Ozone hole over poles : Current status

The ozone in the stratosphere is of great importance for very survival of life on the mother planet the Earth. Ozone acts as an umbrella and protects us from the harmful ultraviolet radiations coming from the Sun. The catalytic destruction of ozone by ClOx & NOx in general and ozone hole phenomenon over Antarctica during spring time in particular has generated unprecedented interest in monitoring of ozone and other trace constituents in the atmosphere. The satellites have proved to be an important tool to monitor the global ozone column on regular basis. The ozone data using various satellite platforms has been analyzed for the ozone hole studies over north and south poles. Also Ozone measurements were carried out at Maitri, Antarctica. The satellite data indicates that some recovery of ozone hole as a result of international efforts in reduction of use of CFCs which are the main culprit for ozone hole. However, it will be too early to conclude about ozone hole recovery. In the present communication current status of ozone hole will be discussed in detail.

New reference materials for trace-levels of actinide elements in plutonium

Two plutonium oxides were prepared as unique reference materials for measurement of actinide elements present as trace constituents. Each reference material unit is approximately 200 mg of PuO2 powder in a quartz glass bottle. Characterized attributes of the oxides included mass fractions of plutonium, americium, neptunium, and uranium. Isotope-amount ratios were also determined for plutonium and uranium, but neptunium and americium were observed to be monoisotopic 237Np and 241Am. Measurements for characterization and verification of the attributes show that plutonium and trace actinides are homogeneous with the exception of limited heterogeneity for uranium, primarily observed for the 238U isotope. Model purification ages calculated from measured americium and uranium attribute values are consistent with material histories and indicate that these impurities are predominantly due to the decay of plutonium isotopes.

2 and 3-dimensional structure of the descent of mesospheric trace constituents after the 2013 SSW elevated stratopause event

We use the Specified Dynamics version of the Whole Atmosphere Community Climate Model Extended (SD-WACCMX) to model the descent of nitric oxide (NO) and other mesospheric tracers in the extended, elevated stratopause phase of the 2013 Sudden Stratospheric Warming (SSW). The dynamics are specified with a high altitude version of the Navy Global Environmental model (NAVGEM-HA). Consistent with our earlier published results, we find that using a high altitude meteorological analysis to nudge WACCMX allows for a realistic simulation of the descent of lower thermospheric nitric oxide down to the lower mesosphere, near 60 km. This is important because these simulations only included auroral electrons, and did not consider additional sources of NO from higher energy particles, for example, medium energy electron precipitation (> 30 keV). This suggests that the so-called energetic particle precipitation indirect effect (EPP-IE) can be accurately simulated, at least in years of low geomagnetic activity, such as 2013, without the need for additional NO production, provided the meteorology is accurately constrained. Despite the general success of WACCMX in simulating mesospheric NO, a detailed comparison of the WACCMX fields with the analyzed NAVGEM-HA H2O and satellite NO and H2O data from the Solar Occultation for Ice Experiment (SOFIE) and the Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS) reveals significant differences in the latitudinal and longitudinal distributions in the 45–55 km region. This stems from the tendency for WACCMX descent to maximize at sub-polar latitudes and while such sub-polar descent is seen in the NAVGEM-HA analysis, it is more transient than in the WACCMX simulation. These differences are linked to differences in the Transformed Eulerian Mean (TEM) circulation between NAVGEM-HA and WACCMX, most likely arising from small differences in how gravity wave forcing is represented. To attempt to compensate for the differing distributions of model vs. observed NO and to enable us to quantify the total amount of upper atmospheric NO delivered to the stratopause region, we use potential vorticity and equivalent latitude coordinates. Preliminary results suggest both model and observations are generally consistent with NO totals in the range of 0.1–0.25 gigamoles (GM).

