scholarly journals Study of Heavy Metals Bio Toxicity Present in Locally Produced Palm Kernel Oil in Osun State, Nigeria

Author(s):  
Oluwadamilola Ayoola Ajibade ◽  
Pascal Tchokossa ◽  
Taye Victoria Oluwasusi ◽  
Michael Oluwasanmi Adeleye ◽  
Funmilayo Joke Okparaocha

This study investigates the heavy metals content presents in locally produced Palm Kernel Oil in Osun State, Nigeria. 16 samples were collected from four major factories in four towns in the study area.  Atomic Absorption Spectrometry (AAS) was used for the concentration of the heavy metals analysis in the samples. The results show the contents of the heavy metal present were 0.022, 0.018, 0.090, 0.071, 0.166 and 0.010 ppm for Cd, As, Fe, Zn, Cu and Pb, respectively. The range of measured concentration of heavy metal contents in the palm kernel oil varies within the same factory which may be due to the fact that the production processes and most especially the source of the palm kernel used by the factories and nature of the soil where the palm tree is planted varied. The mean concentration of Cd, Zn, As, Fe and Pb were below the bio-recommended limit published by joint FAO/WHO. Only Cu is well above the permissible limit.

2021 ◽  
Vol 25 (2) ◽  
pp. 173-182
Author(s):  
E. Biose ◽  
C.F. Amaechi ◽  
C. Nwaemene

This study was carried out to determine some physicochemical properties and heavy metals level in primary school playground located in Benin City, Southern Nigeria using standard methods. A total of 10 topsoil samples were collected from five primary school playgrounds from different locations in Benin metropolis, Southern Nigeria in February, 2017. The mean levels of pH and EC ranged from 5.53 to 7.02 and 200.05 - 410.00 µS/cm respectively. The mean concentrations for heavy metals ranged from 337.15±64.28 and 464.10±19.37 for Fe, 23.40±7.50 and 29.70±4.81 for Mn, 45.95±8.70 and 67.95±4.74 for Zn, 8.48±1.61 and 12.90±3.82 for Cu, 5.10±2.33 and 7.41±1.54 for Cd, 4.42±2.02 and 8.39±7.09 for Cr, 6.17±2.82 and 13.82±6.76 for Pb, 0.99±0.09 and3.24±3.73 for Ni respectively. Heavy metal concentrations were in the following order. In Ogiegbaen, Eresoyen and Ekosodin Primary schools (PS) playground, the order was Fe> Zn> Mn> Cu> Pb> Cd> Cr> Ni while the order in Agbado PS and Olua PS were Fe> Zn> Mn> Cu> Pb> Cr> Cd> Ni and Fe> Zn> Mn> Pb> Cu> Cd> Cr> Ni respectively. Enrichment factor (EF), Contamination factor (CF) and Geoaccumulation index (Igeo) were used to evaluate the pollution status of the soil. Keywords: Topsoil, Playground, Heavy metals, Assessment Indices


Author(s):  
Biljana Bogdanova Popov ◽  
Vesna Karapetkovska Hristova ◽  
Stefce Presilski ◽  
Muhhamad Ali Shariati ◽  
Stevo Najman

In this study, the contents of five representative heavy metals (Cr, Pb, Zn, Cd and Cu) were determined in soil and propolis samples from four locations in southwestern Macedonia using atomic absorption spectrometry. The aim was to pinpoint the key factors that influence the content of heavy metals in propolis and to establish whether there is a connection between the contents of heavy metals in soil and in propolis from the same location. Generally, at all of the locations, the relative concentrations of heavy metals in soil were found to decrease in the following order: Zn>Cr>Cu>Pb>Cd. The highest mean values for concentrations of heavy metals in these soils were found to be: 72.03, 38.28, 26.64, 17.15 and 0.60 mg kg–1 for Zn, Cr, Cu, Pb and Cd, respectively, and they are all below the target values from the new Dutch list. The general trend of the heavy metal contents in propolis from the same four locations, in decreasing order, is: Pb>Cr>Zn>Cu≈Cd. Generally, the propolis samples from the highland locations (Orle and Rapeš) had lower overall contents of heavy metals than the lowland locations (Novaci and Makovo). All of the analyzed propolis samples meet the requirements of the Macedonian legislation and the international organizations for the maximum allowed levels for heavy metals. Attempts were made to find a correlation between the heavy metal contents in soil and propolis. According to our aim, the investigation presented herein offers one step towards a complete picture of ecological safety of the specific areas in the Republic of Macedonia. To do so, it is necessary to perform additional studies and to find appropriate biomonitoring methods. Further studies are needed to complete the picture and to determine the major pathways of incorporation of heavy metals in beehive products.  


2012 ◽  
Vol 610-613 ◽  
pp. 198-202
Author(s):  
Ying Xie ◽  
Tao Zhang ◽  
Chong Li Xu ◽  
Yuan Feng Hui ◽  
Wen Jing Ou Yang

Application of sludge-to-energy is an important direction for disposal of sludge, and it is necessary to provide the contents change of heavy metals in sludge. Through sampling in situ and analysis in laboratory, distributions of seven heavy metals in five kinds of sludge, which were come from wastewater treatment plant of Jilin Petrochemical Company of Petro China, were studied, and contents change of heavy metals in the course of sludge-to-energy were analyzed. The results were compared with the other sludge in the factory and municipal wastewater treatment plants and the national standard. The results showed that the heavy metal contents are different in the different sludge, and the mean is Fe>Cu>Zn>Mn>Pb >Cr>Cd, the total content distributions from high to low is incinerated sludge, chemical sludge, activated sludge, neutralization sludge, digested sludge. Contents of Cu and Zn exceeded the the mean of 44 municipal wastewater treatment plants and GB18918-2002. After biogas of digested sludge and energy of incinerated sludge were recovered, heavy metal contents exceeded in varying degrees, which were paid more attention for treatment and utilization.


