Preheated composite: Innovative approach for aesthetic restoration

Resin-based composites are today one of the most widely used restorative materials. However, its most debilitating problem is volumetric shrinkage due to polymerization which may result in contraction stress and subsequent micro leakage and adhesion failure. Preheating composites prior to polymerisation have several advantages over conventional composites. This review article highlights the mechanical properties, advantages and significance of preheated composites.

The Influence of Various Photoinitiators on the Properties of Commercial Dental Composites

The aim of this article was to compare the biomechanical properties of commercial composites containing different photoinitiators: Filtek Ultimate (3M ESPE) containing camphorquinone (CQ); Estelite Σ Quick (Tokuyama Dental) with CQ in RAP Technology®; Tetric EvoCeram Bleach BLXL (Ivoclar Vivadent AG) with CQ and Lucirin TPO; and Tetric Evoceram Powerfill IVB (Ivoclar Vivadent AG) with CQ and Ivocerin TPO. All samples were cured with a polywave Valo Lamp (Ultradent Products Inc.) with 1450 mW/cm2. The microhardness, hardness by Vicker’s method, diametral tensile strength, flexural strength and contraction stress with photoelastic analysis were tested. The highest hardness and microhardness were observed for Filtek Ultimate (93.82 ± 17.44 HV), but other composites also displayed sufficient values (from 52 ± 3.92 to 58,82 ± 7.33 HV). Filtek Ultimate not only demonstrated the highest DTS (48.03 ± 5.97 MPa) and FS (87.32 ± 19.03 MPa) but also the highest contraction stress (13.7 ± 0.4 MPa) during polymerization. The TetricEvoCeram Powerfill has optimal microhardness (54.27 ± 4.1 HV), DTS (32.5 ± 5.29 MPa) and FS (79.3 ± 14.37 MPa) and the lowest contraction stress (7.4 ± 1 MPa) during photopolymerization. To summarize, Filtek Ultimate demonstrated the highest microhardness, FS and DTS values; however, composites with additional photoinitiators such as Lucirin TPO and Ivocerin have the lowest polymerization shrinkage. These composites also have higher FS and DTS and microhardness than material containing CQ in Rap Technology.

Biomimetic Prosthetic Hand Enabled by Liquid Crystal Elastomer Tendons

As one of the most important prosthetic implants for amputees, current commercially available prosthetic hands are still too bulky, heavy, expensive, complex and inefficient. Here, we present a study that utilizes the artificial tendon to drive the motion of fingers in a biomimetic prosthetic hand. The artificial tendon is realized by combining liquid crystal elastomer (LCE) and liquid metal (LM) heating element. A joule heating-induced temperature increase in the LCE tendon leads to linear contraction, which drives the fingers of the biomimetic prosthetic hand to bend in a way similar to the human hand. The responses of the LCE tendon to joule heating, including temperature increase, contraction strain and contraction stress, are characterized. The strategies of achieving a constant contraction stress in an LCE tendon and accelerating the cooling for faster actuation are also explored. This biomimetic prosthetic hand is demonstrated to be able to perform complex tasks including making different hand gestures, holding objects of different sizes and shapes, and carrying weights. The results can find applications in not only prosthetics, but also robots and soft machines.

The Influence of Cement Layer Thickness on the Stress State of Metal Inlay Restorations—Photoelastic Analysis

The successful restoration of teeth requires a good connection between the inlay and natural tissue. A strong bond may improve retention and reinforce tooth structure. The purpose of this study was to evaluate the influence of cement layer thickness on contraction stress generated during photopolymerization, and to determine the changes in stress state of the cement occurring during aging in water (over 84 days). Two cements were used: resin composite cement (NX3) and self-adhesive resin cement (Maxcem Elite Chroma). A cylindrical sample made of CuZn alloy was used to imitate the inlay. The stress state was measured by photoelastic analysis. The contraction stress of the inlay restoration was calculated for cement layer thicknesses of 25 µm, 100 µm, 200 µm, and 400 µm. For both tested materials, the lowest contraction stress was observed for the thinnest layer (25 µm), and this increased with thickness. Following water immersion, a significant reduction in contraction stress was observed due to hygroscopic expansion. Applying a thin layer (approximately 25 µm) of composite and self-adhesive resin cements resulted in high levels of expansion stresses (over −6 MPa) after water aging.

Influence of an Alkoxylation Grade of Acrylates on Shrinkage of UV-Curable Compositions

Commercially available UV curable restorative materials are composed of inorganic filler hydroxyapatite, multifunctional methacrylate, photoinitiator and alkoxylated acrylate. Especially, the application of alkoxylated monomers with different alkoxylation grade allows the reduction of polymerization shrinkage which plays the major role by application of low shrinkage composites as high quality restorative dental materials or other adhesive materials in the form of UV-polymerized self-adhesive acrylics layers (films). There are several ways to reduce polymerization shrinkage of restorative compositions, for example, by adjusting different alkoxylated acrylic monomers, which are integral part of investigated UV curable restorative composites. This article is focused on the studies of contraction-stress measured as shrinkage during UV-initiated curing of restorative composites containing various commercially available alkoxylated acrylates. Moreover, studies with experimental restorative materials and recent developments typical for UV curing technology using special photoreactive monomers are described.

Hot Tearing of 9Cr3Co3W Heat-Resistant Steel during Solidification

The linear contraction and hot tearing behavior of 9Cr3Co3W heat-resistant steel during solidification were studied by combining in-situ casting experiments and the corresponding numerical simulations. The linear contraction, stress and temperature of the samples were detected during solidification. The results show that the linear contraction of 9Cr3Co3W heat-resistant steel was 1.7% in the sand mold. Meanwhile, the critical temperature and stress of the hot tearing that occurred at the hot spot were 1304 °C and 0.72 MPa, respectively. The occurrence of hot tearing was observed at the tip of secondary dendrites along the primary dendritic arms, where the solute elements were significantly enriched at the final solidification.

Contraction and Hydroscopic Expansion Stress of Dental Ion-Releasing Polymeric Materials

Ion-releasing polymeric restorative materials seem to be promising solutions, due to their possible anticaries effect. However, acid functional groups (monomers) and glass filler increase hydrophilicity and, supposedly, water sorption. The purpose of the study was to evaluate the influence of water sorption of polymeric materials on the stress state at the restoration-tooth interface. Beautifil Bulk Fill Flow, Beautifil Flow Plus F00, Beautifil Flow F02, Dyract eXtra, Compoglass Flow, Ionosit, Glasiosite, TwinkiStar, Ionolux and Fuji II LC were used for the study. The stress state was measured using photoelastic analysis after: 0.5, 24, 72, 96, 168, 240, 336, 504, 672, 1344 and 2016 h. Moreover, water sorption, solubility and absorption dynamic were assessed. The water sorption, solubility and absorption dynamic of ion-releasing restorative materials are material dependent properties. The overall results indicated that the tested restorative materials showed significant stress decrease. The total reduction in contraction stress and water expansion stress was not observed for materials with low value of water sorption (Beautifil Bulk Fill, Dyract eXtra, Glasionosit and Twinky Star). The photoelastic method turned out to be inadequate to evaluate stress changes of resin modified glass-ionomer cement (RMGI, Fuji II LC and Ionolux).