Effect of modifiers and mineral additives from industrial waste on the quality of aerated concrete products

The given article is devoted to research of influence of polymer modifiers and mineral additives on quality of composite aerated concrete products. When selecting the composition of composite aerated concrete local raw materials and components were used: portland cement, sand, aluminum powder, polyvinyl acetate, fly ash, post-alcoholic bard and whey of milk. Preliminary polyvinyl acetate was combined with binder mixing water at a temperature above 55ºC to obtain a readily soluble polymer emulsion. Dispersion was carried out with a rotary-pulsation apparatus at a pressure of 0.5-1.0 MPa and a rotor speed of ~1200 rpm. In the same apparatus the complex modifier was produced. The offered technology of production of a complex modifier seems to be the most effective for composite aerated concrete. It made it possible to reduce water absorption and capillary suction of composite aerated concrete by an average of 25% and 45%, respectively. Moreover, different combinations of fly ash, polymer and modifier made it possible to achieve optimal values of thermal conductivity, compressive strength and frost resistance of composite aerated concrete.

Application of Okra Mucilage for the Prevention of Shale Swelling

Maintain wellbore stability is a very critical aspect of the drilling operation. The unstable wellbore provides severe loss to the drilling operators in terms of time and money. One of the significant reasons for unstable wellbore occurs due to the expansion of shale formation. Several solutions are utilized to tackle the expansion of shales, such as salts, PHPA, silicates, and oil-based drilling fluids. There are limitations associated with these solutions, such as thermal instability, limited supply, unfriendly to the environment and marine life, etc. In this study, Okra mucilage has been introduced as a shale swelling inhibitor in drilling fluids. Okra is widely used in the medical and food industries as a viscosifier as it is abundantly available in tropical and subtropical regions. Okra powder has been used as a fluid loss control additive in the literature. The application of the Okra solution as a shale swelling inhibitor in drilling fluids was not investigated in the past. In this study, Okra mucilage was extracted from the Okra plant and used as shale swelling inhibitor. Three different concentrations (5, 10 & 20) vol% of Okra mucilage mixed solutions were used for linear swell test. The test was performed using a linear swell tester at atmospheric conditions for 24 hours on bentonite wafers. Further zeta potential, particles size and capillary suction timer test (CST) were conducted. The experimental study revealed that Okra mucilage reduced the swelling of bentonite. For instance, 10 and 20% of Okra mucilage solutions reduced the swelling by 36.8% and 50.5%, respectively. The Okra mucilage decreased the zeta potential of clay and increased its particle size. CST time decreased initial at low concentration and increased with concentration. Overall, experimental investigations suggested that Okra mucilage could be an alternate green shale inhibitor in drilling fluids without compromising other drilling fluids' properties.

Variations of nanoparticle layer properties during nucleate pool boiling

The nanoparticle layer detachment during nucleate pool boiling and its influences on heat transfer surface properties were explored experimentally. The material of the heat transfer surface was copper and the nanoparticle layer was formed on the heat transfer surface by nucleate boiling in the water-based TiO2 nanofluid. It was found that the detachment of the nanoparticle layer during nucleate boiling in pure water is significant. In the present experiment, more than half of nanoparticles deposited on the heated surface were detached before the CHF condition was reached. The thickness and roughness decreased accordingly. However, the wettability and wickability that are the influential parameters on the CHF value were maintained even after the occurrence of nanoparticle layer detachment and deteriorated only after the CHF condition was reached. It is therefore considered that the onset of CHF brings qualitative change to the capillary suction performance of the layer of nanoparticles. In exploring the effect of the nanoparticle layer properties on the nucleate boiling heat transfer, sufficient attention should be paid to the variation of the nanoparticle layer properties during nucleate boiling.

Determination of Relationship between Higher Heating Value and Atomic Ratio of Hydrogen to Carbon in Spent Coffee Grounds by Hydrothermal Carbonization

This study was a preliminary investigation of solid recovered fuel production from spent coffee grounds using the hydrothermal carbonization (HTC) technique. The spent coffee grounds (SCGs) were subjected to HTC at 170 to 250 °C. The biochar was characterized by proximate analysis, ultimate analysis, capillary suction time, time to filter, suspended solids, and particle size distribution. The biochar yields decreased with increasing HTC temperature and time. However, the higher heating value (HHV) of biochar increased with the HTC temperature and time. The H/C slop relative to the O/C atomic rate of spent coffee grounds was 0.10 with low decarboxylation selectivity. Considering the HHV of biochar and dehydration capacity depend on ratio of H/C vs. O/C, the optimum reaction temperature of HTC was 200 °C, and the biochar from SCGs is an attractive biochar.