Author(s):  
Mohd Jumain Jalil ◽  
Aliff Farhan Mohd Yamin ◽  
Mohd Saufi Md Zaini ◽  
Veronique Gloria V. Siduru ◽  
Norhashimah Morad ◽  
...  

Background: Studies pertaining to the epoxidation of fatty acids, garnered much interest in recent years due to the rising demand of eco-friendly epoxides derived from vegetable oils. Methods: Epoxide is an important chemical precursor for the production of alcohols, glycols and polymers, like polyesters and epoxy resin. Epoxidation is the name given to the reaction when the double bonds are converted into epoxide. Results: Temperature at 55oC was used as a reference material in the epoxide process, as it produces a high yield epoxide being 88%. The kinetic rate of epoxidized palm kernel oil, k was obtained to be k11= 0.5125, k12= 0.05045, k21= 0.03185, k41= 0.01 and k51= 0.01243. Conclusion: Hence, by fitting the result with the experimental work and simulation, the summation of error being stimulated by I-sight simulation was 0.731116428 and the correlation between the experimental and simulation data was 0.925544.


2021 ◽  
Author(s):  
Samuel O. Egbuna ◽  
Ukeh J. Nwachukwu ◽  
Chinedu M. Agu ◽  
Christain O. Asadu ◽  
Bernard Okolo

2021 ◽  
Vol 45 (1) ◽  
Author(s):  
Elijah Abakpa Adegbe ◽  
Oluwaseyi Oluwabukola Babajide ◽  
Lois Riyo Maina ◽  
Shola Elijah Adeniji

Abstract Background Heavy metal accumulation in the ecosystem constitutes a potential toxic effect which is hazardous to human health. Increasing environmental pollution has necessitated the use of cattle egrets to evaluate the levels of heavy metal contamination, to establish their use in biomonitoring of heavy metals and to provide data for monitoring pollution in the environment. Results The present study assessed the utilization of Bubulcus ibis in monitoring pollution in five abattoirs, namely Agege, Bariga, Kara, Itire and Idi-Araba, all situated in Lagos State. The concentration of five (5) heavy metals, cadmium (Cd), copper (Cu), nickel (Ni), lead (Pb) and zinc (Zn) was determined in the liver, muscle and feather of Bubulcus ibis using the atomic absorption spectrophotometer. The trend of metal accumulation was in the order: Zn > Cu > Pb > Cd > Ni for all the sampled tissues. The mean tissue concentrations of the metals were significantly different (p < 0.05) among the sites. The highest levels of metal concentration were reported in the liver in all the locations. Mean concentration of Cd in Kara (0.003 ± 0.00058) was significantly (p < 0.05) higher than those found at Agege (0.0013 ± 0.00058) and Idi-Araba (0.001 ± 0.001). A significant difference (p < 0.05) was also observed between the mean concentrations of Cu in Bariga (0.01 ± 0.001) and Idi-Araba (0.003 ± 0.001). Conclusion All the studied heavy metals were present in the liver, muscle and feathers of the cattle egrets. The contamination levels were ascertained from the study which indicated that cattle egrets are useful in biomonitoring studies and the generated data will serve as baseline data which could be compared with data from other locations for monitoring heavy metal pollution.


Foods ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1310
Author(s):  
Matúš Várady ◽  
Sylwester Ślusarczyk ◽  
Jana Boržíkova ◽  
Katarína Hanková ◽  
Michaela Vieriková ◽  
...  

The aim of this study was to determine the effect of roasting on the contents of polyphenols (PPH), acrylamide (AA), and caffeine (CAF) and to analyze heavy metals in specialty coffee beans from Colombia (COL) and Nicaragua (NIC). Samples of NIC were naturally processed and COL was fermented anaerobically. Green beans from COL (COL-GR) and NIC (NIC-GR) were roasted at two levels, light roasting (COL-LIGHT and NIC-LIGHT) and darker roasting (COL-DARK and NIC-DARK), at final temperatures of 210 °C (10 min) and 215 °C (12 min), respectively. Quantitative analyses of PPH identified caffeoylquinic acids (CQA), feruloylquinic acids, and dicaffeoylquinic acids. Isomer 5-CQA was present at the highest levels and reached 60.8 and 57.7% in COL-GR and NIC-GR, 23.4 and 29.3% in COL-LIGHT and NIC-LIGHT, and 18 and 24.2% in COL-DARK and NIC-DARK, respectively, of the total PPH. The total PPH contents were highest in COL-GR (59.76 mg/g dry matter, DM). Roasting affected the contents of PPH, CAF, and AA (p < 0.001, p < 0.011 and p < 0.001, respectively). Nickel and cadmium contents were significantly higher in the COL-GR than in the NIC-GR beans. Darker roasting decreased AA content, but light roasting maintained similar amounts of CAF and total PPH.


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