Sediment metals adhering to biochar enhanced phosphorus adsorption in sediment capping

Metal ions in sediment were inherent Ca and Fe sources for biochar modification. In this work, effect of Ca2+ and Fe2+ released from sediment on biochar for phosphorus adsorption was evaluated. Results showed that, raw peanut shell biochar (PSB) was poor in phosphorus adsorption (0.48 mg/g); sediment-triggered biochar (S-PSB) exhibited P adsorption capacity of 1.32 mg/g in capping reactor and maximum adsorption capacity of 10.72 mg/g in Langmuir model. Sediment released Ca2+ of 2.2–4.1 mg/L and Fe2+/Fe3+ of 0.2–9.0 mg/L. The metals loaded onto biochar surface in the forms of Ca-O and Fe-O, with Ca and Fe content of 1.47 and 0.29%, respectively. Sediment metals made point of zero charge (pHpzc) of biochar shifted from 5.39 to 6.46. The mechanisms of enhanced P adsorption by S-PSB were surface complexation of CaHPO4 followed by precipitation of Ca3(PO4)2 and Ca5(PO4)3(OH). Sediment metals induced modification of biochar and improvement of P adsorption, which was feasible to overcome the shortcomings of biochar on phosphorus control in sediment capping.

Mining Contamination Disrupts Successional Change in Salt Marshes

<p>Salt marshes can generally be considered as sinks for metals. Research into salt marshes in Cornwall, UK suggests those estuaries heavily impacted by mining contamination are characterised by a less diverse vegetation compared with a significantly less-polluted site. Assessment using the National Vegetation Classification on the mid-marsh confirmed an Armeria maritima-dominated community was to be found in the most metal-enriched salt marsh of Restronguet Creek. However, this plant was co-dominant with Plantago maritima in the moderately contaminated marsh of Lelant and not present at all in the Camel, which has been subject to limited mining related contamination. Using canonical correspondence analysis, vegetation abundance data was compared with geochemical variables within the sediment. Metals were studied using extractions to signal bioavailability. P. maritima was not associated with the very high metal levels found in Restronguet Creek. A. maritima, had some association with soluble copper and was closer to the bulk of metals than P. maritima. As tolerance to adverse conditions and competitiveness are mutually exclusive, A. maritima, therefore, exists in a successional relationship with P. maritima. A. maritima then appears to be outcompeted by P. maritima in marshes with low metal loadings. Moderately high metal content results in a loss of competitiveness by P. maritima allowing A. maritima to co-dominate. In extremely metal-rich estuaries, however, P. maritima is unable to compete, allowing A. maritima to colonize the mid-marsh. Vegetation community may, therefore, be useful as an indicator of the level of metal contamination.</p>

Metal Distribution and Sediment Quality Variation across Sediment Depths of a Subtropical Ramsar Declared Wetland

The study of wetlands is particularly important as these systems act as natural water purifiers and thus can act as sinks for contaminated particles. Wetland sediments are important as they provide an indication of potential contamination across temporal and spatial scales. The current study aimed to investigate the distributions of selected metals and nutrients in different sites in relation to sediment depth, and identify relationships among sediment metals. Significant differences in nutrient (i.e., N, P) and metal (i.e., K, Mg, Na, Fe, Cu, B) concentrations were found across study sites, whereas nutrients (i.e., N, P) and metals (i.e., Ca, Mg, Fe, Cu, Zn) were significantly different with sediment depths. When compared against Canadian sediment standards, most of the assessed metals were within the “no effect” level across the different sites and depths. The K, Ca, and Mg concentration showed extreme contamination across all sites and depths. The enrichment factor values for K, Ca, and Mg showed extremely high enrichment levels for all sites and sediment depths. The Na, Mn, Fe, Cu, Zn, and B concentration showed mostly background enrichment levels. All sediments across the different sites and sediment depths indicated deterioration of sediment quality. Pearson correlations suggest that most metals might have originated in a similar source as that of Mn and B, owing to a lack of significant differences. These results provide baseline information for the general management of the Nylsvley Wetland in relation to sediment metal pollution. The specific sources of metal contaminants also require further elucidation to further inform management efforts.

Use of pre-industrial baselines to monitor anthropogenic enrichment of metals concentrations in recently deposited sediment of floodplain lakes in the Peace-Athabasca Delta (Alberta, Canada)

Well-designed monitoring approaches are needed to assess effects of industrial development on downstream aquatic environments and guide environmental stewardship. Here, we develop and apply a monitoring approach to detect potential enrichment of metals concentrations in surficial lake sediments of the Peace-Athabasca Delta (PAD), northern Alberta, Canada. Since the ecological integrity of the PAD is strongly tied to river floodwaters that replenish lakes in the delta, and the PAD is located downstream of the Alberta oil sands, concerns have been raised over the potential transport of industry-supplied metals to the PAD via the Athabasca River. Surface sediment samples were collected in September 2017 from 61 lakes across the delta, and again in July 2018 from 20 of the same lakes that had received river floodwaters 2 months earlier, to provide snapshots of metals concentrations (Be, Cd, Cr, Cu, Ni, Pb, V, and Zn) that have recently accumulated in these lakes. To assess for anthropogenic enrichment, surficial sediment metals concentrations were normalized to aluminum and compared to pre-industrial baseline (i.e., reference) metal-aluminum linear relations for the Athabasca and Peace sectors of the PAD developed from pre-1920 measurements in lake sediment cores. Numerical analysis demonstrates no marked enrichment of these metals concentrations above pre-1920 baselines despite strong ability (> 99% power) to detect enrichment of 10%. Measurements of river sediment collected by the Regional Aquatics- and Oil Sands-Monitoring Programs (RAMP/OSM) also did not exceed pre-1920 concentrations. Thus, results presented here show no evidence of substantial oil sands-derived metals enrichment of sediment supplied by the Athabasca River to lakes in the PAD and demonstrate the usefulness of these methods as a monitoring framework.