Waste Apple Pomace Conversion to Acrylic Acid: Economic and Potential Environmental Impact Assessments

The global demand for acrylic acid (AA) is increasing due to its wide range of applications. Due to this growing demand, alternative AA production strategies must be explored to avoid the exacerbation of prevailing climate and global warming issues since current AA production strategies involve fossil resources. Investigations regarding alternative strategies for AA production therefore constitute an important research interest. The present study assesses waste apple pomace (WAP) as a feedstock for sustainable AA production. To undertake this assessment, process models based on two production pathways were designed, modelled and simulated in ASPEN plus® software. The two competing production pathways investigated included a process incorporating WAP conversion to lactic acid (LA) prior to LA dehydration to generate AA (denoted as the fermentation–dehydration, i.e., FD, pathway) and another process involving WAP conversion to propylene prior to propylene oxidation to generate AA (denoted as the thermochemical–fermentation–oxidation, i.e., TFO, pathway). Economic performance and potential environmental impact of the FD and TFO pathways were assessed using the metrics of minimum selling price (MSP) and potential environmental impacts per h (PEI/h). The study showed that the FD pathway presented an improved economic performance (MSP of AA: USD 1.17 per kg) compared to the economic performance (MSP of AA: USD 1.56 per kg) of the TFO pathway. Crucially, the TFO process was determined to present an improved environmental performance (2.07 kPEI/h) compared to the environmental performance of the FD process (8.72 kPEI/h). These observations suggested that the selection of the preferred AA production pathway or process will require a tradeoff between economic and environmental performance measures via the integration of a multicriteria decision assessment in future work.

‘We Pay to Buy Ourselves’: Netflix, Spectators & Streaming

This article explains how Netflix has transformed the ways in which we interact with media in the contemporary milieu. I argue that Netflix works through a process of planned differentiation, designing unique customization experiences to create a new type of media user that participates in its global and regional release and production strategies. This leads me into a discussion of how the Netflix interface manages the spectators’ experience through a series of connected features. Thus, I detail Netflix’ personalization mechanisms, proposing that, ultimately, its users ‘pay to buy themselves’, or the version of themselves its interface offers back to users upon systematically gathering data on their habits. Finally, I remark that the key characteristics of the current streaming service/spectator relationship are deceptive limitlessness, customization, the automation of content flow and ubiquity, weaving a form of audiovisual engagement that has partially and, at times completely, conquered our everyday.

Waste apple pomace conversion to acrylic acid: Economic and environmental assessment

The global demand for acrylic acid (AA) is increasing due to its wide range of applications. Due to this growing demand, alternative AA production strategies must be explored to avoid the exacerbation of prevailing climate and global warming issues since current AA production strategies involve AA production using fossil resources. Investigations on alternative strategies for AA production therefore constitute an important research interest. The present study therefore assesses waste apple pomace (WAP) as a feedstock for the sustainable AA produc-tion. To undertake this assessment, process models, based on two production pathways were designed, modelled and simulated in ASPEN plus® software. The two competing production pathways investigated include a process incorporating WAP conversion to lactic acid (LA), prior to LA dehydration to generate AA (denoted as the FD pathway) and another process involving WAP conversion to propylene, prior to propylene oxidation to generate AA (denoted as the TFO pathway). Economic and environmental performances of the FD and TFO pathways were assessed via the minimum selling price (MSP) and potential environmental impacts per h (PEI/h) metrics. The study was able to show that the FD pathway presented an improved economic performance (MSP of AA: US $1.17 per kg) performance compared to the economic performance (MSP of AA: US $1.56 per kg) of the TFO pathway. Crucially, the TFO process was shown to present an improved environmental performance (2.07 kPEI/h) compared to the environmental performance of the FD process (8.72 kPEI/h). These observations sug-gests that the selection of the preferred AA production will require a trade-off between the performance measures, and the integration of a multi-criteria decision assessment in future work.

