Effects of temperature and thermal cycles on the mechanical properties of expanded polystyrene foam

Understanding the effects of high temperature and thermal cycles on the mechanical properties of expanded polystyrene (EPS) foam is critical for its use in sandwich panels. This paper presents an experimental investigation of these effects in typical environmental conditions that exist in construction applications. A total of 117 small specimens were cut from metal-faced sandwich panels with EPS core and were exposed to different numbers of thermal cycles and/or sustained high temperatures. The specimens were then loaded under compression, tension, and four-point bending for evaluating the degradation of the mechanical properties of the foam. The thermal cycles reflect typical surface temperature during daily summer conditions, with a period of 24 h each and with a temperature varying between 24°C to 80°C. The results show that the modulus of elasticity of EPS foam in compression reduced by about 38% after exposure to thermal cycles for 45 days, whereas the tensile and shear moduli reduced by about 5.7% and 13.8%, respectively. Exposure to sustained high temperature after thermal cycles led to larger degradation of the elastic and shear moduli in the range of 38%–50%. These degradations can lead to early failures in applications that rely on the EPS foam as a structural component like in insulating sandwich panels.

Improvised centrifugal spinning for the production of polystyrene microfibers from waste expanded polystyrene foam and its potential application for oil adsorption

A straightforward approach to recycle waste expanded polystyrene (EPS) foam to produce polystyrene (PS) microfibers using the improvised centrifugal spinning technique is demonstrated in this work. A typical benchtop centrifuge was improvised and used as a centrifugal spinning device. The obtained PS microfibers were characterized for their potential application for oil adsorption. Fourier transform infrared spectroscopy results revealed similarity on the transmission bands of EPS foam and PS microfibers suggesting the preservation of the EPS foam’s chemical composition after the centrifugal spinning process. Scanning electron microscopy displayed well-defined fibers with an average diameter of 3.14 ± 0.59 μm. At the same time, energy dispersive X-ray spectroscopy revealed the presence of carbon and oxygen as the primary components of the fibers. Contact angle (θCA) measurements showed the more enhanced hydrophobicity of the PS microfiber (θCA = 100.2 ± 1.3°) compared to the untreated EPS foam (θCA = 92.9 ± 3.5°). The PS microfiber also displayed better oleophilicity compared to EPS foam. Finally, the fabricated PS microfibers demonstrated promising potential for oil removal in water with a calculated sorption capacity value of about 15.5 g/g even at a very short contact time. The fabricated PS fiber from the waste EPS foam may provide valuable insights into the valorization of polymeric waste materials for environmental and other related applications.

Synthesis and Characterization of Polystyrene Sulfonic Acid from Expanded Polystyrene Foam as a Catalyst in the Synthesis of Triacetin

In Indonesia, the composition of waste has gradually changed over time. To reduce expanded polystyrene (EPS) foam waste, we converted it into a heterogeneous acid catalyst, namely Polystyrene Sulfonic Acid (PSSA). The catalyst was then used in an esterification reaction to generate triacetin. In this research, the synthesis of PSSA was performed using a sulfonation reaction with silver sulfate (Ag2SO4) as the catalyst. Based on FTIR analysis, the sulfonation reaction was successful. The use of 0.5% and 1% catalysts led to a significant increase in the degree of sulfonation of PSSA, while there was a relatively constant increase when using 1.5–2.5% catalysts. The highest degree of sulfonation (78.63%) was achieved when the reaction was performed using 2% Ag2SO4 catalyst for 25 min. The PSSA with the highest degree of sulfonation was characterized using X-Ray Diffraction (XRD), SEM-EDX, and BET-BJH. This PSSA had a semi-crystalline structure with a crystallinity of 73.83%, a particle size of 1.75 nm, mesoporous pores with a radius of 16.984 Å, and a sulfur content of 15% (% mass).

