The control of the height and shape of the track in laser metal deposition by the QCW laser mode

The control of the track shape in laser metal deposition technology by the QCW laser mode has been studied. The different geometric characteristics of the tracks are shown to obtain at the same average laser power, depending on the selected laser power control mode. The difference in the temperature regimes of track formation is shown.

A Strategy for Achieving Smooth Filamentation Cutting of Transparent Materials with Ultrafast Lasers

A strategy is proposed for achieving a practically important mode of laser processing—a so-called “smooth” laser filamentation cutting (LFC) of transparent materials by a moving beam of a pulse-periodic pico- or subpicosecond laser. With such cutting, the surface of the sidewalls of the cuts have a significantly improved smoothness, and, as a result, the laser-cut plates have increased resistance to damage and cracking due to mechanical impacts during their subsequent use. According to the proposed analytical model, for the case when each filament is formed only by a single laser pulse, the strategy of such cutting is defined by a set of necessary conditions, whose implementation requires, in turn, a certain selection and matching with each other of irradiation parameters (pulse duration and energy, repetition rate, pitch of filaments following) and of material parameters—thermal, optical and mechanical strength constants. The model shows good agreement with experiments on sapphire and tempered glass. Besides, LFC modes are also predicted that provide very high cutting speeds of the order of 1–25 m/s or more, or allow cutting with an extremely low average laser power, but still at a speed acceptable for practical applications.

Micromachining of Invar Foils with GHz, MHz and kHz Femtosecond Burst Modes

In this work, a burst mode laser is used for micromachining of 20 µm–250 µm thick Invar (Fe64/Ni36) foils. Holes were drilled by firing multiple pulses transversely onto the sample without moving the beam (percussion drilling). The utilized laser system generates a burst of a controllable number of pulses (at 1030 nm) with tunable pulse-to-pulse time spacing ranging from 200 ps to 16 ns. The sub-pulses within the burst have equal amplitudes and a constant duration of 300 fs that do not change regardless of the spacing in time between them. In such a way, the laser generates GHz to MHz repetition rate pulse bursts with a burst repetition rate ranging from 100 kHz to a single shot. Drilling of the material is compared with the non-burst mode of kHz repetition rate. In addition, we analyze the drilling speed and the resulting dependence of the quality of the holes on the number of pulses per burst as well as the average laser power to find the optimal micromachining parameters for percussion drilling. We demonstrate that the micromachining throughput can be of an order of magnitude higher when using the burst mode as compared to the best results of the conventional kHz case; however, excess thermal damage was also evident in some cases.

Effects of Laser Ablation Parameters to Pattern High Purity Magnesium Surfaces

Magnesium and magnesium-based alloys have relatively low weight and desirable mechanical properties for many applications in multiple industries including aerospace and automotive. In the past decade, due to its biocompatible nature, the medical field has expressed significant interest in magnesium for biodegradable implant applications. However, utilization of magnesium-based alloys in surgical implant applications is strictly limited by magnesium’s high vulnerability to corrosion causing premature disintegration inside the human body. Hydrophobic (non-wetting) behavior of metal surfaces has been proven to be beneficial for corrosion protection in academic literature. One way of achieving hydrophobic and super-hydrophobic surfaces on metal surfaces without using non-biocompatible coatings is creating uniform microstructures that would alter the wetting characteristics of the surface. This work focuses on creating uniform pillar shaped micro-patterns on smooth pure magnesium surfaces by utilizing a picosecond laser (λ = 355 nm). The study reports the effects of average laser power, partial laser beam overlap and number of laser scans on the height, steepness, roughness of the resultant micro-pillars. Information gathered from this study could be useful in creating more complex or finer micro-structures on magnesium and its alloys to alter their wetting or corrosion characteristics using laser ablation which is a fast, repeatable and an un-convoluted process.

Laser-slicing at a low-emittance storage ring

Laser-slicing at a diffraction-limited storage ring light source in the soft X-ray region is investigated with theoretical and numerical modelling. It turns out that the slicing efficiency is favoured by the ultra-low beam emittance, and that slicing can be implemented without interference to the standard multi-bunch operation. Spatial and spectral separation of the sub-picosecond radiation pulse from a hundreds of picosecond-long background is achieved by virtue of 1:1 imaging of the radiation source. The spectral separation is enhanced when the radiator is a transverse gradient undulator. The proposed configuration applied to the Elettra 2.0 six-bend achromatic lattice envisages total slicing efficiency as high as 10−7, one order of magnitude larger than the demonstrated state-of-the-art, at the expense of pulse durations as long as 0.4 ps FWHM and average laser power as high as ∼40 W.

