The object of research is the structure of flows in the absorber of hydrogen chloride. One of the most problematic areas in the study of flow hydrodynamics in chemical-technological devices are both technological and technical difficulties, when the device is exposed to random disturbances and/or the supply of a standard indicator is impossible due to a violation of the technological regulations.
A method for studying the hydrodynamic structure of flows in a shelf absorber of hydrogen chloride of the «Korobon-KA» type (Germany) in the normal operation of a chemical apparatus using the theory of random functions is proposed. An industrial experiment was carried out on the operating equipment to determine the input and output concentrations of the components of the gas flow. The absorber of hydrogen chloride is considered as a one-dimensional object, at the input of which a random function acts – the concentration of hydrogen chloride in the input stream, and at the output there is a random variable – the concentration of hydrogen chloride in the output stream. The method for determining hydrogen chloride and chlorine in a gas stream is based on the absorption of chlorine by a solution of potassium iodide, followed by titration of the released iodine with sodium thiosulfate. In parallel, portions of acid were sampled at the inlet and outlet, and then the density and temperature of the hydrochloric acid solutions were determined.
An algorithm for calculating the impulse function estimates is developed. The obtained experimental data are smoothed. As a result of processing the experimental data, autocorrelation and cross-correlation functions were obtained, the Wiener-Hopf equation was solved, and the impulse weight function was obtained. Having calculated the moments of the obtained impulse weight function, it was proved that the structure of flows in the «Korobon-KA» absorber can be satisfactorily described by the ideal displacement model. The calculations were carried out in software environments MathCAD, Matlab.
According to the results obtained, the proposed method for determining the hydrodynamic structure of flows will find application in the study of chemical-technological devices, when the object is exposed to random disturbances and the supply of a standard indicator is impossible due to violation of technological regulations. This makes it possible to find the parameters of flow hydrodynamics in the apparatus in the mode of its normal operation.