Resistance of ETICS with Fire Barriers to Cyclic Hygrothermal Impact

The article presents the results of a set of hygrothermal experiments of an external wall insulated with an ETICS. As an add-on to previous studies, thermal insulation in the form of polystyrene with an additional horizontal strip of mineral wool was used. Laboratory tests were carried out in accordance with ETAG 004. The ETICS test rig was composed of combustible expanded polystyrene foam (EPS) and horizontal strips of noncombustible mineral wool (MW) fire barriers over windows. The physical and mechanical properties of four types of finishing renders (without an additional reinforcement mesh in base coat of the fire barriers) were analyzed across full hygrothermal cycles in a climate chamber. Temperature sensors were mounted onto different ETICS layers to collect thermal data during the weathering. The testing of ETICS regarding their hygrothermal performance revealed that there were no visible defects on any renderings and over the junctions depending on the type of used insulation materials. Results also showed that the joints of EPS and MW have approximately half of their bond strength from polystyrene strength.

A machine learning approach to estimate the strain energy absorption in expanded polystyrene foams

Traditional modeling of mechanical energy absorption due to compressive loadings in expanded polystyrene foams involves mathematical descriptions that are derived from stress/strain continuum mechanics models. Nevertheless, most of those models are either constrained using the strain as the only variable to work at large deformation regimes and usually neglect important parameters for energy absorption properties such as the material density or the rate of the applying load. This work presents a neural-network-based approach that produces models that are capable to map the compressive stress response and energy absorption parameters of an expanded polystyrene foam by considering its deformation, compressive loading rates, and different densities. The models are trained with ground-truth data obtained in compressive tests. Two methods to select neural network architectures are also presented, one of which is based on a Design of Experiments strategy. The results show that it is possible to obtain a single artificial neural networks model that can abstract stress and energy absorption solution spaces for the conditions studied in the material. Additionally, such a model is compared with a phenomenological model, and the results show than the neural network model outperforms it in terms of prediction capabilities, since errors around 2% of experimental data were obtained. In this sense, it is demonstrated that by following the presented approach is possible to obtain a model capable to reproduce compressive polystyrene foam stress/strain data, and consequently, to simulate its energy absorption parameters.

Synthesis and Simulation of Nano-Composite Metamaterial for Broadband Negative Refractive Index in Visible Spectral Regime

In this paper, a nano-metamaterial with the structure of Ag-SiO2-PbTe is proposed that has a random arrangement in the host medium of expanded polystyrene (foam) for the realization of a broadband negative refractive index at the visible spectrum. The negative refractive index for the purposed meta-material was obtained from the plasmonic resonance in the core and outer layer for both electric and magnetic components of light. Here, we use different radii for the outer layer of nanoparticles to create the broadband negative permeability. In this way, the doped semiconductor nanoparticles are included in the host medium to create the broadband negative permittivity. The overlap between the spectrum of the negative permittivity and permeability introduces the broadband negative refractive index at the visible band. The novel introduced structure creates the broadband negative refractive index and it is simple and practical for fabrication. For the realization of the proposed material, synthesis and characterization of the designed nanocomposite structure are investigated. To this end, the absorption and the transmission coefficients of the synthesized material are measured and compared with theoretical results. The obtained results indicate that the numerical simulations using Mie theory have good agreement with the experimental results.

Solar drying of residue from Brazil nut processing

Brazil nuts are often used for direct consumption or in the preparation process of water-soluble extract. After obtaining the water-soluble extract, a large amount of Brazil nut residues with good sensory characteristics are generated. Thus, this study aimed to dry Brazil nut processing residues in layers with different thicknesses in a direct solar dryer as well as by direct exposure to the sun, in order to fit different mathematical models to the experimental data of drying kinetics, and calculate the drying rates and effective diffusivity. The drying procedures began at 9 a.m. on a concrete base, for samples dried by direct exposure to the sun, and in a solar dryer constructed with expanded polystyrene foam zinc plated and a glass cover. The mass loss of the samples was monitored by weighing at regular times until the hygroscopic equilibrium was obtained. The direct solar dryer had temperatures about 80% higher than those recorded in the open environmental air temperature. Drying rates were higher in dehydrations performed in the solar dryer compared to the drying by exposure to the sun. The Midilli model was selected as the most adequate for predicting the drying of the samples under all experimental conditions, showing coefficients of determination above 0.99. The effective diffusion coefficients of moisture were higher in samples dehydrated in the solar dryer when compared to those dried by exposure to the sun. Regarding the research conducted under the experimental conditions of this study, the performance of the solar dryer to dry Brazil nut processing residues was satisfactory.

