Experimental Study on Shut-in-Time Optimization for Multi-Fractured Horizontal Wells in Shale Reservoirs

The optimization of shut-in-time in shale gas well is an important factor affecting the production of single well after volume fracturing. In this study, a new method for determining the optimal shut-in-time considering clay mineral content and ion diffusion concentration was proposed. First, a novel water spontaneous imbibition apparatus under the conditions of formation temperature and confining pressure was designed. Then, the water imbibition satuation of 15 shale samples from the Longmaxi Formation (LF) of the Sichuan Basin were measured to quantitatively evaluate the water imbibition ability and classify reservoir types. Finally, the salt ion concentration diffusion experiment was carried out to optimize the shut-in-time of different types of shale reservoirs. The experimental results shown that the clay mineral content was the key factor affecting water wettability of shale, the shale reservoirs can be divided into two types and the critical value of clay mineral content was about 40%. Based on the law of salt ion diffusion in shale, the initiation time of micro-fractures induced by shale hydration was about 10-15 days. Under the experimental conditions, the optimal shut-in time of type I shale reservoir and type II shale reservoir were about 20 days and 15 days respectively. The average daily gas production has increased from 15.6×104 m3/day to 25.1×104 m3/day. The study results can provide scientific basis for the optimization of flowback regime of shale gas resrvoirs.

EDFM-based Multi-Continuum Shale Gas Simulation with Low Velocity Non-Darcy Water Flow Effect

The exploitation of shale gas has attracted extensive attention in industry and academia. Multi-scale gas transportation mechanisms in matrix and fractures have been well studied. However, due to the presence of water originating from both fracking fluids and connate water, shale gas production is also greatly affected by water imbibition and flowback, of which the processes have not been thoroughly analyzed. This paper aims at presenting a comprehensive multi-continuum multi-component model to characterize the complicated shale gas flow behaviors as well as the impact of non-Darcy water flow on shale gas production. A two-phase numerical simulator is built up with multi-continuum settings. Shale matrix is split into organic and inorganic matters while natural and hydraulic fractures are modeled using an embedded discrete fracture model (EDFM). Fracture closure and elongation are modeled using a dynamic gridding approach. Different transportation mechanisms are considered to describe gas flow in shale, including Knudsen diffusion, ab/desorption, and convection. The low-velocity non-Darcy flow of water is used in inorganic pores to analyze the effect of water flow. A pre-stage model based on pumping history is simulated firstly before production starts. This serves as an initialization step to model fracking fluid imbibition and early-stage water flowback. This pre-stage simulation gives out more precise pressure and saturation profiles than the conventional non-equilibrium initialization method, especially in enhanced pore volumes and fractures. Based upon simulation results from the production period, Langmuir isotherm absorption has shown a massive impact on gas flow in shale, and Knudsen diffusion weights highest among transport mechanisms. Water non-Darcy flow better benefits in simulating both early-stage water flowback and production process compared with Darcy flow, which gives us a new explanation on the low flowback efficiency in real shale gas operations. Studies on early-stage water flowback also show that the flowback affects saturation distribution, which has a strong relationship with gas production and shall not be ignored. This work establishes a novel method to simulate and analyze shale gas production. It considers multiple and complex flow mechanisms and gives out better estimates of water flux. It is also used to initialize a model for pumping water imbibition and early-stage flowback, which can be used as technical resources for analyzing and simulating unconventional plays.

Aqueous Solution of Ketone For Enhanced Water Imbibition in Shale Reservoirs

This paper presents an experimental study of improved oil recovery from fractured shale cores by huff-n-puff of the aqueous solutions of 3-pentanone. The huff-n-puff experiments with different 3-pentanone concentrations were analyzed by the material balance for components: oil, brine, and 3-pentanone. Naturally sulfate-rich brine of low salinity was used as the injection brine. Results show that the 3-pentanone solution recovered more oil from the shale matrix than the injection brine alone. The oil recovery increased when the 3-pentanone concentration increased from 0.56-wt% to 2.85-wt%. Huff-n-puff with the 2.85-wt% 3-pentanone solution showed the highest improved oil recovery by 3-pentanone. However, the huff-n-puff experiment with the 1.07-wt% 3-pentanone solution showed the highest efficiency measured by the mass ratio of the produced oil to the injected 3-pentanone. That is, an optimal concentration of 3-pentanone appeared to exist. The material balance analysis showed that 3-pentanone was efficiently imbibed into the shale matrix, and that oil was recovered from shale mainly by the displacement by brine after the wettability alteration by 3-pentanone.