Synergetic Effect of Combined CaO2 and Microwave Treatment on Waste Active Sludge Dewaterability and Organic Contaminants’ Removal

This study investigated the synergetic effect of the combined calcium peroxide (CaO2) and microwave (MW) treatment on waste active sludge dewatering properties and organic contaminants’ removal. The optimal sludge dewaterability was obtained at CaO2 (20 mg/gVSS)/MW (70°C), and the capillary suction time decreased by 52% compared with raw sludge. Further investigation indicated that total extracellular polymeric substances (EPS), tightly bound EPS, total protein, and protein present in tightly bound EPS were closely correlated with sludge dewaterability. Tryptophan, aromatic protein–like substances and humic acid–like substances were the key compounds that affect sludge dewaterability. The charge neutralization and bridge effect of cation ions were strengthened when combined with MW irradiation. In addition, it was revealed that MW facilitated CaO2 to produce more hydroxyl and superoxide anion radicals. This study confirmed CaO2/MW to be an effective way to improve sludge dewatering and remove organic pollutants from sludge.

Enhancing Phosphorus Recovery and Dewaterability of Waste Activated Sludge for Combined Effect of Thermally Activated Peroxydisulfate and Struvite Precipitation

Phosphorus is a nonrenewable and irreplaceable limited resource, and over 90% of phosphorus in influenttransfers into sludge in wastewater treatment plants. In this study, thermally activated peroxydisulfate (TAP) treatment was combined with struvite precipitation to enhance waste activated sludge (WAS) dewaterability and phosphorus recovery. TAP simultaneously enhanced dewaterability and solubilization of WAS. The optimal conditions of TAP treatment were PDS dosage 2.0 mmol/g TSS, 80 °C, pH 4.0~7.0 and 40 min, which enhanced dewaterability (capillary suction time (CST) from 94.2 s to 28.5 s) and solubilization (PO43−-P 177.71 mg/L, NH4+-N 287.22 mg/L and SCOD 10754 mg/L). Radical oxidation disintegrated tightly bound extracellular polymeric substances (TB-EPS) and further released bound water. The acidification effect neutralized the negative surface charge of colloid particles. Compared with thermal hydrolysis, TAP effectively promoted the release of PO43−, NH4+ and SCOD. Cation exchange removed most Ca and Al of the TAP treated supernatant. The optimal conditions of struvite precipitation were Mg/P 1.4 and pH 10.0, which achieved phosphorus recovery of 95.06% and struvite purity of 94.94%. The income obtained by struvite adequately covers the cost of struvite precipitation and the cost of WAS treatment is acceptable.

Operation of Submerged Anaerobic Membrane Bioreactors at 20 °C: Effect of Solids Retention Time on Flux, Mixed Liquor Characteristics and Performance

Four flat-sheet submerged anaerobic membrane bioreactors ran for 242 days on a simulated domestic wastewater with low Chemical Oxygen Demand (COD) and high suspended solids. Organic loading was maintained around 1.0 g COD L−1 day−1, while solids retention time (SRT) was varied from 20–90 days. This was achieved at a constant membrane flux, maintained by adjusting transmembrane pressure (TMP) in the range 1.8-9.8 kPa. Membrane fouling was assessed based on the required TMP, with mixed liquors characterised using capillary suction time, frozen image centrifugation and quantification of extracellular polymeric substances (EPS). SRT had a significant effect on these parameters: fouling was least at an SRT of 30 days and highest at 60 days, with some reduction as this extended to 90 days. Operation at SRT <30 days showed no further benefits. Although operation at a short SRT was optimal for membrane performance it led to lower specific methane productivity, higher biomass yields and higher effluent COD. Short SRT may also have accelerated the loss of essential trace elements, leading to reduced performance under these conditions. A COD-based mass balance was conducted, including both biomass and methane dissolved in the effluent.