Calendar Aging of Li-Ion Cells—Experimental Investigation and Empirical Correlation

The lifetime of the battery significantly influences the acceptance of electric vehicles. Calendar aging contributes to the limited operating lifetime of lithium-ion batteries. Therefore, its consideration in addition to cyclical aging is essential to understand battery degradation. This study consequently examines the same graphite/NCA pouch cell that was the subject of previously published cyclic aging tests. The cells were aged at different temperatures and states of charge. The self-discharge was continuously monitored, and after each storage period, the remaining capacity and the impedance were measured. The focus of this publication is on the correlation of the measurements. An aging correlation is obtained that is valid for a wide range of temperatures and states of charge. The results show an accelerated capacity fade and impedance rise with increasing temperature, following the law of Arrhenius. However, the obtained data do also indicate that there is no path dependency, i.e., earlier periods at different temperature levels do not affect the present degradation rate. A large impact of the storage state of charge at 100% is evident, whereas the influence is small below 80%. Instead of the commonly applied square root of the time function, our results are in excellent agreement with an exponential function.

Critical Raw Materials Saving by Protective Coatings under Extreme Conditions: A Review of Last Trends in Alloys and Coatings for Aerospace Engine Applications

Several applications where extreme conditions occur require the use of alloys often containing many critical elements. Due to the ever increasing prices of critical raw materials (CRMs) linked to their high supply risk, and because of their fundamental and large utilization in high tech products and applications, it is extremely important to find viable solutions to save CRMs usage. Apart from increasing processes’ efficiency, substitution, and recycling, one of the alternatives to preserve an alloy and increase its operating lifetime, thus saving the CRMs needed for its manufacturing, is to protect it by a suitable coating or a surface treatment. This review presents the most recent trends in coatings for application in high temperature alloys for aerospace engines. CRMs’ current and future saving scenarios in the alloys and coatings for the aerospace engine are also discussed. The overarching aim of this paper is to raise awareness on the CRMs issue related to the alloys and coating for aerospace, suggesting some mitigation measures without having the ambition nor to give a complete overview of the topic nor a turnkey solution.

Highly Efficient Small Anode Ion Source

We describe some modifications to a Bernas-type ion source that improve the ion beam production efficiency and source operating lifetime. The ionization efficiency of a Bernas type ion source has been improved by using a small anode that is a thin rod, oriented along the magnetic field. The transverse electric field of the small anode causes the plasma to drift in the crossed ExB field to the emission slit. The cathode material recycling was optimized to increase the operating lifetime, and the wall potential optimized to suppress deposition of material and subsequent flake formation. A three-electrode extraction system was optimized for low energy ion beam production and efficient space charge neutralization. An ion beam with emission current density up to 60 mA/cm2 has been extracted from the modified source running on BF3 gas. Space charge neutralization of positive ion beams was improved by injecting electronegative gases.

Experimental Study on Mitigation of Lifetime-Limiting Dielectric Cracking in Extreme Temperature 4H-SiC JFET Integrated Circuits

While NASA Glenn Research Center’s “Generation 10” 4H-SiC Junction Field Effect Transistor (JFET) integrated circuits (ICs) have uniquely demonstrated 500 °C electrical operation for durations of over a year, this experimental work has also revealed that physical cracking of chip dielectric passivation layers ultimately limits extreme-environment operating lifetime [1-3]. The prevention of such dielectric passivation cracks should therefore improve IC high temperature durability and yield, leading to more beneficial technology adoption into aerospace, automotive, and energy systems. This report describes Generation 10.2, 11.1, and 11.2 die tested under unbiased and unpackaged accelerated age testing at 500 °C, 600 °C, 720 °C, and 800 °C in air-atmosphere ovens for 100-and 200-hour duration. Additional samples were separately subjected to 10 thermal cycles between the same high temperatures (with 10-hour high-temperature soak each cycle) and 50 °C. It is shown that having two stoichiometric Si3N4 layers in the interconnect dielectric stack substantially decreases the amount of dielectric cracking observed following these oven tests.

Damage Detection of Truss Structures by Reduction of Degrees of Freedom Using the Serep Method

Damage detection of bridge structures during their operating lifetime is essential. In this paper, two approaches, All Degrees of Freedom and Reduction of the Degrees of Freedom methods, are used to detect the damages in structures. The first method considers All Degrees of Freedom of the structure and the second method, Reduction of the Degrees of Freedom. Since the sensors are installed only on a few degrees of freedom, the responses are available for some of them. The Degrees of Freedom must be reduced and System Equivalent Reduction Expansion Process method is one of the most efficient ways to solve the problem. This research aimed to identify the damage of structures using the Modal Strain Energy method by reducing the structural degree of freedom. Two standard examples are used and the results compared to different damage cases to examine the efficiency of the mentioned method. The results illustrated the proper performance of the Reduction of the Degrees of Freedom method to identify the damage in truss structures. By increasing the number of modes, Reduction of the Degrees of Freedom method detects considerably more accurate the damaged elements, especially when the noise is considered. Also, based on the outcomes to identify damaged elements, it is possible to consider more modes instead of more sensors.

METHODS OF PROLONGATION OF OPERATING LIFETIMES FOR COMPLEX TECHNICAL SYSTEMS LIKE MOVABLE MOUNTINGS OF SPECIAL PURPOSE

The article is devoted to the relevant issue of prolongation of operating lifetimes for complex technical systems like movable mountings of special purpose. The issues of mean and residual lives have been considered, mathematical models of mean and residual lives have been represented. Methods of prolongation of operating lifetimes for expensive objects of special purpose like movable mountings have been described. In particular, mathematical model of prolongation of operating lifetimes by the calculation and analytical method, which is based on of normal distribution law of actual load and durability, has been represented. The experimental method, which is based on analysis of actual technical state of element base and material, has been described. The probabilistic method of calculation of reliability function during prolonged operating lifetime taking into account actual technical state of element base has been represented.

Maximizing Lifetime of Barrier Coverage Wireless Sensor Network with Tell Neighbor Algorithm

The maximizing lifetime of Barrier coverage in wireless sensor network has attracted researchers in recent past. In barrier coverage applications it is essential to prolong the lifetime of sensor networks which guarantees extended operating lifetime of the overall network. In this paper, we propose a novel Tell Neighbor Algorithm (TNA), which increases the operating lifetime of the overall network. Simulation results show that the lifetime obtained by TNA is better than some of the already existing state-of-art algorithms. Lifetime obtained by TNA is doubled when compared already existing algorithms.