Inertial Effect on Spontaneous Oil-Water Imbibition by Molecular Kinetic Theory

Imbibition is one of the most common physical phenomena in nature, and it plays an important role in enhanced oil recovery, hydrology, and environmental engineering. For the tight reservoirs, the imbibition method has an obvious advantage in fracturing, shut-in, and huff-puff development. Although the current imbibition studies focus on oil recovery, and the inertial effect in imbibition is neglected and its mechanism is also unclear. In this paper, the inertial effect on spontaneous oil-water imbibition at micron-scale is studied by molecular kinetic theory (MKT). The frictional coefficient in the model is a fitted parameter to match the experimental data during the total imbibition process. Then, the simulation of the initial imbibition stage is conducted and the inertial effect on imbibition is identified by the difference between the model considering the inertial effect (CI) and the model neglecting the inertial effect (NI), or by the proportion of inertial force to the total resistance. Results show that (i) with an increase in the water phase viscosity, the inertial effect time shortens, maximum imbibition height and rate decrease, and thus the inertial effect on imbibition weakens; (ii) with an increase in the oil phase viscosity, the inertial effect time changes little, the maximum imbibition height and rate decrease slightly, namely, the inertial effect depends slightly on the oil phase. (iii) with an increase in the capillary wettability (hydrophilicity), the inertial effect time shortens, the maximum imbibition rate first increases and then decreases, and the inertial effect on imbibition weakens. This work sheds light on the inertial effect on oil-water imbibition by MKT, considering the effects of dynamic contact angle, water phase viscosity, oil phase viscosity, and wettabilities, which is helpful to understand the role of inertia in the oil-water or oil-fracturing fluid imbibition process.

Numerical Investigation of Oil–Water Exchange Behaviors in Shale During Post-Fracturing Soaking Periods

Fracturing fluid imbibition and retention are treated as a main mechanism for oil production from shale reservoirs. However, the oil–water exchange phenomenon during post-fracturing soaking periods has not been thoroughly studied. In this study, a water–oil flow model is built to investigate the water imbibition and oil drainage phenomenon in hydraulically fractured shale. With the developed numerical simulator, the main characteristics of post-fracturing soaking, that is, pressure diffusion, water imbibition, and especially, the oil–water exchange behavior are simulated. Three key time points, that is, oil–water exchange equilibrium, steady exchange efficiency, and oil breakthrough in fracture are found. The oil–water exchange efficiency and exchange volume are also calculated. Moreover, the proposed model is validated by field wellhead pressure dynamics, indicating a relevance of time between the oil–water exchange efficiency and the wellhead pressure falloff derivatives. Finally, the influences of shale permeability, wettability, fracture complexity, and oil viscosity on the oil–water exchange behavior are investigated. Results indicate that the matrix of oil-wet shale almost does not suck water and discharge oil, and only the oil in natural fractures exchanges with the water in hydraulic fractures. The water-wet shale with low permeability, high oil viscosity, and few natural fractures needs extra soaking time to achieve good oil–water exchange performance. The suitable soaking period for the water-wet base case in this study is from 17.25 to 169 days, among which 64 days is the optimal soaking time.

Glycine for Enhanced Water Imbibition in Carbonate Reservoirs – What is the Role of Amino Group?

Previous studies indicated the efficacy of the simplest amino acid, glycine, as an aqueous additive for enhanced water imbibition in carbonate reservoirs. The objective of this research was to investigate the importance of the amino group of glycine in its enhanced water imbibition. To this end, glycine was compared with two carboxylates (acetate and formate) with/without adding hydrogen chloride (HCl) for adjusting the solution pH. Note that the amino group is the only difference between glycine and acetate. Contact-angle experiments on calcite were carried out at 347 K and atmospheric pressure with 68000-ppm reservoir brine (RB), and 4 different concentrations of glycine, acetate, and formate solutions in RB. To test the hypothesis that calcite dissolution is one of the main mechanisms in wettability alteration by glycine, we performed another set of contact angle experiments by adding HCl to brine, acetate, and formate solutions. HCl was added to match the pH of the glycine solution at the same concentration. We also performed imbibition tests with Texas Cream Limestone cores at 347 K with brine, glycine, acetate, and formate solutions (with and without HCl) in RB at 5.0 wt%. Contact-angle results indicated that glycine changed calcite's wettability from oil-wet to water-wet (45°). However, acetate solution was not able to change the wettability to water-wet; and formate moderately decreased the contact angle to 80°. The pH level increased from 6.1 to 7.6 after the contact angle experiment in glycine solution, indicating the consumption of hydrogen ions due to calcite dissolution. The levels of pH in formate and acetate solutions, however, decreased from 8.4 to 7.8. The acidity of glycine above its isoelectric point arises from the deprotonation of the carboxyl group. Imbibition tests with carbonate cores supported the observations from the contact-angle experiments. The oil recovery was 31% for glycine solution, 20% for RB, 21% for formate solution, and 19% for acetate solution. This re-confirmed the effectiveness of glycine as an additive to improve the oil recovery from carbonates. An additional set of imbibition tests revealed that acetate at the pH reduced to the same level as glycine was still not able to recover as much oil as glycine. This showed that glycine recovered oil not only because of the calcite dissolution and the carboxyl group, but also because of the amino group. It is hypothesized that the amino group with its electron donor ability creates a chelation effect that makes glycine entropically more favorable to get attached to the calcite surface than acetate. Another important result is that the formate solution at an adjusted pH resulted in a greater oil recovery than RB or RB at the same pH. This indicates that there is an optimal pH for the carboxyl group to be effective in wettability alteration as also indicated by the pH change during the contact-angle experiment.