Incomplete Gamma distribution of rainfall for sustainable crop production strategies at Palampur, Himachal Pradesh

The knowledge of rainfall pattern (amount and probability) helps in planning of crops to be grown in a region. Therefore weekly, monthly, seasonal and annual rainfall data for 33 years (1974-2006) for the station Palampur have been collected and its analysis has been attempted. The annual and monthly rainfall data were analyzed for finding out drought normality and abnormality. The analysis indicated that the rainfall is mainly confined in annual rainfall 2343 mm with 25.7 per cent variability. The standard deviation of annual rainfall is 62.8 mm. Each standard week from 26th to 35th receive a rainfall of more than 100 mm, indicating the crop period. Seed sowing in paddy nursery in the Palampur region generally takes places immediately after initiation of monsoon during 23rd - 25th standard meteorological weeks and transplanting is carried out around 27th or 28th standard meteorological week. The tillering, 50 percent flowering and dough stage are observed during 32-33rd, 37-38th and 40-41st standard meteorological weeks respectively.

Bioconversion of Lignocellulosic Biomass into Value Added Products under Anaerobic Conditions: Insight into Proteomic Studies

Production of biofuels and other value-added products from lignocellulose breakdown requires the coordinated metabolic activity of varied microorganisms. The increasing global demand for biofuels encourages the development and optimization of production strategies. Optimization in turn requires a thorough understanding of the microbial mechanisms and metabolic pathways behind the formation of each product of interest. Hydrolysis of lignocellulosic biomass is a bottleneck in its industrial use and often affects yield efficiency. The accessibility of the biomass to the microorganisms is the key to the release of sugars that are then taken up as substrates and subsequently transformed into the desired products. While the effects of different metabolic intermediates in the overall production of biofuel and other relevant products have been studied, the role of proteins and their activity under anaerobic conditions has not been widely explored. Shifts in enzyme production may inform the state of the microorganisms involved; thus, acquiring insights into the protein production and enzyme activity could be an effective resource to optimize production strategies. The application of proteomic analysis is currently a promising strategy in this area. This review deals on the aspects of enzymes and proteomics of bioprocesses of biofuels production using lignocellulosic biomass as substrate.

Vaca Muerta: An Emerging Shale Petroleum Reservoir

Argentina is ranked second globally in terms of technically recoverable shale gas, and fourth in shale oil (EIA 2015). The most prolific shale is the Vaca Muerta formation. The objective of this paper is to present geological and reservoir characterization, drilling and production strategies, as well as historical performance and economics of Vaca Muerta. The word petroleum as used in this paper includes oil, natural gas, and natural gas liquids. This paper describes natural fractures and their impact on hydrocarbon productivity. The successful commercial production from this unconventional resource has been driven by many factors, including regional geology, availability of advanced technology such as horizontal drilling and multi-stage hydraulic fracturing, as well as domestic and regional hydrocarbon demand (Sierra 2016). Vaca Muerta itself is very unique with multiple hydrocarbon windows from east to west, ranging from dry gas to wet gas, to light oil and black oil. The productivity of Vaca Muerta is benchmarked to some of the best US shale plays such as the Eagle Ford and the Marcellus. Vaca Muerta contains 1202 Tcf of risked gas in-place and 270 billion barrels of risked oil in-place. It is estimated that 308 Tcf and 16 billion barrels of these resources are technically recoverable (EIA 2015). To date, the total number of horizontal wells exceeds 600, mostly drilled in the black oil window (Secretaria de Energia de Argentina 2020; Wood Mackenzie 2020b). Dubbed the ‘golden goose’ of Argentina, the last decade has seen rapid exploration and development activities. The Argentina state oil company (YPF) leads the development in this region together with its partners. In 2019, production from Vaca Muerta reached 90,000 bbl/d of oil and 1180 MMcf/d of gas, contributing 21% of Argentina's total production (Secretaria de Energia de Argentina 2020; Wood Mackenzie 2020b). YPF predicted these rates would increase by 150% in 2022 (Rassenfoss 2018). Part of this increase will be contributed by La Amarga Chica block, where YPF and its partner, PETRONAS approved their 30-year master development plan in late 2018 to deliver 54,000 boe/d by 2022 (Zborowski 2019). This production increase has obviously been delayed due to the COVID-19 pandemic. The novelty of this paper is integration of geological and reservoir characterization, drilling and production strategies, as well as historical performance and economics of Vaca Muerta. It is concluded that oil and gas potential in the Vaca Muerta shale is significant and rivals the potential of some of the shales widely developed in the Unites States and Canada.