scholarly journals Pah Content of Clarais gariepinus Harvested from Ekulu River, Eastern Nigeria Contaminated with Effluents Generated from a Roofing Sheet Industry Risk Impact Assessment

Author(s):  
Ubani, Chibuike S. ◽  
Nweze, Ekene J. ◽  
Aneke, Munachimso V. ◽  
Arazu, Amarachukwu V. ◽  
Okeke, Emmanuel S. ◽  
...  

Aim: This study evaluated PAH content and health risks associated with consuming Clarais gariepinus (cat fish) from Ekulu Rivers, in Enugu, Nigeria fed with roofing sheet company effluent. Place and Duration of Study Design: Ekulu River, the largest body of water in the city of Enugu in Enugu State, south-eastern Nigeria, is a 25-kilometer long river (16mi) and it originates in the same city as well. The city is located on latitude 06o 21o N and 06o 30o and longitude 07o 26o E and 07o 37 Eo. Methodology: This analysis was conducted with the use of Gas Chromatography – Mass Spectroscopy (GC-MS) machine equipped with Flame ionization detector (FID). The health risks were evaluated by the mathematical models stipulated by USEPA and WHO. Results: The PAHs identified from the Clarias gariepinus samples were Acenaphthene, Acenaphthylene, Naphthalene, Fluorene, Phenanthrene, Anthracene, Flouranthene, Pyrene, Benzo(α)pyrene and Benzo (g-h-i)perylene. Benzo(α)pyrene and Benzo (g-h-i)perylene were predominant. The quantity of PAHs detected in all fish samples including the control ranged from below detectable limit (BDL) through 0.001 to 0.0786mg/kg. The LMW PAHs detected were 60 % while the HMW PAHs were 40 % of the total PAHs in isolated. The total PAH concentration observed from the different point locations were 0.1003 mg/kg, 0.0977 mg/kg, 0.1102 mg/kg and 0.0414 mg/kg for the downstream, upstream, POD and control respectively. The HQ and HI obtained in all point locations were < 1. The ILCR of all the PAHs detected were in the range of 10-5 to 10-9.  The benzo (α) pyrene in cat fish obtained from the POD has the most carcinogenic potency and also recorded the maximum limit (5E -03 mg/kg). Conclusion: it is pertinent to enlighten the fish consumers and mongers on the dangers posed by the consumption of fish from Ekulu River and also caution industries with injudicious effluent disposal into water bodies.

2021 ◽  
Vol 21 (2) ◽  
pp. 539-546
Author(s):  
ABIONA OLUSEYE OLADAPO ◽  
ADEGUNWA ABIODUN ODUNLAMI ◽  
AWOJIDE SHOLA HEZEKIAH ◽  
ANIFOWOSE ADEBANJO JACOB ◽  
TAYO ADENIYI SOLOMON

The present study was conducted to assess the carcinogenic and non-carcinogenic health risks of PAHs contamination in roasted plantain collected from three different locations within Osogbo metropolis, Nigeria. The PAHs were extracted using Soxhlet extraction technique with n-hexane and dichloromethane (3:1) as the extracting solvent. A column, packed with silica gel, was used for clean-up process and the levels of the targeted PAHs were determined by a gas chromatograph–flame ionization detector (GC-FID). The result revealed that the concentrations of total PAHs detected in the roasted samples at location A, B, C were 3.958 μg/kg, 3.654 μg/kg and 3.217 μg/kg. The HMW carcinogenic PAHs constitute about 32% of the total PAHs in the roasted plantain samples where benzo(a)pyrene, which is a marker for carcinogenicity, was found to be 9%. Comparing these results with the regulatory limits, all the analyzed roasted plantain samples were found below the maximum residual limit (MRL) of 5 μg/kg, but the calculated carcinogenic risk (CR) presented value greater than 1×10-4, signifying health risk associated with the consumption of the roasted plantain. The major source of the PAHs using diagnostic ratios (Fla/Pyr and Ph/Ant) showed that the charcoal used in roasting is a major contributing factor to the high levels of PAHs detected in the roasted plantain samples.


2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
A. J. Nyantakyi ◽  
S. Wiafe ◽  
O. Akoto ◽  
Bernard Fei-Baffoe

Appreciable levels of trace metals have been reported in the Tano basin, but data on the corresponding levels in fish and the risk they pose to consumers are limited. The levels of 7 trace metals in 18 fish muscles were assessed between November 2016 and October 2017 using acid digestion and PerkinElmer (PinAACle 900T) Atomic Absorption Spectrophotometry. Apart from Cu, all the metals studied were detected in all fish samples. The levels of Cr, As, and Hg were higher than the acceptable levels of fish muscles. Cr concentration ranged from 16.10 ± 0.2 mg/kg in Clarias gariepinus to 57.9 ± 4.2 mg/kg in Sarotherodon galilaeus. The levels of As ranged from 1.01 ± 0.08 in Clarias gariepinus to 3.00 ± 0.01 mg/kg in Mormyrus rume. Hg level was 0.58 ± 0.69 mg/kg in Oreochromis niloticus and 2.52 ± 0.70 mg/kg in Ctenopoma kingsleyae. However, Pb, Zn, and Cd concentrations were below the Food and Agriculture Organization limits with low target hazard quotients in all fish samples, suggesting no possible noncarcinogenic risks to adult consumers. Possible noncarcinogenic and carcinogenic health risks were recorded for As, Hg, and Cr in all fish species. Strong associations were observed between Hg, As, Zn, and Cr and between Pb and Cd suggesting a possible common source. Mormyrus rume fish species was under stress in the river, but the remaining species were in good condition. Periodic monitoring of trace metal concentrations in fish and enforcement of the buffer zone policy are recommended.


