Laboratory Measurements of Zeta Potential in Fractured Lewisian Gneiss: Implications for the Characterization of Flow in Fractured Crystalline Bedrock

Despite the broad range of interest and possible applications, the controls on the electric surface charge and the zeta potential of gneiss at conditions relevant to naturally fractured systems remain unreported. There are no published zeta potential measurements conducted in such systems at equilibrium, hence, the effects of composition, concentration and pressure remain unknown. This study reports zeta potential values for the first time measured in a fractured Lewisian gneiss sample saturated with NaCl solutions of various concentrations, artificial seawater and artificial groundwater solutions under equilibrium conditions at confining pressures of 4 MPa and 7 MPa. The constituent minerals of the sample were identified using X-ray diffraction and linked to the concentration and composition dependence of the zeta potential. The results reported in this study demonstrate that the zeta potential remained negative for all tested solutions and concentrations. However, the values of the zeta potential of our Lewisian gneiss sample were found to be unique and dissimilar to pure minerals such as quartz, calcite, mica or feldspar. Moreover, the measured zeta potentials were smaller in magnitude in the experiments with artificial complex solutions compared with those measured with NaCl, thus suggesting that divalent ions (Ca2+, Mg2+ and SO42−) acted as potential determining ions. The zeta potential was also found to be independent of salinity in the NaCl experiments, which is unusual for most reported data. We also investigated the impact of fracture aperture on the electrokinetic response and found that surface electrical conductivity remained negligibly small across the range of the tested confining pressures. Our novel results are an essential first step for interpreting field self-potential (SP) signals and facilitate a way forward for characterization of water flow through fractured basement aquifers.

A conceptual geological model for offshore wind sites in palaeo ice stream settings: The Utsira Nord site, North Sea

Conceptual geological models of the shallow subsurface which integrate geological and geotechnical information are important for more strategic data acquisition and engineering at offshore wind sites. Utsira Nord is an offshore wind site in the Norwegian North Sea. It covers an area of 23 km x 43 km within the Norwegian Channel palaeo ice stream, with an average water depth of 267 m making the site a candidate for floating offshore wind. The goal of this study is to present a preliminary conceptual geological model for the site, which combines an overview of previous knowledge about the complex ice streaming history of the Norwegian Channel with key observations from high resolution bathymetric data, 2D acoustic data, and shallow cores. Despite limited data, four geotechnical provinces can be defined: 1) exposed glacimarine to marine sediments, 2) buried to exposed subglacial traction till, 3) buried lodgment till and 4) shallowly buried to exposed crystalline bedrock. The model serves as a basis for planning site surveys at Utsira Nord and as a reference for offshore wind sites on other formerly glaciated coasts where palaeo ice stream systems are common, such as the northern coastlines of the United States and the United Kingdom.

Evidence for a Northern Hemispheric trigger of the 100,000-y glacial cyclicity

The causes of the Mid-Pleistocene Transition, the shift from ∼41-ky to 100-ky interglacial–glacial cycles and more intense ice ages, remain intensely debated, as this fundamental change occurred between ∼1,250 and 650 ka without substantial changes in astronomical climate forcings. Recent studies disagree about the relative importance of events and processes in the Northern and Southern Hemispheres, as well as whether the shift occurred gradually over several interglacial–glacial cycles or abruptly at ∼900 ka. We address these issues using a north-to-south reconstruction of the Atlantic arm of the global meridional overturning ocean circulation, a primary means for distributing heat around the globe, using neodymium (Nd) isotopes. Results reveal a period of intense erosion affecting the cratonic shields surrounding the North Atlantic between Marine Isotope Stages (MIS) 27 and 25 (∼980 and 950 ka), reflected by unusually low Nd isotope ratios in deep North Atlantic seawater. This episode preceded a major ocean circulation weakening between MIS 25 and 21 (950 and 860 ka) that coincided with the first ∼100-ky-long interglacial–glacial onset of Northern Hemisphere glaciation at around 2.4 to 2.8 Ma. The data point to a Northern Hemisphere–sourced initiation for the transition, possibly induced through regolith loss and increased exposure of the crystalline bedrock, which would lead to increased friction, enabling larger ice sheets that are characteristic of the 100-ky interglacial–glacial cycles.

