Handheld LIBS for Li Exploration: An Example from the Carolina Tin-Spodumene Belt, USA

Laser-induced breakdown spectroscopy (LIBS), which has recently emerged as tool for geochemical analysis outside the traditional laboratory setting, is an ideal tool for Li exploration because it is the only technique that can measure Li in minerals, rocks, soils, and brines in-situ in the field. In addition to being used in many products essential to modern life, Li is a necessary element for a reduced carbon future and Li–Cs–Ta (LCT) granitic pegmatites are an important source of Li. Such pegmatites can have varying degrees of enrichment in Li, Rb, Cs, Be, Sn, Ga, Ta>Nb, B, P, and F. We focus here on the LCT pegmatites of the Carolina Tin-Spodumene Belt (CTSB) situated in the Kings Mountain Shear Zone, which extends from South Carolina into North Carolina. The CTSB hosts both barren and fertile pegmatites, with Li-enriched pegmatites containing spodumene, K-feldspar, albite, quartz, muscovite, and beryl. We illustrate how handheld LIBS analysis can be used for real-time Li analysis in the field at a historically important CTSB pegmatite locality in Gaston County, N.C. in four contexts: (i) elemental detection and identification; (ii) microchemical mapping; (iii) depth profiling; and (iv) elemental quantitative analysis. Finally, as an example of a practical exploration application, we describe how handheld LIBS can be used to measure K/Rb ratios and Li contents of muscovite and rapidly determine the degree of pegmatite fractionation. This study demonstrates the potential of handheld LIBS to drastically reduce the time necessary to acquire geochemical data relevant to acquiring compositional information for pegmatites during a Li pegmatite exploration program.

Geopolymers and Fiber-Reinforced Concrete Composites in Civil Engineering

This paper discusses the influence of fiber reinforcement on the properties of geopolymer concrete composites, based on fly ash, ground granulated blast furnace slag and metakaolin. Traditional concrete composites are brittle in nature due to low tensile strength. The inclusion of fibrous material alters brittle behavior of concrete along with a significant improvement in mechanical properties i.e., toughness, strain and flexural strength. Ordinary Portland cement (OPC) is mainly used as a binding agent in concrete composites. However, current environmental awareness promotes the use of alternative binders i.e., geopolymers, to replace OPC because in OPC production, significant quantity of CO2 is released that creates environmental pollution. Geopolymer concrete composites have been characterized using a wide range of analytical tools including scanning electron microscopy (SEM) and elemental detection X-ray spectroscopy (EDX). Insight into the physicochemical behavior of geopolymers, their constituents and reinforcement with natural polymeric fibers for the making of concrete composites has been gained. Focus has been given to the use of sisal, jute, basalt and glass fibers.

Photocatalytic Behaviour of Zinc Oxide Nanostructures on Surface Activation of Polymeric Fibres

Zinc oxide (ZnO) in various nano forms (nanoparticles, nanorods, nanosheets, nanowires and nanoflowers) has received remarkable attention worldwide for its functional diversity in different fields i.e., paints, cosmetics, coatings, rubber and composites. The purpose of this article is to investigate the role of photocatalytic activity (role of photogenerated radical scavengers) of nano ZnO (nZnO) for the surface activation of polymeric natural fibres especially cotton and their combined effect in photocatalytic applications. Photocatalytic behaviour is a crucial property that enables nZnO as a potential and competitive candidate for commercial applications. The confirmed features of nZnO were characterised by different analytical tools, i.e., scanning electron microscopy (SEM), field emission SEM (FESEM) and elemental detection spectroscopy (EDX). These techniques confirm the size, morphology, structure, crystallinity, shape and dimensions of nZnO. The morphology and size play a crucial role in surface activation of polymeric fibres. In addition, synthesis methods, variables and some of the critical aspects of nZnO that significantly affect the photocatalytic activity are also discussed in detail. This paper delineates a vivid picture to new comers about the significance of nZnO in photocatalytic applications.

ATG3 Is Important for the Chorion Ultrastructure During Oogenesis in the Insect Vector Rhodnius prolixus

In insects, the last stage of the oogenesis is the choriogenesis, a process where the multiple layers of the chorion are synthesized, secreted, and deposited in the surface of the oocytes by the follicle cells. The chorion is an extracellular matrix that serves as a highly specialized protective shield for the embryo, being crucial to impair water loss and to allow gas exchange throughout development. The E2-like enzyme ATG3 (autophagy related gene 3) is known for its canonical function in the autophagy pathway, in the conjugation of the ubiquitin-like ATG8/LC3 to the membranes of autophagosomes. Although the ATGs were originally described and annotated as genes related to autophagy, additional functions have been attributed to various of these genes. Here, we found that Rhodnius prolixus ATG3 is highly expressed in the ovaries of the adult vitellogenic females. Parental RNAi depletion of ATG3 resulted in a 15% decrease in the oviposition rates of depleted females and in the generation of unviable eggs. ATG3-depleted eggs are small and present one specific phenotype of altered chorion ultrastructure, observed by high resolution scanning electron microscopy. The amounts of the major chorion proteins Rp30, Rp45, Rp100, and Rp200 were decreased in the ATG3-depleted chorions, as well as the readings for dityrosine cross-linking and sulfur, detected by fluorescence emission under ultraviolet excitation and X-ray elemental detection and mapping. Altogether, we found that ATG3 is important for the proper chorion biogenesis and, therefore, crucial for this vector reproduction.

Life history parameters in acellular extrinsic fiber cementum microstructure

Life-history parameters such as pregnancies, skeletal trauma, and renal disease have previously been identified from hypomineralized growth layers (incremental lines) of acellular extrinsic fiber cementum (AEFC). The precise periodicity of these growth layers remains vaguely approximated, so causal life-history explanations using tooth cementum cannot yet be rigorously calculated or tested. On the other hand, we show how life history parameters in AEFC can be identified by two contrasting elemental detection methods. Based on our results we reject the possibility of accurate estimation of pregnancies and other life history parameters from cementum using scanning electron microscopy alone. Here, we propose a new methodological approach for cementum research, Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS), to measure degree and distribution of mineralization of cementum growth layers. Our results show that Tof-SIMS can significantly increase our knowledge of cementum composition and is therefore a powerful new tool for life history researchers.

Combustion generated nanomaterials: online characterization via an ICP-MS based technique. Part II: resolving power for heterogeneous matrices

Elemental detection with high resolving power in the total particle size distribution.