Food Research ◽  
2020 ◽  
Vol 5 (1) ◽  
pp. 185-194
Author(s):  
E.O. Oni ◽  
M.C. Adetunji ◽  
D.D. John-Babatunde ◽  
A.M. Omemu

This study aimed at evaluating the effect of Moringa leaves Marinade (MOM) on aflatoxin contamination of Clarias gariepinus. A total of thirty fresh fish samples (n = 30) grouped into four; Fresh fish without smoking and storage, smoked fish +1% and 2% Moringa oleifera Marinade (MOM) respectively and Control (0% MOM) were subjected to microbiological and HPLC analysis while storing for 0-3 months. Mean CFU/g of 2.8 and 3.1 x 102 CFU/g for bacteria and fungi were recovered, respectively. Furthermore, four bacteria and fungi genera each of which Aspergillus spp. was the most predominant (57%) were recovered from the fishes. Aflatoxin concentration increased progressively in 0% MOM smoked fish as the storage period increased, while aflatoxin concentration reduced in the fishes treated with 2% MOM (p≥0.05). On average, between 1-40% reduction in aflatoxin concentration and increased keeping quality was enhanced with 2% MOM treatment. These findings recommend the possibility of the use of moringa leaves in the treatment of commercially smoked fish.


2020 ◽  
Vol 4 (2) ◽  
pp. 41-45
Author(s):  
Sadam Sulaiman Indabo ◽  
Rufai Zakari

Dermestes maculatus is a major pest of stored fish in Nigeria, fish is preserved with highly persistent synthetic chemicals. There have been an increasing effort at developing plant-based toxicants that are environmentally friendly. Therefore, this study was conducted to screen the leaf extract of Azadirachta indica for phytochemical constituents. The efficacy of the methanolic leaf extract of the plant against D. maculatus was also evaluated. The leaves of A. indica were obtained, processed and taken to laboratory for methanolic extraction. Phytochemical screening was carried out to identify saponins, flavonoids, alkaloids, tannins, steroids, cardiac glycosides, glycosides, triterpenes and carbohydrates using standard procedure.  Both clean and infested samples of smoke-dried Clarias gariepinus were purchased from Sabon Gari Market, Zaria. The infested samples were used as initial source of D. maculatus larvae. Range finding test was carried out prior to the bioassay. During the bioassay, clean un-infested fish samples were weighed and introduced into kilner jars and respective dosages of 0.2g, 0.4g, 0.6g and 0.8g of extract were added. Another set of fish samples without the extract were maintained as control. The experiment was arranged in Completely Randomized Design with three replicates. Fifteen larvae of D. maculatus were introduced into both treated and control containers and covered. Mortality was recorded after 24, 48, 72 and 96 hours. Data obtained revealed an increase in mortality with increasing dose and time. Mortality ranged from 1.67 to 11.00. Therefore, leaf extract of A. indica should be incorporated in the development of larvicide against D. maculatus.   


2021 ◽  
Vol 13 (2) ◽  
pp. 804
Author(s):  
Jean Dubé ◽  
Maha AbdelHalim ◽  
Nicolas Devaux

Many applications have relied on the hedonic pricing model (HPM) to measure the willingness-to-pay (WTP) for urban externalities and natural disasters. The classic HPM regresses housing price on a complete list of attributes/characteristics that include spatial or environmental amenities (or disamenities), such as floods, to retrieve the gradients of the market (marginal) WTP for such externalities. The aim of this paper is to propose an innovative methodological framework that extends the causal relations based on a spatial matching difference-in-differences (SM-DID) estimator, and which attempts to calculate the difference between sale price for similar goods within “treated” and “control” groups. To demonstrate the potential of the proposed spatial matching method, the researchers present an empirical investigation based on the case of a flood event recorded in the city of Laval (Québec, Canada) in 1998, using information on transactions occurring between 1995 and 2001. The research results show that the impact of flooding brings a negative premium on the housing price of about 20,000$ Canadian (CAN).


Author(s):  
Carmelo Gugliotta ◽  
Davide Gentili ◽  
Silvia Marras ◽  
Marco Dettori ◽  
Pietro Paolo Muglia ◽  
...  

The aim of the study is to evaluate the preparedness of retirement and nursing homes in the city of Sassari at the end of the first wave of the severe acute respiratory syndrome coronavirus 2 epidemic, first by investigating the risk perception of epidemic outbreaks by the facility managers and subsequently by carrying out a field assessment of these facilities. To perform the field assessment, a checklist developed by the CDC (Infection Prevention and Control Assessment Tool for Nursing Homes Preparing for COVID-19) and adapted to the Italian context was used. Fourteen facilities took part in the survey (87.5%). The application of good practices for each survey area was expressed as a percentage with the following median values: restriction policies (87.5%), staff training (53.8%), resident training (67.6%), availability of personal protective equipment (41.7%), infection control practices (73.5%) and communication (80%). Among the facilities, considerable variability was observed in these evaluation fields: only the restriction policies and communication activities were applied uniformly. A discrepancy was found between perceived risk and real danger in the facilities, requiring targeted communication actions. At present, it is necessary to promote a new approach based on the prediction of critical events, thereby providing the means to effectively address them.


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