AbstractA direct consequence of quantization of gravity would be the existence of gravitons. Therefore, spontaneous transition of an atom from an excited state to a lower-lying energy state accompanied with the emission of a graviton is expected. In this paper, we take the gravitons emitted by hydrogen and helium in the Universe after recombination as a possible source of high frequency background gravitational waves, and calculate the energy density spectrum. Explicit calculations show that the most prominent contribution comes from the $$3d-1s$$
3
d
-
1
s
transition of singly ionized helium $$\mathrm {He}^{+}$$
He
+
, which gives a peak in frequency at $$\sim 10^{13}$$
∼
10
13
Hz. Although the corresponding energy density is too small to be detected even with state-of-the-art technology today, we believe that the spontaneous emission of $$\mathrm {He}^{+}$$
He
+
is a natural source of high frequency gravitational waves, since it is a direct consequence if we accept that the basic quantum principles we are already familiar with apply as well to a quantum theory of gravity.