Mapping Soil Organic Matter and Analyzing the Prediction Accuracy of Typical Cropland Soil Types on the Northern Songnen Plain

Soil organic matter (SOM) plays a critical role in agroecosystems and the terrestrial carbon cycle. Thus, accurately mapping SOM promotes sustainable agriculture and estimations of soil carbon pools. However, few studies have analyzed the changing trends in multi-period SOM prediction accuracies for single cropland soil types and mapped their spatial SOM patterns. Using time series 7 MOD09A1 images during the bare soil period, we combined the pixel dates of training samples and precipitation data to explore the variation in SOM accuracy for two typical cropland soil types. The advantage of using single soil type data versus the total dataset was evaluated, and SOM maps were drawn for the northern Songnen Plain. When almost no precipitation occurred on or near the optimal pixel date, the accuracies increased, and vice versa. SOM models of the two soil types achieved a lower root mean squared error (RMSE = 0.55%, 0.79%) and mean absolute error (MAE = 0.39%, 0.58%) and a higher coefficient of determination (R2 = 0.65, 0.75) than the model using the total dataset and resulted in a mean relative improvement (RI) of 30.21%. The SOM decreased from northeast to southwest. The results provide reference data for the accurate management of cultivated soil and determining carbon sequestration.

Elevated Fe and Mn Concentrations in Groundwater in the Songnen Plain, Northeast China, and the Factors and Mechanisms Involved

Groundwater is an essential source of drinking and irrigation water. However, elevated Fe and Mn concentrations in groundwater have been found in recent decades, which can adversely affect human health and decrease crop quality and yields. The roles of hydrogeochemical changes and groundwater pollution (exogenous reductive material inputs) in this have not been studied adequately. We determined the distribution of Fe and Mn concentrations in groundwater in the Songnen Plain, northeast China, which is known for elevated Fe and Mn concentrations, and investigated the factors and mechanisms involved in causing the elevated concentrations. Chemical and statistical analyses indicated that the Fe and Mn concentrations in groundwater significantly correlated with climate parameters (precipitation and temperature), surface features (altitude, distance from a river, soil type, soil texture, and land use type) and hydrogeochemical characteristics (chemical oxygen demand and NH4+, NO3−, and P concentrations). In particular, the Fe and Mn concentrations in groundwater are higher in areas containing paddy fields and water bodies than other land use type areas. Areas with groundwater containing ultra-high Fe and Mn concentrations have almost all of the favorable factors. The main reasons for the elevated Fe and Mn concentrations in groundwater in the study area are the Fe/Mn mineral-rich strata and soil with abundant organic matter acting as sources of Fe and Mn to the groundwater and the reductive environment in the lower terrain and areas containing water bodies favoring Fe and Mn dissolution in the groundwater. Inputs of pollutants from agricultural activities have caused the Fe and Mn concentrations in groundwater to increase. Future studies should be performed to study interactions between pollutants from agricultural activities and Fe and Mn in groundwater and develop environmental management strategies for preventing future increases in Fe and Mn concentrations and promoting sustainable development of agriculture.

Distribution, Formation and Human Health Risk of Fluorine in Groundwater in Songnen Plain, NE China

Songnen Plain is one of the three great plains in northeast China with abundant groundwater resources. The continuous population growth and the rapid development of agriculture and economy in China has caused a series of environmental problems in the plain, such as endemic diseases caused by the accumulation of harmful substances in drinking water. This paper conducts a systematic investigation of fluorine in the groundwater of Songnen Plain. The results showed that fluorine was widespread in the groundwater of the plain in the concentration range of BDL–8.54 mg·L−1, at a mean value of 0.63 mg·L−1 and detectable at a rate of 85.91%. The highest concentrations of fluorine were found in central and southwest areas of the plain. The concentration exceeded the guideline values for fluorine in drinking water and may have varying degrees of adverse effects on adults, and especially children, in the study area. The fluorine in groundwater mainly came from the dissolution of fluorite and other fluorine-containing minerals, and the concentrations and distribution of fluorine were affected by cation exchange, groundwater flow field and hydrochemical indexes (pH, TDS and HCO3−). The study provides scientific basis for the investigation, evaluation and prevention of endemic diseases caused by fluorine.

Assessment of Groundwater Quality and Pollution in the Songnen Plain of Jilin Province, Northeast China

Clean groundwater resources are vital to human health. To evaluate groundwater quality in the Songnen Plain (Jilin), a field investigation sampling test, multivariate statistical analysis, and spatial analysis were conducted based on a geographic information system. The main substances exceeding the standard were screened out, and the main controlling factors affecting groundwater quality were discussed. The research result showed that nine components exceeded groundwater standards by approximately 10%: Al, total hardness (TH), total dissolved solids (TDS), Mn, As, NO3−, Fe, F−, and BaP. The over-standard of TDS and TH in groundwater are mainly distributed in the geological environment conditions and unreasonable exploitation and utilization of groundwater in this area. The results of the multi-index evaluation showed that the most important factors affecting groundwater quality were general chemical indices, followed by inorganic toxicology and heavy metals. Controlling the overexploitation of water resources, controlling agricultural activities and sewage discharge, and implementing water conservation systems are the main pathways to improve water quality in the study area. The research results can provide a reference for groundwater pollution control and water resource protection in the Songnen Plain (Jilin).