Model Prediction of Critical Gas Rate with Water-Cut Reversal Effect

Accurate prediction of gas critical rate is critical to the successful management of gas wells. This paper covers the prediction of gas critical rate and presents limitations of old models with gas condensate wells with water-cut reversal. Comparison of prediction methods or models with this new method will be explained using field data of condensate wells. The effect and relation of water-cut with critical gas rate determination will be presented and the best method that universally meets changing conditions of the well will be tested with field data. Any method that must be acceptable must meet the dynamics of the well. No static model can predict accurately a dynamic well and reservoir performance. The old models of critical gas rate prediction show a static outlook, probably see the beginning of the well-life and cannot predict correctly when the fluid phases change in gravity. The late life prediction of the well performance is much more critical than the early life when the well has sufficient energy. The production envelope is more critical at depletion than at when the reservoir energy just kick. Therefore, any model prediction must be dynamic. The results from the old models show that they fail the dynamic test of the well performance. This limitation makes those model unusable in a late life of the well when water cut increases. This study has revealed a method or a model for critical rate prediction that is accurate throughout the life of the well. The effect of water cut reversal is well tracked with this new model whereas the static nature of other models predicts a wrong minimum rate at a liquid load up rate. The field data reveals that the dynamic nature of well and reservoir performance can only be understood dynamically.

Model Prediction of Critical Gas Rate With Water-Cut Reversal Effect

Accurate prediction of gas critical rate is critical to the successful management of gas wells. This paper covers the prediction of gas critical rate and presents limitations of old models with gas condensate wells with water-cut reversal. Comparison of prediction methods or models with this new method will be explained using field data of condensate wells. The effect and relation of water-cut with critical gas rate determination will be presented and the best method that universally meets changing conditions of the well will be tested with field data. Any method that must be acceptable must meet the dynamics of the well. No static model can predict accurately a dynamic well and reservoir performance. The old models of critical gas rate prediction show a static outlook, probably see the beginning of the well-life and cannot predict correctly when the fluid phases change in gravity. The late life prediction of the well performance is much more critical than the early life when the well has sufficient energy. The production envelope is more critical at depletion than at when the reservoir energy just kick. Therefore, any model prediction must be dynamic. The results from the old models show that they fail the dynamic test of the well performance. This limitation makes those model unusable in a late life of the well when water cut increases. This study has revealed a method or a model for critical rate prediction that is accurate throughout the life of the well. The effect of water cut reversal is well tracked with this new model whereas the static nature of other models predicts a wrong minimum rate at a liquid load up rate. The field data reveals that the dynamic nature of well and reservoir performance can only be understood dynamically.

Neighborhood Relationships of Widely Distributed and Irregularly Shaped Particles in Partially Dewatered Filter Cakes

A more thorough understanding of the properties of bulk material structures in solid–liquid separation processes is essential to understand better and optimize industrially established processes, such as cake filtration, whose process outcome is mainly dependent on the properties of the bulk material structure. Here, changes of bulk properties like porosity and permeability can originate from local variations in particle size, especially for non-spherical particles. In this study, we mix self-similar fractions of crushed, irregularly shaped Al2O3 particles (20 to 90 µm and 55 to 300 µm) to bimodal distributions. These mixtures vary in volume fraction of fines (0, 20, 30, 40, 50, 60 and 100 vol.%). The self-similarity of both systems serves the improved parameter correlation in the case of multimodal distributed particle systems. We use nondestructive 3D X-ray microscopy to capture the filter cake microstructure directly after mechanical dewatering, whereby we give particular attention to packing structure and particle–particle relationships (porosity, coordination number, particle size and corresponding hydraulic isolated liquid areas). Our results reveal widely varying distributions of local porosity and particle contact points. An average coordination number (here 5.84 to 6.04) is no longer a sufficient measure to describe the significant bulk porosity variation (in our case, 40 and 49%). Therefore, the explanation of the correlation is provided on a discrete particle level. While individual particles < 90 µm had only two or three contacts, others > 100 µm took up to 25. Due to this higher local coordination number, the liquid load of corresponding particles (liquid volume/particle volume) after mechanical dewatering increases from 0.48 to 1.47.

Hydrothermal Carbonization of Lemon Peel Waste: Preliminary Results on the Effects of Temperature during Process Water Recirculation

Hydrothermal carbonization (HTC) is a promising thermochemical pre-treatment to convert waste biomass into solid biofuels. However, the process yields large amounts of organic process water (PW), which must be properly disposed of or reused. In this study, the PW produced from the hydrothermal carbonization of lemon peel waste (LP) was recycled into HTC process of LP with the aim of maximize energy recovery from the aqueous phase while saving water resources and mitigating the overall environmental impact of the process. The effects of HTC temperature on the properties of solid and liquid products were investigated during PW recirculation. Experiments were carried out at three different operating temperatures (180, 220, 250 °C), fixed residence times of 60 min, and solid to liquid load of 20 wt%, on a dry basis. Hydrochars were characterized in terms of proximate analysis and higher heating values while liquid phases were analyzed in terms of pH and total organic carbon content (TOC). PW recirculation led to a solid mass yield increase and the effect was more pronounced at lower HTC temperature. The increase of solid mass yield, after recirculation steps (maximum increase of about 6% at 180 °C), also led to a significant energy yield enhancement. Results showed that PW recirculation is a viable strategy for a reduction of water consumption and further carbon recovery; moreover preliminary results encourage for an in-depth analysis of the effects of the PW recirculation for different biomasses and at various operating conditions.

