entropy conservation
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Author(s):  
John M. Peters ◽  
Jake P. Mulholland ◽  
Daniel R. Chavas

AbstractCommon assumptions in temperature lapse rate formulas for lifted air parcels include neglecting mixing, hydrostatic balance, the removal of all condensate once it forms (pseudoadiabatic), and/or the retention of all condensate within the parcel (adiabatic). These formulas are commonly derived from the conservation of entropy, which leads to errors when non-equilibrium mixed-phase condensate is present. To evaluate these assumptions, a new general lapse rate formula is derived from an expression for energy conservation, rather than entropy conservation. This new formula incorporates mixing of the parcel with its surroundings, relaxes the hydrostatic assumption, allows for non-equilibrium mixed-phase condensate, and can be formulated for pseudoadiabatic or adiabatic ascent. The new formula is shown to exactly conserve entropy for reversible ascent. Predictions by the new formula are compared to that of older and less general formulas. The errors in previous formulas arise from the assumption of hydrostatic balance, which results in considerable warm biases due to the neglect of the energy sink from buoyancy. Predictions of ascent with entrainment using the new formula are then compared to parcel properties along trajectories in large eddy simulations. Simulated parcel properties are better predicted by the formula using a diluted analogy to adiabatic ascent, wherein condensate is diluted at the same rate as other parcel properties, than by the diluted analogy to pseudoadiabatic ascent, wherein all condensate is removed. These results suggest that CAPE should be computed with adiabatic, rather than pseudoadiabatic, parcel ascent.


Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2196
Author(s):  
Michael H. Peters

Nonequilibrium statistical mechanics or molecular theory has put the transport equations of mass, momentum and energy on a firm or rigorous theoretical foundation that has played a critical role in their use and applications. Here, it is shown that those methods can be extended to nonequilibrium entropy conservation. As already known, the “closure” of the transport equations leads to the theory underlying the phenomenological laws, including Fick’s Law of Diffusion, Newton’s Law of Viscosity, and Fourier’s Law of Heat. In the case of entropy, closure leads to the relationship of entropy flux to heat as well as the Second Law or the necessity of positive entropy generation. It is further demonstrated how the complete set of transport equations, including entropy, can be simplified under physically restrictive assumptions, such as reversible flows and local equilibrium flows. This analysis, in general, yields a complete, rigorous set of transport equations for use in applications. Finally, it is also shown how this basis set of transport equations can be transformed to a new set of nonequilibrium thermodynamic functions, such as the nonequilibrium Gibbs’ transport equation derived here, which may have additional practical utility.


2021 ◽  
Vol 143 (5) ◽  
Author(s):  
Fabio Licheri ◽  
Francesco Cambuli ◽  
Pierpaolo Puddu ◽  
Tiziano Ghisu

Abstract Wells turbines are among the most interesting power takeoff devices used in oscillating water column (OWC) systems for the conversion of ocean-wave energy into electrical energy. Several configurations have been studied during the last decades, both experimentally and numerically. Different methodologies have been proposed to estimate the efficiency of this turbine, as well as different approaches to evaluate the intermediate quantities required. Recent works have evaluated the so-called second-law efficiency of a Wells turbine, and compared it to the more often used first-law efficiency. In this study, theoretical analyses and numerical simulations have been used to demonstrate how these two efficiency measures should lead to equivalent values, given the low pressure ratio of the machine. In numerical simulations, small discrepancies can exist, but they are due to the difficulty of ensuring entropy conservation on complex three-dimensional meshes. The efficiencies of different rotor geometries are analyzed based on the proposed measures, and the main sources of loss are identified.


2018 ◽  
Vol 27 (10) ◽  
pp. 1844014
Author(s):  
S. G. Moiseenko ◽  
G. S. Bisnovatyi-Kogan

One of the difficulties of numerical simulations of cold supersonic astrophysical flows is a big difference in different types of energy. Gravitational and/or kinetic energy of the gas could be much larger than its internal energy. In such a case, it is possible to get large numerical errors in the simulations. To avoid this difficulty, conservation of entropy equation was used instead of energy conservation equation. The entropy conservation equation does not contain the gravitational and kinetic energy. The application of the isentropic set of equations is correct when the flow does not contain shocks or the amplitude of the shocks (shock wave Mach number) is not large. We estimate the violation of the energy conservation low when the “shock wave” is isentropic.


2018 ◽  
Vol 229 (3) ◽  
pp. 1223-1238 ◽  
Author(s):  
Piotr Gwiazda ◽  
Martin Michálek ◽  
Agnieszka Świerczewska-Gwiazda

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