Geomorphology and shallow sub-sea floor structures underneath the Ekström Ice Shelf, Antarctica

The Ekström Ice Shelf is one of numerous small ice shelves that fringe the coastline of western Dronning Maud Land, East Antarctica. Reconstructions of past ice-sheet extent in this area are poorly constrained, due to a lack of geomorphological evidence. Here, we present a compilation of geophysical surveys in front of and beneath the Ekström Ice Shelf, to identify and interpret evidence of past ice sheet flow, extent and retreat. The sea floor beneath the Ekström Ice Shelf is dominated by an incised trough, which extends from the modern day grounding line on to the continental shelf. Our surveys show that Mega-Scale Glacial Lineations cover most of the mouth of this trough, terminating 11 km away from the continental shelf break, indicating the most recent maximal extent of grounded ice in this region. Beneath the front ~30 km of the ice shelf, the sea floor is characterised by an acoustically transparent sedimentary unit, up to 45 m-thick. This is likely composed of subglacial till, further corroborating the presence of past grounded ice cover. Further inland, the sea floor becomes rougher, interpreted as a transition from subglacial tills to a crystalline bedrock, corresponding to the outcrop of the volcanic Explora Wedge at the sea floor. Ice retreat in this region appears to have happened rapidly in the centre of the incised trough, evidenced by a lack of overprinting of the lineations at the trough mouth. At the margins of the trough uniformly spaced recessional moraines suggest ice retreated more gradually. We estimate the palaeo-ice thickness at the calving front around the Last Glacial Maximum to have been at least 305 m to 320 m, based on the depth of iceberg ploughmarks within the trough and sea-level reconstructions. Given the similarity of the numerous small ice shelves around the Dronning Maud Land coast, these findings are likely representative for other ice shelves in this region and provide essential boundary conditions for palaeo ice-sheet models in this severely understudied region.

Review: Saltwater intrusion in fractured crystalline bedrock

During the past few years, the number of regional and national assessments of groundwater quality in regard to saltwater intrusion in coastal aquifers has increased steadily. However, most of the international literature on saltwater intrusion is focused on coastal plains with aquifers in unconsolidated material. Case studies, modelling approaches and parameter studies dealing with saltwater intrusion in those systems are abundant. While the hydrogeology of fractured rock has been intensively studied with both modelling approaches and parameter studies—mainly in relation to deep-laying fractured crystalline bedrock as potential waste repositories—case studies on saltwater intrusion in shallow fractured rocks are still an exception. This review summarizes the actual knowledge on saltwater intrusion in fractured crystalline rock. In combination with short overviews of the processes of saltwater intrusion, flow in fractured systems and the genesis of these systems, the review highlights the importance of the fracture systems and its specific characteristics. Fracture properties are a direct consequence of the geological history as well as the current situation of the coastal area. A holistic assessment of water quality in coastal areas hosting fractured crystalline bedrock therefore requires the combination of different approaches in order to investigate the impact of saltwater intrusion through the fractured system.

Glacial Erosion Rates Determined at Vorab Glacier: Implications for the Evolution of Limestone Plateaus

Understanding how fast glaciers erode their bedrock substrate is one of the key elements in reconstructing how the action of glaciers gives mountain ranges their shape. By combining cosmogenic nuclide concentrations determined in glacially abraded bedrock with a numerical model, we quantify glacial erosion rates over the last 15 ka. We measured cosmogenic 36Cl in fourteen samples from the limestone forefield of the Vorab glacier (Eastern Alps, Switzerland). Determined glacial erosion rates range from 0.01 mm a−1 to 0.16 mm a−1. These glacial abrasion rates differ quite markedly from rates measured on crystalline bedrock (>1 mm a−1), but are similarly low to the rates determined on the only examined limestone plateau so far, the Tsanfleuron glacier forefield. Our data, congruent with field observations, suggest that the Vorab glacier planed off crystalline rock (Permian Verrucano) overlying the Glarus thrust. Upon reaching the underlying strongly karstified limestone the glacier virtually stopped eroding its bed. We attribute this to immediate drainage of meltwater into the karst passages below the glacier, which inhibits sliding. The determined glacial erosion rates underscore the relationship between geology and the resulting landscape that evolves, whether high elevation plateaus in limestone terrains or steep-walled valleys in granitic/gneissic areas.

