be integrated into the existing Environment Canada oil properties database. The results will be made available to the public both on the world wide web and as a database on disc.

1997 ◽  
Vol 1997 (1) ◽  
pp. 929-930
Author(s):  
William R. Gala ◽  
Gary A. Rausina ◽  
Michael J. Ammann ◽  
Elizabeth A. Harvey ◽  
Patrick Y. O'Brien ◽  
...  

ABSTRACT Chevron has developed oil-specific properties summary sheets for major crude and high-volume oil products to improve our ability to provide timely and accurate information for decision-making processes in the initial stages of a spill and to help address questions posed by trustees and the public. Each summary sheet is composed of five modules that denote (1) the oil's physical and chemical properties; (2) the oil's environmental fate; (3) spill countermeasures; (4) public health and ecotoxicology data; and (5) appropriate analytical methods. Identified information gaps (Le., aquatic toxicity, WAF chemistry, etc.) are being addressed in Chevron-funded research at the University of California—Santa Cruz


Author(s):  
Кonstantin Е. Lesnykh ◽  
◽  
Aleksey А. Korshak ◽  
Nafis N. Khafizov ◽  
Andrey A. Kuznetsov ◽  
...  

The conditions for the formation of technological losses of oil and petroleum products during transportation through the main pipelines are considered and it is established that the main sources of these losses are large and small airflows of reservoirs. The value of technological losses from evaporation from tanks depends on a large number of factors, in particular: storage temperatures, pumping rates, tank filling heights, physical and chemical properties of the transported liquid, tanks turnover. Until now, a unified approach to the procedure for determining the qualitative and quantitative composition of technological losses from the evaporation of hydrocarbons during storage has not been developed, which leads to disagreements in assessing the actual losses of energy carriers. According to the analysis, it was found that the best is the calculation method for determining the actual irrecoverable losses of hydrocarbons. Its application involves the use of mathematical relationships that describe the dynamics of evaporation of oil and petroleum products in real conditions. To establish such relationships, it is proposed to develop and implement a unit that enables simulation of the process of evaporation from tanks under various conditions and obtaining experimental data taking into account a combination of a variety of factors that affect the amount of the technological losses.


Agronomy ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1476
Author(s):  
Ana Cristina Ferrão ◽  
Raquel P. F. Guiné ◽  
Elsa Ramalhosa ◽  
Arminda Lopes ◽  
Cláudia Rodrigues ◽  
...  

Hazelnuts are one of the most appreciated nuts worldwide due to their unique organoleptic and nutritional characteristics. The present work intended to analyse several physical and chemical properties of different hazelnut varieties grown in Portugal, namely Tonda de Giffoni, Grada de Viseu, Segorbe, Longa de Espanha, Butler, Gunslebert, and Negreta. In general, the results revealed statistically significant differences between the varieties under study. The Gunslebert had more elongated hazelnuts and with heavier shelled fruits, while the kernels of the Grada de Viseu revealed to be heavier. Grada de Viseu was harder in the shell, Gunslebert had a harder core, and Segorbe was more resistant to fracture. Fat was the more representative component for all varieties and in some cases the values of moisture and water activity were over the recommended amount (≥0.62). Tonda de Giffoni was the variety with the highest induction time, indicating the highest oxidation stability. Moreover, discriminant analysis revealed that the variables more important to distinguish the varieties were protein (λ = 0.007) and water activity (λ = 0.010). The results of this study help to better understand the differences between some hazelnut varieties that are cultivated in Portugal, which gives important hints for all players in the hazelnut sector.


2021 ◽  
pp. 1-10
Author(s):  
Anshu Siwach ◽  
Siddhartha Kaushal ◽  
Ratul Baishya

Abstract Mosses are one of the most important and dominant plant communities, especially in the temperate biome, and play a significant role in ecosystem function and dynamics. They influence the water, energy and element cycle due to their unique ecology and physiology. The present study was undertaken in three different temperate forest sites in the Garhwal Himalayas, viz., Triyuginarayan (Kedarnath Wildlife Sanctuary (KWLS)), Chakrata, and Kanasar forest range. The study was focused on understanding the influence of mosses on soil physical properties and nutrient availability. Different physico-chemical properties were analysed under two different substrata, that is, with and without moss cover in two different seasons, viz., monsoon and winter. We observed mosses to influence and alter the physical properties and nutrient status of soil in both seasons. All soil physical and chemical properties, except magnesium, showed significant difference within the substrates, among all the sites and across the two seasons. Besides the soil characteristics underneath the moss vegetation, the study also highlights the diversity of mosses found in the area. Mosses appear to create high nutrient microsites via a high rate of organic matter accumulation and retain nutrients for longer periods thus, maintaining ecosystem stability.


Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2998
Author(s):  
Mohammed Nadeem Bijle ◽  
Manikandan Ekambaram ◽  
Edward Lo ◽  
Cynthia Yiu

The in vitro study objectives were to investigate the effect of arginine (Arg) incorporation in a 5% sodium fluoride (NaF) varnish on its physical and chemical properties including F/Arg release. Six experimental formulations were prepared with L-arginine (L-Arg) and L-arginine monohydrochloride at 2%, 4%, and 8% w/v in a 5% NaF varnish, which served as a control. The varnishes were subjected to assessments for adhesion, viscosity, and NaF extraction. Molecular dynamics were simulated to identify post-dynamics total energy for NaF=Arg/Arg>NaF/Arg<NaF concentrations. The Arg/F varnish release profiles were determined in polyacrylic lactate buffer (pH-4.5; 7 days) and artificial saliva (pH-7; 1 h, 24 h, and 12 weeks). Incorporation of L-Arg in NaF varnish significantly influences physical properties ameliorating retention (p < 0.001). L-Arg in NaF varnish institutes the Arg-F complex. Molecular dynamics suggests that NaF>Arg concentration denotes the stabilized environment compared to NaF<Arg (p < 0.001). The 2% Arg-NaF exhibits periodic perennial Arg/F release and shows significantly higher integrated mean F release than NaF (p < 0.001). Incorporating 2% L-arginine in 5% NaF varnish improves its physical properties and renders a stable matrix with enduring higher F/Arg release than control.


2021 ◽  
Vol 410 ◽  
pp. 469-474
Author(s):  
Ivan S. Safronov ◽  
Alexander I. Ushakov

One of the most important purposes of materials science is the ability to govern the physical properties of materials characterized by different structures. The strength properties of nanostructured metal alloys do not always meet the exploitation requirements. The set of properties of such materials is stable within narrow limits: temperature, mechanical, and corrosion conditions. Traditional processing modes are ineffective for such materials. Attempts to use them often lead to the loss of unique physical and chemical properties. The most effective methods of processing such materials are associated with the use of laser radiation. The laser pulse has a number of features, including a complex effect on the surface layers of the material. Spot and short irradiation with high-energy rays can preserve the unique physical properties of samples as a whole and improve strength indicators without destroying the structure of the material as a whole.


2021 ◽  
Vol 1019 ◽  
pp. 174-178
Author(s):  
Ramesh Kumar ◽  
Priti Kumari ◽  
Kumar Saurav ◽  
Purushottam Poddar ◽  
Vijay Kumar Verma

The relative metallic character of noble metals, Cu, Ag & Au has been suggested by their physical and chemical properties. Their position in the metallic series is in the neighborhood of that of Li, Mg and Zn. These Metals are inferior of Li, Mg, Zn, Fe, Co and Ni in metallic character. Li, Mg, Zn, Fe, Co and Ni are inferior to Na, K, Rb, Cs, Ca, Ba and Sr. The noble metals have simple metallic character in physical properties at normal temperatures.


Author(s):  
Waylson Zancanella Quartezani ◽  
Julião Soares de Souza Lima ◽  
Talita Aparecida Pletsch ◽  
Evandro Chaves de Oliveira ◽  
Sávio da Silva Berilli ◽  
...  

There is little knowledge available on the best techniques for transferring spatial information such as stochastic interpolation and multivariate analyses for black pepper. This study applies multiple linear and spatial regression to estimate black pepper productivity based on physical and chemical properties of the soil. A multiple linear regression including all properties of a Latosol was performed and followed by variance analysis to verify the validity of the model. The adjusted variograms and data interpolation by kriging allowed the use of spatial multiple regression with the properties that were significant in the multiple linear regression. The forward stepwise method was used and the model was validated by the F-test. The influence of the Latosol properties was greater than the residual on the prediction of productivity. The model was composed by the physical properties fine sand (FS), penetration resistance (PR), and Bulk density (BD), and by the chemical properties K, Ca, and Mg (except for Mg in the spatial regression). The physical properties were of greater relevance in determining productivity, and the maps estimated by ordinary kriging and predicted by the spatial multiple regression were very similar in shape.


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