Impact Assessment and Geochemical Background Analysis of Surface Water Quality of Catchments Affected by the 2017 Portugal Wildfires

In October 2017, the Mondego hydrological basin was devastated by multiple wildfires. To understand the impacts that these had on surface water quality, monthly monitoring campaigns were implemented in the affected catchments. The campaigns oversaw the water’s physical characteristics and major, minor and trace constituents. Analysis of major changes was performed, as well as comparisons with geochemical backgrounds, determined using publicly available data collected prior to the fires. The backgrounds allowed us to verify which water parameters were most influenced by the fires. Wildfires were responsible for increasing turbidity on all watercourses, and electrical conductivity increased in watercourses with flatter, granitoid/sedimentary-dominated watersheds. Cl−, NO3−, and SO42− surpassed background values in most monitored basins. Changes in Al, Fe, Mn, As, Ba, and Zn concentrations were observed in all watercourses after the wildfires and decreases after intense rainfall. Background values were particularly exceeded for Al in all monitoring points and As in basins with extensive agricultural areas. Burnt plant material and organic matter partially account for the increases in Cl−, NO3−, SO42−, Al, As, Fe, and Mn content. High Al, Fe and Zn with low water conductivity suggests that these elements were associated with sediment loads after the removal of vegetation.

Measurement of VOCs using open-path mid-infrared dual comb spectroscopy

<p>Open-path measurements of atmospheric gas species over km-scale path lengths are well suited to quantify emissions from sources like oil and gas, forest fires, and industry. is a relatively new technique that combines high-resolution and broad spectral coverage with no instrument lineshape and near perfect frequency calibration. These features have enabled open-path DCS to provide accurate measurements of multiple trace gas species simultaneously in the near-infrared across path lengths ranging from 100 m to several km. However, in order to reach the sensitivity necessary to detect many atmospheric trace constituents, including volatile organic compounds (VOCs), operation in the mid-infrared (or UV/Vis) is required.</p><p>Here, we show a mid-infrared open-path dual comb spectrometer operating in the 3-4 and 4.5-5 μm spectral regions. We have used this spectrometer to measure methane, ethane, and propane (arising primarily from oil and gas activity) across a 1-km-long path in Boulder, CO for 1 week with an ethane sensitivity of ∼0.1 ppb for a 2-minute time resolution. In addition, we show quantitative measurements of intentionally released acetone and isopropanol with a 1-σ sensitivity of 5.7 ppm·m and 2.4 ppm·m, respectively. In the 4.5-5 μm region, we have used this system to detect N<sub>2</sub>O, CO, and O<sub>3</sub>. Finally, we have developed a second-generation instrument in the 3-4 μm region that is more compact and has improved stability. This system was recently deployed in a van at an active oil and gas drilling operation. We present preliminary measurements of methane, ethane, and higher hydrocarbons from this deployment as well as initial efforts at emissions quantification.</p>

Characterization of Galvanic Sludges Waste Derived of the Metal Plating Industry from Cariri Region, Northeastern of Brazil

In this study, galvanic sludge waste (GSW) was characterized in order to identify its chemical and structural properties, allowing indicate reuse, treatment and final disposal methods, and evaluate the environmental hazards. The characterization of the galvanic sludge sample originating from a surface treatment plant from galvanic industries of semi-jewels in the Cariri region, NE of Brazil was performed. The chemical characterization of the samples by flame atomic absorption spectroscopy (FAAS) and X-Ray Fluorescence (XRF) showed that Zn and Cu are the predominant elements. However, elements like Ni, Cd, Mn, Fe, Cr and Co are present as a minority or as trace constituents. The concentrations of residues were higher, except Ni, in the LM industry (27 g Zn.kg -1, 194 g Cu.kg -1, 8 g Fe.kg-1, 538 mg Cd.kg -1, 227 mg Ni.kg -1, 73.5 mg Cr.kg1, 14 mg Co.kg-1) in relation to LJ (11 g Zn.kg-1, 3 g Fe.kg-1, 102 g Cu.kg-1, 2 g Cd.kg-1, 141 mg Ni.kg-1, 11 mg Co.kg-1), denoting that there is no uniform standard in the treatment process of the effluent from baths for Metal deposition. According to the standard procedure (Brazilian norm NBR10004/04) the elements Cd and Cr are the main constituents responsible for the classification of the residues as hazardous. The X-ray diffractogram of the dried galvanic sludge only revealed the presence of BaSO4 and CuO as crystalline phases, a result which agrees with the results from FT-IR. The results point to an attractive way of valorizing GSW avoiding the negative impact associated with its disposal in landfills.