Orthogonal Functionalization of Nanodiamond Particles after Laser Modification and Treatment with Aromatic Amine Derivatives

A laser system with a wavelength of 1064 nm was used to generate sp2 carbon on the surfaces of nanodiamond particles (NDPs). The modified by microplasma NDPs were analysed using FT-IR and Raman spectroscopy. Raman spectra confirmed that graphitization had occurred on the surfaces of the NDPs. The extent of graphitization depended on the average power used in the laser treatment process. FT-IR analysis revealed that the presence of C=C bonds in all spectra of the laser-modified powder. The characteristic peaks for olefinic bonds were much more intense than in the case of untreated powder and grew in intensity as the average laser power increased. The olefinized nanodiamond powder was further functionalized using aromatic amines via in situ generated diazonium salts. It was also found that isokinetic mixtures of structurally diverse aromatic amines containing different functional groups (acid, amine) could be used to functionalize the surfaces of the laser-modified nanoparticles leading to an amphiphilic carbon nanomaterial. This enables one-step orthogonal functionalization and opens the possibility of selectively incorporating molecules with diverse biological activities on the surfaces of NDPs. Modified NDPs with amphiphilic properties resulting from the presence carboxyl and amine groups were used to incorporate simultaneously folic acid (FA-CONH-(CH2)5-COOH) and 5(6)-carboxyfluorescein (FL-CONH-(CH2)2-NH2) derivatives on the surface of material under biocompatible procedures.

Characterisation of Pulsed-Fibre-Laser-Perforated Polymeric Food Package Films

A packaging material requires a proper interaction with regard to water vapour transmission between the product and the outside environment. For many fresh food products such as bakery goods, fruits, and vegetables, microperforation is utilised to extend the shelf life of the foodstuff and to provide better food quality. The microperforation potential of five commercial polymeric films has been evaluated using a pulsed fibre laser technique, and significant differences were found between the films in the penetration of the laser beam and in the diameter of the perforation. Breathable polymeric packaging films were prepared with an average laser power of 20 W and a pulse duration of 200 ns. The numbers of holes (80 μm in diameter) in the films were approx. 2000 holes/m2 and 4000 holes/m2. As expected, the number of perforations affected the water vapour transmission (WVT): the WVT was 11 g/m2/d for unperforated film, and 60 g/m2/d for the film with 4000 holes/m2, indicating that the fibre laser can be used successfully for microperforating this type of polymeric films. However, microscopic and microtomographic analyses revealed major differences in hole formation behaviour and in the wall structures of the microperforations.

Sensitivity studies for a space-based methane lidar mission

Methane is the third most important greenhouse gas in the atmosphere after water vapour and carbon dioxide. A major handicap to quantify the emissions at the Earth's surface in order to better understand biosphere-atmosphere exchange processes and potential climate feedbacks is the lack of accurate and global observations of methane. Space-based integrated path differential absorption (IPDA) lidar has potential to fill this gap, and a Methane Remote Lidar Mission (MERLIN) on a small satellite in polar orbit was proposed by DLR and CNES in the frame of a German-French climate monitoring initiative. System simulations are used to identify key performance parameters and to find an advantageous instrument configuration, given the environmental, technological, and budget constraints. The sensitivity studies use representative averages of the atmospheric and surface state to estimate the measurement precision, i.e. the random uncertainty due to instrument noise. Key performance parameters for MERLIN are average laser power, telescope size, orbit height, surface reflectance, and detector noise. A modest-size lidar instrument with 0.45 W average laser power and 0.55 m telescope diameter on a 506 km orbit could provide 50-km averaged methane column measurement along the sub-satellite track with a precision of about 1% over vegetation. The use of a methane absorption trough at 1.65 μm improves the near-surface measurement sensitivity and vastly relaxes the wavelength stability requirement that was identified as one of the major technological risks in the pre-phase A studies for A-SCOPE, a space-based IPDA lidar for carbon dioxide at the European Space Agency. Minimal humidity and temperature sensitivity at this wavelength position will enable accurate measurements in tropical wetlands, key regions with largely uncertain methane emissions. In contrast to actual passive remote sensors, measurements in Polar Regions will be possible and biases due to aerosol layers and thin ice clouds will be minimised.