Active anaerobic methane oxidation and sulfur disproportionation in the deep terrestrial subsurface

Microbial life is widespread in the terrestrial subsurface and present down to several kilometers depth, but the energy sources that fuel metabolism in deep oligotrophic and anoxic environments remain unclear. In the deep crystalline bedrock of the Fennoscandian Shield at Olkiluoto, Finland, opposing gradients of abiotic methane and ancient seawater-derived sulfate create a terrestrial sulfate-methane transition zone (SMTZ). We used chemical and isotopic data coupled to genome-resolved metaproteogenomics to demonstrate active life and, for the first time, provide direct evidence of active anaerobic oxidation of methane (AOM) in a deep terrestrial bedrock. Proteins from Methanoperedens (formerly ANME-2d) are readily identifiable despite the low abundance (≤1%) of this genus and confirm the occurrence of AOM. This finding is supported by 13C-depleted dissolved inorganic carbon. Proteins from Desulfocapsaceae and Desulfurivibrionaceae, in addition to 34S-enriched sulfate, suggest that these organisms use inorganic sulfur compounds as both electron donor and acceptor. Zerovalent sulfur in the groundwater may derive from abiotic rock interactions, or from a non-obligate syntrophy with Methanoperedens, potentially linking methane and sulfur cycles in Olkiluoto groundwater. Finally, putative episymbionts from the candidate phyla radiation (CPR) and DPANN archaea represented a significant diversity in the groundwater (26/84 genomes) with roles in sulfur and carbon cycling. Our results highlight AOM and sulfur disproportionation as active metabolisms and show that methane and sulfur fuel microbial activity in the deep terrestrial subsurface.Significance StatementThe deep terrestrial subsurface remains an environment in which there is limited understanding of the extant microbial metabolisms, despite its reported large contribution to the overall biomass on Earth. It is much less well studied than deep marine sediments. We show that microorganisms in the subsurface are active, and that methane and sulfur provide fuel in the oligotrophic and anoxic subsurface. We also uncover taxonomically and metabolically diverse ultra-small organisms that interact with larger host cells through surface attachment (episymbiosis). Methane and sulfur are commonly reported in terrestrial crystalline bedrock environments worldwide and the latter cover a significant proportion of the Earth’s surface. Thus, methane- and sulfur-dependent microbial metabolisms have the potential to be widespread in the terrestrial deep biosphere.

Multidisciplinary Approaches for Assessing a High Temperature Borehole Thermal Energy Storage Facility at Linköping, Sweden

Assessing the optimal placement and design of a large-scale high temperature energy storage system in crystalline bedrock is a challenging task. This study applies and evaluates various methods and strategies for pre-site investigation for a potential high temperature borehole thermal energy storage (HT-BTES) system at Linköping in Sweden. The storage is required to shift approximately 70 GWh of excess heat generated from a waste incineration plant during the summer to the winter season. Ideally, the site for the HT-BTES system should be able to accommodate up to 1400 wells to 300 m depth. The presence of major fracture zones, high groundwater flow, anisotropic thermal properties, and thick Quaternary overburden are all factors that play an important role in the performance of an HT-BTES system. Inadequate input data to the modeling and design increases the risk of unsatisfactory performance, unwanted thermal impact on the surroundings, and suboptimal placement of the HT-BTES system, especially in a complex crystalline bedrock setting. Hence, it is crucial that the subsurface geological conditions and associated thermal properties are suitably characterized as part of pre-investigation work. In this study, we utilize a range of methods for pre-site investigation in the greater Distorp area, in the vicinity of Linköping. Ground geophysical methods, including magnetic and Very Low-Frequency (VLF) measurements, are collected across the study area together with outcrop observations and lab analysis on rock samples. Borehole investigations are conducted, including Thermal Response Test (TRT) and Distributed Thermal Response Test (DTRT) measurements, as well as geophysical wireline logging. Drone-based photogrammetry is also applied to characterize the fracture distribution and orientation in outcrops. In the case of the Distorp site, these methods have proven to give useful information to optimize the placement of the HT-BTES system and to inform design and modeling work. Furthermore, many of the methods applied in the study have proven to require only a fraction of the resources required to drill a single well, and hence, can be considered relatively efficient.