An Iterative Qualitative–Quantitative Sequential Analysis Strategy for Electron-Excited X-ray Microanalysis with Energy Dispersive Spectrometry: Finding the Unexpected Needles in the Peak Overlap Haystack

When analyzing an unknown by electron-excited energy dispersive X-ray spectrometry, with the entire periodic table possibly in play, how does the analyst discover minor and trace constituents when their peaks are overwhelmed by the intensity of an interfering peak(s) from a major constituent? In this paper, we advocate for and demonstrate an iterative analytical approach, alternating qualitative analysis (peak identification) and standards-based quantitative analysis with peak fitting. This method employs two “tools”: (1) monitoring of the “raw analytical total,” which is the sum of all measured constituents as well as any such as oxygen calculated by the method of assumed stoichiometry, and (2) careful inspection of the “peak fitting residual spectrum” that is constructed as part of the quantitative analysis procedure in the software engine DTSA-II (a pseudo-acronym) from the National Institute of Standards and Technology. Elements newly recognized after each round are incorporated into the next round of quantitative analysis until the limits of detection are reached, as defined by the total spectrum counts.

Cyanobacteria: The Great Liberators

This chapter discusses the importance of cyanobacteria. The evolution of cyanobacteria brought the biological production of oxygen to Earth for the first time. This led, in turn, to the eventual accumulation of oxygen in the atmosphere and to the widespread evolution of oxygen-utilizing organisms. However, the importance of cyanobacteria goes beyond this. Cyanobacteria were the first photosynthetic organisms on Earth to use water as a source of electrons. Unlike the sulfide, Fe2+, and H2 used by anoxygenic phototrophic organisms, water is almost everywhere on the planet surface. This means that biological production on Earth was no longer limited by the electron source (water in this case), but rather by nutrients and other trace constituents making up the cells. In the end, the use of water in photosynthesis resulted in an increase in rates of primary production on Earth by probably somewhere between a factor of ten to a thousand. For the first time, life on Earth became truly plentiful. With the evolution of cyanobacteria, Earth was on its way to becoming a green planet.

Chemistry of riming: the retention of organic and inorganic atmospheric trace constituents

During free fall in clouds, ice hydrometeors such as snowflakes and ice particles grow effectively by riming, i.e., the accretion of supercooled droplets. Volatile atmospheric trace constituents dissolved in the supercooled droplets may remain in ice during freezing or may be released back to the gas phase. This process is quantified by retention coefficients. Once in the ice phase the trace constituents may be vertically redistributed by scavenging and subsequent precipitation or by evaporation of these ice hydrometeors at high altitudes. Retention coefficients of the most dominant carboxylic acids and aldehydes found in cloud water were investigated in the Mainz vertical wind tunnel under dry-growth (surface temperature less than 0 °C) riming conditions which are typically prevailing in the mixed-phase zone of convective clouds (i.e., temperatures from −16 to −7 °C and a liquid water content (LWC) of 0. 9 ± 0. 2 g m−3). The mean retention coefficients of formic and acetic acids are found to be 0. 68 ± 0. 09 and 0. 63 ± 0. 19. Oxalic and malonic acids as well as formaldehyde show mean retention coefficients of 0. 97 ± 0. 06, 0. 98 ± 0. 08, and 0. 97 ± 0. 11, respectively. Application of a semi-empirical model on the present and earlier wind tunnel measurements reveals that retention coefficients can be well interpreted by the effective Henry's law constant accounting for solubility and dissociation. A parameterization for the retention coefficients has been derived for substances whose aqueous-phase kinetics are fast compared to mass transport timescales. For other cases, the semi-empirical model in combination with a kinetic approach is suited to determine the retention coefficients. These may be implemented in high-resolution cloud models.