Numerical Study of Epitaxial Growth after Partial Remelting during Selective Electron Beam Melting in the Context of Ni–Al

In the selective electron beam melting approach an electron beam is used to partially melt the material powder. Based on the local high energy input, the solidification conditions and likewise the microstructures strongly deviate from conventional investment casting processes. The repeated energy input into the material during processing leads to the partial remelting of the already existing microstructure. To closer investigative this effect of partial remelting, in the present work the phase-field model is applied. In the first part the solidification of the referenced Ni–Al system is simulated in respect to selective electron beam melting. The model is calibrated such to reproduce the solidification kinetics of the superalloy CMSX-4. By comparison to experimental observations reported in the literature, the model is validated and is subsequently applied to study the effect of partial remelting. In the numerical approach the microstructures obtained from the solidification simulations are taken as starting condition. By systematically varying the temperature of the liquid built layer, the effect of remelting on the existing microstructure can be investigated. Based on these results, the experimental processing can be optimized further to produce parts with significantly more homogenous element distributions.

Metastable–solid phase diagrams derived from polymorphic solidification kinetics

Nonequilibrium processes during solidification can lead to kinetic stabilization of metastable crystal phases. A general framework for predicting the solidification conditions that lead to metastable-phase growth is developed and applied to a model face-centered cubic (fcc) metal that undergoes phase transitions to the body-centered cubic (bcc) as well as the hexagonal close-packed phases at high temperatures and pressures. Large-scale molecular dynamics simulations of ultrarapid freezing show that bcc nucleates and grows well outside of the region of its thermodynamic stability. An extensive study of crystal–liquid equilibria confirms that at any given pressure, there is a multitude of metastable solid phases that can coexist with the liquid phase. We define for every crystal phase, a solid cluster in liquid (SCL) basin, which contains all solid clusters of that phase coexisting with the liquid. A rigorous methodology is developed that allows for practical calculations of nucleation rates into arbitrary SCL basins from the undercooled melt. It is demonstrated that at large undercoolings, phase selections made during the nucleation stage can be undone by kinetic instabilities amid the growth stage. On these bases, a solidification–kinetic phase diagram is drawn for the model fcc system that delimits the conditions for macroscopic grains of metastable bcc phase to grow from the melt. We conclude with a study of unconventional interfacial kinetics at special interfaces, which can bring about heterogeneous multiphase crystal growth. A first-order interfacial phase transformation accompanied by a growth-mode transition is examined.

Mathematical Modeling of Technological Modes of Operation of Liquid Stamping of Aluminum Alloy AK7

In this paper we examine a mathematical model of solidification of the melt in a two-phase zone during the formation of forgings through liquid stamping. From the simultaneous solution of the Fourier equations of thermal conductivity for the melt, the two-phase zone, and the solid crust, the solidification kinetics has been established and the effect of external pressure on the temperature fields and components of the solidification time of hollow thin-walled forgings has been thoroughly assessed.