Combined specular and off-specular reflectometry: elucidating the complex structure of soft buried interfaces

Neutron specular reflectometry (SR) and off-specular scattering (OSS) are nondestructive techniques which, through deuteration, give a high contrast even among chemically identical species and are therefore highly suitable for investigations of soft-matter thin films. Through a combination of these two techniques, the former yielding a density profile in the direction normal to the sample surface and the latter yielding a depth-resolved in-plane lateral structure, one can obtain quite detailed information on buried morphology on length scales ranging from the order of ångströms to ∼10 µm. This is illustrated via quantitative evaluation of data on SR and OSS collected in time-of-flight (ToF) measurements of a set of films composed of immiscible polymer layers, protonated poly(methyl methacrylate) and deuterated polystyrene, undergoing a decomposition process upon annealing. Joint SR and OSS data analysis was performed by the use of a quick and robust originally developed algorithm including a common absolute-scale normalization of both types of scattering, which are intricately linked, constraining the model to a high degree. This, particularly, makes it possible to distinguish readily between different dewetting scenarios driven either by the nucleation and growth of defects (holes, protrusions etc.) or by thermal fluctuations in the buried interface between layers. Finally, the 2D OSS maps of particular cases are presented in different spaces and qualitative differences are explained, allowing also the qualitative differentiation of the in-plane structure of long-range order, the correlated roughness and bulk defects by a simple inspection of the scattering maps prior to quantitative fits.

Prototyping Platform for Laser-Based Sensor Technologies: Inspection of Conversion Coatings on Alumina

Transferring laser-based sensors into industrial applications (for instance, for contact and destruction-free inline quality control of alumina alloys) is very challenging due to laser-safety regulations and the complex implementation requirements of individual technological infrastructures. In order to open laser-based sensor technology even for small to medium size enterprises, we introduce a prototyping platform for laser-based sensor technologies that enables fast, error-free, flexible and low-cost transformations in the industry. As an example, the transformation of a laser-based sensor concept using coherent light scattering at technical insulating films is shown. The transformation of this type of sensor for inline quality control is particularly demanding due to the requirements of probing transparent conversion coatings (with a thickness of less than 70 nm) that commonly applied electronic techniques fail to affect. The conversion films are produced on the top of cold-rolled, unpolished alumina so that coherently scattered laser light is regarded as superposition from diffuse scattering processes at the surfaces/interfaces, inclusions, and/or layer imperfections. Analysis is realized by extending the principal approach of reflectometry and considering the role of diffuse and specular scattering together with the concepts of light interferometry. The functionality of the transformed sensor was successfully validated using five different conversion coating thicknesses on AA3003 alumina substrates.

Spiral sound-diffusing metasurfaces based on holographic vortices

In this work, we show that scattered acoustic vortices generated by metasurfaces with chiral symmetry present broadband unusual properties in the far-field. These metasurfaces are designed to encode the holographic field of an acoustical vortex, resulting in structures with spiral geometry. In the near field, phase dislocations with tuned topological charge emerge when the scattered waves interference destructively along the axis of the spiral metasurface. In the far field, metasurfaces based on holographic vortices inhibit specular reflections because all scattered waves also interfere destructively in the normal direction. In addition, the scattering function in the far field is unusually uniform because the reflected waves diverge spherically from the holographic focal point. In this way, by triggering vorticity, energy can be evenly reflected in all directions except to the normal. As a consequence, the designed metasurface presents a mean correlation-scattering coefficient of 0.99 (0.98 in experiments) and a mean normalized diffusion coefficient of 0.73 (0.76 in experiments) over a 4 octave frequency band. The singular features of the resulting metasurfaces with chiral geometry allow the simultaneous generation of broadband, diffuse and non-specular scattering. These three exceptional features make spiral metasurfaces extraordinary candidates for controlling acoustic scattering and generating diffuse sound reflections in several applications and branches of wave physics as underwater acoustics, biomedical ultrasound, particle manipulation devices or room acoustics.

Understanding Ku-Band Ocean Radar Backscatter at Low Incidence Angles under Weak to Severe Wind Conditions by Comparison of Measurements and Models

The rain-free normalized radar cross-section (NRCS) measurements from the Ku-band precipitation radars (PRs) aboard the tropical rainfall measuring mission (TRMM) and the global precipitation measurement (GPM) mission, along with simultaneous sea surface wind truth from buoy observations, stepped-frequency microwave radiometer (SFMR) measurements, and H*Wind analyses, are used to investigate the abilities of the quasi-specular scattering models, i.e., the physical optics model (PO) and the classical and improved geometrical optics models (GO and GO4), to reproduce the Ku-band NRCS at low incidence angles of 0–18° over the wind speed range of 0–45 m/s. On this basis, the limitations of the quasi-specular scattering theory and the effects of wave breaking are discussed. The results show that the return caused by quasi-specular reflection is affected significantly by the presence of background swell waves at low winds. At moderate wind speeds of 5–15 m/s, the NRCS is still dominated by the quasi-specular reflection, and the wave breaking starts to work but its contribution is very small, thus, the models are found in excellent agreement with the measurements. With wind speed increasing, the impact of wave breaking increases, whereas the role of standard quasi-specular reflection decreases. The wave breaking impact on NRCS is first visible at incidence angles near 18° as wind speed exceeds about 20 m/s, then it becomes dominant when wind speed exceeds about 37 m/s where the NRCS is insensitive to wind speed and depends linearly on incidence angle, which cannot be explained by the standard quasi-specular scattering theory.

BornAgain: software for simulating and fitting grazing-incidence small-angle scattering

BornAgain is a free and open-source multi-platform software framework for simulating and fitting X-ray and neutron reflectometry, off-specular scattering, and grazing-incidence small-angle scattering (GISAS). This paper concentrates on GISAS. Support for reflectometry and off-specular scattering has been added more recently, is still under intense development and will be described in a later publication. BornAgain supports neutron polarization and magnetic scattering. Users can define sample and instrument models through Python scripting. A large subset of the functionality is also available through a graphical user interface. This paper describes the software in terms of the realized non-functional and functional requirements. The web site https://www.bornagainproject.org/ provides further documentation.

Broadband corner cloak using a uniaxial transformation medium of stacked artificial dielectric sheets

We demonstrate corner cloak operations mimicking a corner reflector and hiding objects in a truncated corner. The corner cloak is designed at 18.25 GHz and implemented by nonresonant artificial dielectric sheets stacked onto the bottom hypotenuse. It is shown by the near-field measurements that the measured field distributions for the cloak agree well with those for the original area of the corner reflector as well as those for the numerical prediction. The bistatic radar cross-sections (BRCSs) for the cloak and the original area calculated from the measured field distributions coincide with each other and the cloak operation is quantitatively confirmed. The bandwidth evaluated by the specular scattering angles from the BRCSs shows broadband operation as wide as from 16 to 22 GHz.