Development and Mechanical Testing of Porous-Lightweight Geopolymer Mortar

In this study, a novel porous geopolymer mortar (GP) was produced and tested experimentally. Industrial waste materials/by-products were used as constituents of the GP, along with dune sand. One sample was produced as a control sample for benchmarking. For the rest of the samples, 15%, 30%, and 45% by volume, the solid constituents were replaced with expanded polystyrene foam (EPS) beads. These mortar samples were heat cured to depolymerize the EPS to cause porosity inside the samples. Indoor experiments were conducted to evaluate the response of produced porous GP to high heat flux. The porous samples were able to reduce heat transmission across the opposite surfaces. Induced porosity resulted in a decrement in compressive strength from 77.2 MPa for the control sample to 15.8 MPa for 45% porous sample. However, the limit lies within the standards for partitioning walls in buildings and pavements in urban areas to absorb rainwater.

Structural Performance of Shear Loaded Precast EPS-Foam Concrete Half-Shaped Slabs

Precast concrete elements provide a feasible way to expedite on-site construction; however, typical precast components are massive, making their use particularly undesirable at construction sites that suffer from low load-bearing capacity or have swelling soils. This research aims to develop an optimal lightweight expanded polystyrene foam concrete (EPS-foam concrete) slab through a consideration of various parameters. The precast EPS-foam concrete half-shaped slabs were prepared with a density and compressive strength of 1980 kg/m3 and 35 MPa, respectively. Quarry dust (QD) and EPS beads were utilized as substitutions for fine and coarse aggregates with replacement-levels that varied from 5% to 22.5% and 15% to 30%, respectively. The use of EPS beads revealed sufficient early age strength; at the same time, the utilization of quarry dust in EPS-foam concrete led to a more than 30% increase in compressive strength compared to the EPS-based mixtures. Two hundred and fifty-six trial mixes were produced to examine the physical and mechanical characteristics of EPS-foam concrete. Three batches of a total of four EPS-foam concrete half-shaped slabs with spans of 3.5 and 4.5 m and thicknesses of 200 and 250 mm were prepared. Findings showed that the ultimate shear forces for the full-scale EPS-foam concrete half-shaped slabs were approximately 6–12% lower than those of the identical concrete samples with a 2410 kg/m3 average density, and 26–32% higher than the theoretical predictions. Also, it was observed that the self-weight of EPS-foam concrete was reduced by up to 20% compared to the control mixtures. Findings revealed that the prepared precast EPS-foam concrete half-shaped slabs could possibly be applied as flooring elements in today’s modern infrastructure.

Development and Mechanical Testing of Porous-Lightweight Geopolymer Mortar

In this study, a novel porous geopolymer mortar (GP) was produced and tested experimentally. Industrial waste materials/by-products were used as constituents of the GP, along with dune sand. One sample was produced as a control sample for benchmarking. For the rest of the samples, 15%, 30%, and 45% by volume, the solid constituents were replaced with expanded polystyrene foam (EPS) beads. These mortar samples were heat cured to depolymerize the EPS to cause porosity inside the samples. Indoor experiments were conducted to evaluate the response of produced porous GP to high heat flux. The porous samples were able to reduce heat transmission across the opposite surfaces. Induced porosity resulted in a decrement in compressive strength from 77.2 MPa for the control sample to 15.8 MPa for 45% porous sample. However, the limit lies within the standards for partitioning walls in buildings and pavements in urban areas to absorb rainwater.