QUALITY BY DESIGN APPROACH FOR ENHANCEMENT THE DISSOLUTION RATE OF LAFUTIDINE LIQUISOLID TABLETS

The aim of present work was to enhancing the solubility and dissolution rate of the aquaphobic drug Lafutidine by liquisolid technique. Lafutidine is a H2-receptor antagonist BCS class II drug. Lafutidine compatibility with excipients was evaluated by FT-IR and DSC spectrum. Preliminary trial taken to check the effect of carrier to coating material ratio (R) and non-volatile solvent (PEG- 600) on pre compression and post compression characteristic. Flowable liquid retention potential (Ø -value) and Liquid load factors (Lf) were calculated for required amount of excipients necessary to preparing Lafutidine liquisolid tablet. A 32 full factorial design was employed to check the effect of carrier to coating material ratio R (X1) and PEG- 600 (X2) on hardness (Y1), angle of repose (Y2), % of Cumulative drug release at 5 min Q5 (Y3), and disintegration time (Y4). Multiple linear regression analysis, ANOVA and graphical representation of the influence of factor by 3D plots were performing by using Design expert 7.0. In this study, the following constraints were arbitrarily used for the selection of an optimized batch: Hardness: 3 to 5.5, Angle of repose: 25 to 30, % of Cumulative Drug Release at 5 min (Q5) > 27.09 % and Disintegration time <1.3 min. The desirability value of various dependent variables calculated for determining the optimized batch of tablet and it was also found to be nearer to one. Performance of optimized batch had no shown any significant change at the end of stability study.

CFD Analysis of Falling Film Hydrodynamics for a Lithium Bromide (LiBr) Solution over a Horizontal Tube

Falling film evaporators are used in applications where high heat transfer coefficients are required for low liquid load and temperature difference. One such application is the lithium bromide (LiBr)-based absorber and generator. The concentration of the aqueous LiBr solution changes within the absorber and generator because of evaporation and vapor absorption. This causes the thermophysical properties to differ and affects the film distribution, heat, and mass transfer mechanisms. For thermal performance improvement of LiBr-based falling film evaporators, in-depth analysis at the micro level is required for film distribution and hydrodynamics. In this work, a 2D numerical model was constructed using the commercial CFD software Ansys Fluent v18.0. The influence of the liquid load corresponding to droplet and jet mode, and the concentration, on film hydrodynamics was examined. It was found that the jet mode was more stable at a higher concentration of 0.65 with ±0.5% variation compared to lower concentrations. The recirculation was stronger at a low concentration of 0.45 and existed until the angular position (θ) = 10°, whereas at 0.65 concentration it diminished after θ = 5°. The improved heat transfer is expected at lower concentrations due to lower film thickness and thermal resistance, more recirculation, and a higher velocity field.

The role of supercritical CO2 in gas well health issue – liquid loading

Liquid load or condensate banking is a common well health issue in gas/gas-condensate reservoirs that decreases well productivity by a factor of two to four. Due to the depletion of bottom-hole pressure, the produced liquid accumulates around the wellbore and creates a static column of liquid that reduces gas production until well production ceases. Enhancing gas recovery by CO2 injection is a promising technology because it reduces greenhouse gas emissions and improves CO2 storage. More investigation needs to be conducted to understand the role of supercritical CO2 (SCCO2) in minimising liquid loading. The aim of this research is to examine the impact of SCCO2 in surface tension, condensate viscosity and well productivity. This study consists of simulation and laboratory experiments. Eclipse 300 was used to develop a model that examines the effect of SCCO2 injection on reducing liquid loading issues by varying the well parameters. We found that injecting SCCO2 improved the microscopic displacement efficiency and minimised liquid loading by decreasing the condensate viscosity and the surface tension. The model shows that (1) condensate recovery increases when the injection rate increases up to a limit after which there is no change of production and (2) condensate recovery improves with decreasing production rate.

Determining the Effective Mass Transfer Area in Three-Phase Fluidized Bed with Low Density Inert Solids

The absorption process is strongly influenced by the effective mass transfer area. In this study the effective mass transfer area in gas-solid-liquid three-phase fluidized bed was determined, in a fluidizing column having an internal diameter of 0.14 m and a height of 1.10 m. The solid packing is made of plastic hollow spheres of 0.01 m diameter, with 415 m2/m3 geometric area and a density of 170 Kg/m3. The absorption of carbon dioxide from the air-carbon dioxide mixture with molar concentration of 0.05M, 0.08M and 0.1M CO2 into sodium hydroxide aqueous solutions of 0.5N and 1.0 N has been employed as test reaction. The experiments were conducted with liquid load changing from 6.49 to 16.24 m�/(m� h) and gas velocity of 1.1 m/s and 2.1 m/s. It was found that the effective mass transfer area increased both with the increase of the gas velocity and the increase of the liquid spray density. It has been observed that the effective mass transfer area in gas-solid-liquid three-phase fluidized bed absorber is from three to eight times higher than the geometric area of the solid packing. A mathematical correlation has been established in order to predict the effective mass transfer area,under the specified conditions, with a deviation of less than 5%.